吉林大学学报(地球科学版) ›› 2016, Vol. 46 ›› Issue (6): 1697-1710.doi: 10.13278/j.cnki.jjuese.201606109
王力, 孙丽伟
Wang Li, Sun Liwei
摘要: 莱州寺庄金矿床位于焦家成矿带南段,是焦家金矿田的一部分,也是焦家成矿带上重要的热液脉型金矿床。区内主要有黄铁绢英岩带、黄铁绢英岩化花岗碎裂岩带和黄铁绢英岩化花岗岩带3个控矿带,位于焦家断裂带下盘。矿石矿物主要为银金矿、黄铁矿、自然金、黄铜矿、方铅矿和闪锌矿等。该矿床发育了绢英岩化、硅化、钾化、碳酸盐化等蚀变类型,且硅化和绢英岩化与矿化关系最为密切。本文从流体包裹体岩相学特征、显微测温、单个包裹体成分激光拉曼光谱分析以及氢、氧同位素分析方面对山东省寺庄金矿床成矿流体特征进行综合研究。结果显示:该矿床金矿石中主要发育含CO2相、气液两相和CO2相三类包裹体。在成矿过程中,流体经历了CO2-H2O-NaCl体系的不混溶作用。成矿流体具有低盐度(w(NaCl)为(0.53%~10.24%))、低密度(0.50~1.03 g/cm3)的特点。成矿温度为260~340℃,压力为82~116 MPa,成矿深度为中成(7.40~8.94 km)。氢、氧同位素分析成矿流体δDV-SNOW为-76.6‰~-69.0‰,δ18O水为2.94‰~7.24‰,说明成矿流体以幔源流体为主,并有少量的岩浆水和大气降水参与。结合该矿床地质特征与实验结果综合分析,认为寺庄金矿的矿床成因类型为受断裂构造控制的幔源流体参与成矿的中温中成热液蚀变岩型金矿床。
中图分类号:
| [1] 宋明春, 崔书学, 杨之利, 等. 山东焦家金矿带深部找矿的重大突破及其意义[J]. 地质与勘探,2008,44(1):1-8. Song Mingchun,Cui Shuxue, Yang Zhili, et al. Grest Progress and Far-Reacting Signification of Deep Exploration in the Jiaojia Metallogenic Belt, Shandong Province[J]. Geology and Prospecting, 2008, 44(1):1-8. [2] 王思红, 于晓杰, 丁明飞, 等. 寺庄金矿床矿床地质特征及深部找矿方向预测[J]. 现在矿业, 2014(3):36-38. Wang Sihong, Yu Xiaojie, Ding Mingfei,et al. The Geological Characteristics and Deep Prospecting Direction Prediction of the Sizhuang Gold Deposit[J]. Modern Mining, 2014(3):36-38. [3] 杨之利, 姜洪利, 柳贡海, 等. 山东省莱州市寺庄矿区深部金矿详查报告[R]. 济南:山东省国土资源厅, 2006. Yang Zhili, Jiang Hongli, Liu Gonghai, et al. Deep-Space Detailed Survey Report of Sizhuang Gold Deposit in Laizhou, Shandong Province[R]. Jinan: Shandong Procincial Department of Land and Resources, 2006. [4] 杨之利, 张旭, 姜洪利. 山东省莱州市寺庄金矿床地质特征[J]. 山东国土资源, 2007, 23(5): 6-10. Yang Zhili, Zhang Xu, Jiang Hongli. Geological Characteristics of Sizhuang Gold Deposit in Laizhou City of Shandong Province[J].Shandong Land and Resources, 2007, 23(5):6-10. [5] 董金奎, 申延, 邱俊刚. 焦家金矿寺庄矿区岩体节理裂隙调查与矿岩稳定性分析[J]. 黄金科学技术, 2012, 20(2):58-61. Dong Jinkui, Shen Yan, Qiu Jungang. Investigation of Joint Fissure and Analysis of Ore-Rock Stability in Sizhuang Mining of Jiaojia Gold Deposit[J]. Gold Science and Technology, 2012, 20(2):58-61. [6] 崔书学, 袁文花, 杨之利. 莱州寺庄金矿床深部地质特征[J]. 西北地质, 2008, 41(4):82-92. Cui Shuxue, Yuan Wenhua, Yang Zhili. Geological Characteristics in the Deep of Sizhuang Gold Deposit in Laizhou City[J]. Northwestern Geology, 2008, 41(4): 82-92. [7] 崔书学, 袁文花. 莱州市寺庄金矿区第二金矿富集带成矿规律[J]. 地质调查与研究, 2008, 31(3): 186-191. Cui Shuxue, Yuan Wenhua. Ore-Forming Regularity of the Second Enrichment Zone of the Sizhuang Gold Deposit in Laizhou,Shandong Province[J]. Geological Survey and Reseach, 2008, 31(3):186-191. [8] 张晓飞, 孙爱群, 牛树银,等. 胶东焦家金矿田成矿构造及控矿作用分析[J].黄金科学技术, 2012,20(3):18-22. Zhang Xiaofei, Sun Aiqun, Niu Shuyin,et al. Analysis on the Mineralization Constrution and Ore-Controlling Role of Jiaojia Gold Ore Field Jiaojia Area[J]. Gold Science and Technology, 2012, 20(3): 18-22. [9] 张佳楠. 