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Hydrothermal Synthesis and Crystal Structure of Coordination Complex [Cu(imi)24[(imi)2(Mo8O26)]·H2O

DING Hong, HE Xin, XU Jia-ning, LI Ya-nan, ZHANG Ping   

  1. College of Chemistry, Jilin University, Changchun 130012, China
  • Received:2005-08-26 Revised:1900-01-01 Online:2006-05-26 Published:2006-05-26
  • Contact: ZHANG Ping

Abstract: A molybdenum complex [Cu(imi)24[(imi)2(Mo8O26)]·H2O(imi: imidazole) was prepared by means of hydrothermal synthesis and characterized via single crystal Xray analysis, IR and XPS spectra, thermogravimetric analysis, elemental analysis and electrochemistry analysis. The complex molecular consists of an imidazolecoordinated octamolybdate anion, four imidazolecoordinated copper(I) cations and a lattice water molecule. A three dimensional framework was formed by complex hydrogen bonding and π-π interactions.

Key words: copper, polyoxomolybdate, crystal structure, complex

CLC Number: 

  • O614