异喹啉修饰金属有机骨架配合物的合成及其二氧化碳和碘的吸附性能

Abstract

Abstract: We synthesized a metal-organic framework complex [Cu₃(L)₃·2DMF]·2DMF modified by isoquinoline. The structure of the complex was characterized by elemental analysis, thermogravimetric analysis, infrared spectroscopy, X-crystal diffraction and powder X-ray diffraction. The results show that this complex has a new topology network structure with {3,4,6}-connectivity, which can selectively separate carbon dioxide from methane and has good adsorption performance for iodine in solution with a maximum adsorption capacity of 661.84 mg/g.

Key words: metal-organic framework complex, iodine adsorption, isoquinoline

CLC Number:

O614

MI Shengyong, GUO Huadong. Synthesis of MOF Complex Modified by Isoquinoline and Its Adsorption Properties for Carbon Dioxide and Iodine[J].Journal of Jilin University Science Edition, 2023, 61(5): 1230-1236.

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Synthesis of MOF Complex Modified by Isoquinoline and Its Adsorption Properties for Carbon Dioxide and Iodine

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