Journal of Jilin University Science Edition ›› 2024, Vol. 62 ›› Issue (2): 444-0451.

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Dithiocarbamate Modified GO Material and Its  Adsorption Performance for  Cu2+

YANG Weijie,  LI Jie,  LI Yanxia,  ZHAO Hui   

  1. School of Chemistry and Chemical Engineering,  Zhoukou Normal University,  Zhoukou 466001,  Henan Province,  China
  • Received:2023-10-16 Online:2024-03-26 Published:2024-03-26

Abstract: The dithiocarbamate modified graphene oxide (GO) material (GO-TETA-DTC) based on triethylenetetramine (TETA) was prepared by grafting TETA onto the surface of GO firstly and then reacting it with CS2. The GO-TETA-DTC was characterized and analyzed by infrared spectrometer,  element analyzer and scanning electron microscope. We studied the adsorption performance of the material on Cu2+, and investigated the effects of pH values of solution, initial  mass concentration of Cu2+, adsorption time and temperature on adsorption effects. The  results show  that the adsorption process of Cu2+ in water by GO-TETA-DTC follows the quasi-second order kinetic equation,  the intra-particle diffusion equation and Langmuir equation.  The maximum adsorption capacity of GO-TETA-DTC for Cu2+ calculated from Langmuir equation is 294.12 mg/g. The  adsorption process takes place in the form of heat absorption and  entropy increase.

Key words:  , graphene,  , dithiocarbamate,  , copper ion,  , adsorption

CLC Number: 

  • O69