Journal of Jilin University Science Edition ›› 2024, Vol. 62 ›› Issue (3): 734-741.

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Synthesis of a Novel Mn(Ⅱ)-Based Metal-Organic Framework Materials and Its Photocatalytic Degradation Performance of Tetracycline

WANG Lishan,  GUO Huadong   

  1. College of Chemistry, Changchun Normal University, Changchun 130032,  China
  • Received:2023-11-29 Online:2024-05-26 Published:2024-05-26

Abstract: Aiming at the problem that it was difficult to eliminate tetracycline in wastewater and achieve water quality purification through self-purification of the environment, we developed and designed a  new type of sewage treatment agents. A novel metal-organic framework (MOF) material [Mn2(TCPQ)(H2O)8]·xsolvent.  was synthesized by 4,4′,4″,4′′′-(quinoxalin-2,3,6,7-tetrayl)tetrabenzoic acid as the organic ligand and Mn(Ⅱ) as the metal center ion. The structure and stability of the material were studied by using powder X-ray diffraction,  X\|ray single crystal diffraction, Fourier transform infrared spectroscopy and thermogravimetry,  and its photocatalytic performance was analyzed. The experimental results show that the degradation rate of tetracycline by the prepared MOFs material can reach 97.5% when exposed to visible light for 30 min. The compound can be used as an excellent  material for the degradation of tetracycline.

Key words: metal-organic framework material, photocatalysis, tetracycline

CLC Number: 

  • O614