基于羟基苯基卟啉骨架的二聚卟啉合成及性能

Abstract

Abstract: Using 1,4-dichloro-2,5-dinitrotoluene as bridging agent, H-2MHTPP porphyrin dimer was prepared by one-step synthesis. The structure of porphyrin dimer was characterized by MALDI-TOF mass spectrometry. The electrochemical and photochemical properties of the porphyrin dimer and the surface photovoltage spectrum (SPS) of the porphyrin dimer were studied. The results show that the H2MHTPP porphyrin dimer is a p-type semiconductor.

Key words: dimeric porphyrin, electrochemical and photochemical properties, surface photovoltage spectrum, ptype semiconductor

CLC Number:

O614

SHI Yingyan, ZHANG Chang, XU Fenghui, LI Di. Synthesis and Properties of Dimeric PorphyrinsBased on Hydroxyphenyl Porphyrin Skeleton[J].Journal of Jilin University Science Edition, 2020, 58(4): 1010-1014.

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Synthesis and Properties of Dimeric PorphyrinsBased on Hydroxyphenyl Porphyrin Skeleton

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