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Influence Factors for the Degradation of Sodium mNitrobenzene Sulfonate by CWPO

ZHENG Shuang1, DONG Guohua2, WANG Jian1, LIU Jianlin3, LI Yu1,3   

  1. 1. College of Environment and Resources, Jilin University, Changchun 130012, China; 2. College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, Heilongjiang Province, China;3. Energy and Environmental Research Center, North China Electric Power University, Beijing 102206, China
  • Received:2007-06-28 Revised:1900-01-01 Online:2008-05-26 Published:2008-05-26
  • Contact: LI Yu

Abstract: Degradation of sodium mnitrobenzene sulfonate was investigated by the catalytic wet peroxide oxidation (CWPO), and the removal effectiveness of the degradation were compared under conditions of different catalysts (Co/Bi, Mn/Ce, Cu/Mn/Ce, Cu(NO3)2, and activated carbon) and oxidants (peroxide and oxygen). Meanwhile, the effects of the reaction conditions, including reaction temperature, amounts of peroxide and catalyst, oxygen partial pressure and the initial concentration on the removal efficiencies were also discussed. The results show that sodium mnitrobenzene sulfonate was more efficiently decomposed by CWPO with Cu(NO3)2 as catalyst; the reaction temperature, am ounts of peroxide and sodium mnitrobenzene sulfonate have significant influence on the degradation reaction. Besides, the addition of oxygen and catalyst can enhancethe degradation efficiency. Otherwise, the temperatureincreasing process has important influence on the degradation of sodium mnitrobenzene sulfonate through CWPO.

Key words: catalytic wet peroxide oxidation, electroplating waste water, sodium mnitrobenzene sulfonate, peroxide

CLC Number: 

  • X703