卟啉化合物的电化学性质

J4 ›› 2011, Vol. 49 ›› Issue (05): 944-948.

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Electrochemical Properties of Porphyrin Compounds

ZHENG Wenqi¹, SHAN Ning², SHI Yingyan¹, FA Huanbao³, LI Di⁴, WANG Xingqiao²

1. Department of Basic Science, Jilin Institute of Architecture and Civil Engineering, Changchun 130118, China;2. College of Chemistry, Jilin University, Changchun 130021, China;3. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;4. School of Science, Tsinghua University, Beijing 100084, China

Received:2011-01-09 Online:2011-09-26 Published:2011-09-27
Contact: SHAN Ning E-mail:shining@jlu.edu.cn

Abstract

Abstract:

The authors synthesized two porphyrin monomers with different substituents and four porphyrin oligomers with different bridglinked reagents according to the literatures. The electrochemical properties of the porphyrins were studied by using cyclic voltammetry (CV) and compared with those of other porphyrin molecules under similar experimental conditions. It was found that porphyrin monomer linked with an electrondonating group was easy to reduce. The electrochemical properties of porphyrin oligomers were influenced by bridgelinked reagents and conjugative effect of porphyrin molecules.

Key words: porphyrin, monomer, oligomer, electrochemical property

CLC Number:

O646

ZHENG Wen-Qi, CHAN Ning, DAN Ying-Yan, FA Huan-Bao, LI Di, WANG Xing-Jiao. Electrochemical Properties of Porphyrin Compounds[J].J4, 2011, 49(05): 944-948.

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Electrochemical Properties of Porphyrin Compounds

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