一种多功能性Keggin型多酸基配合物的合成、 结构及性能

Journal of Jilin University Science Edition ›› 2023, Vol. 61 ›› Issue (5): 1223-1229.

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Synthesis, Structure and Properties of a Multifunctional Keggin-Type Polyacid Complex

WANG Liang¹， XU Tingshuang²， GENG Jiaqi³， YANG Boqi¹， QI Chong²， YU Xiaoyang³, LU Tong¹

1. College of Chemistry， Jilin University， Changchun 130012， China； 2. Institute of Translational Medicine， the First Hospital of Jilin University， Changchun 130021， China； 3. Institute of Chemistry and Pharmaceutical Engineering，Jilin Institute of Chemical Technology， Jilin 132022， Jilin Province， China

Received:2023-03-01 Online:2023-09-26 Published:2023-09-26

Abstract

Abstract: We designed and synthesized an inorganic-organic hybrid complex based on Keggin-type polyacids, and obtained [SiW₁₂O₄₀][Ag(bpy)₂]₄·H₂O (1)(bpy=2,2′-bipyridine) by using hydrothermal in situ synthesis method. The bpy in complex 1 was obtained by in situ decarboxylation of 2,2′-bipyridine-6,6′-dicarboxylic acid. The structure of complex was characterized by single crystal X-ray diffraction, elemental analysis, infrared spectrum and thermogravimetric analysis, and its fluorescence, photocatalytic degradation of organic dyes, electrochemical and antibacterial properties were studied.

Key words: Keggin-type polyacid, , hydrothermal synthesis, , structural characterization, , electrochemical property

CLC Number:

O611.3

WANG Liang, XU Tingshuang, GENG Jiaqi, YANG Boqi, QI Chong, YU Xiaoyang, LU Tong. Synthesis, Structure and Properties of a Multifunctional Keggin-Type Polyacid Complex [J].Journal of Jilin University Science Edition, 2023, 61(5): 1223-1229.

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Synthesis, Structure and Properties of a Multifunctional Keggin-Type Polyacid Complex

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