山东莱州焦家金矿床矿化富集规律及矿床成因探讨[D]. 长春:吉林大学, 2012. Zhang Jianan. Mineralization Enrichment Regularity and the Genesis Discussed of Jiaojia Gold Deposit, Shandong Province Laizhou[D]. Changchun: Jilin University, 2012. [10] Taylor H P. The Application of Oxygen and Hydrogen Isotope Studies to Problem of Hydrothermal Alteration and Ore Deposition[J]. Econ Geologic, 1974, 69(6):843-883. [11] Craig H, Lupton J E. Primordial Neon, Helium and Hydrogen in Oceanic Basalts[J]. Earth and Planetary Sciencce Letters, 1976, 31(3): 369-385. [12] 赵鹏沄, 顾雪祥, 邓小华. 山东焦家金矿成矿成因及成矿模式[J].地质与勘探, 2007,43(3):29-35. Zhao Pengyun, Gu Xuexiang, Deng Xiaohua. Gensis and Metallogenic Model of Jiaojia Gold Deposit, Shandong[J]. Geology and Prospecting, 2007,43(3):29-35. [13] 王力, 孙丰月, 王佳良. 山东金岭金矿床成矿流体地球化学特征[J]. 岩石学报, 2010, 26(12):3735-3744. Wang Li, Sun Fengyue, Wang Jialiang. Geochemical Features of Ore-Forming Fluids of the Jinling Gold Deposit, Shandong Province[J]. Acta Petrologica Sinica, 2010, 26(12):3735-3744. [14] 马芳, 孙丰月, 霍亮, 等. 山东焦家金矿煌斑岩特征及金矿化关系[J]. 世界地质, 2014, 33(2):388-398. Ma Fang, Sun Fengyue, Huo Liang,et al. Lamprophyre Characteristics and Their Relation to Gold Mineralization of Jiaojia Gold Deposit,Shandong[J]. Global Geology, 2014, 33(2):388-398. [15] 孙丰月, 石准立, 冯本智. 胶东金矿地质及幔源C-H-O流体分异成岩成矿[M]. 长春:吉林人民出版社,1995. Sun Fengyue, Shi Zhunli, Feng Benzhi. Gold Ore Geology,Lithogenesis and Metallogenesis Related to the Differentiation of Mantle-Derived C-H-O Fluids in Jiaodong Peninsula[M]. Changchun: Jilin People Press, 1995. [16] 卢焕章, 范宏瑞, 倪培,等. 流体包裹体[M].北京:科学出版社, 2004. Lu Huanzhang, Fan Hongrui, Ni Pei, et al. The Fluid Inclusion[M]. Beijing: Science Press, 2004. [17] Robert F, Kelly W C. Ore-Forming Fluids in Archean Gold-Bearing Quartz Vein at the Sigma Mine, Abitibi Greenstone Belt, Quebec Canada[J]. Economic Geology, 1987, 82: 1464-1482. [18] Tbrahim M S, Kyser T K. Fluid Inclusion and Isotope Systematics of the High-T Protozoic Star Lake Lode Gold Deposit, Transvaal, South Arica[J]. Eur J Mineral, 1991, 4: 933-948. [19] 王力, 潘忠翠, 孙丽伟. 山东莱州新城金矿床流体包裹体[J]. 吉林大学学报(地球科学版), 2014, 44(4):1166-1176. Wang Li, Pan Zhongcui, Sun Liwei. Fluid Inclusion of the Xincheng Gold Doposit of Laizhou City in Shandong Province[J]. Journal of Jilin University(Earth Science Edition), 2014,44(4):1166-1176. [20] Bozzo A T, Chen J R, Barduhn A J. The Properties of Hydrates of Chlorine and Carbon Dioxide[C]//Delyannis A, Delyannis E. Fourth International Symposium on Fresh Water the Sea, 1973: 437-451. [21] Potter R W, Clynne M A, Brown D L. Freezing Point Depression of Aqueous Sodium Chloride Solution[J]. Economic Geology, 1978, 73: 284-285. [22] 刘斌, 段光贤.NaCl-H2O溶液包裹体的密度式和等容式及其应用[J]. 矿物学报, 1987, 7(4):345-352. Liu Bin, Duan Guangxian. The Density and Isochoric Formulae for NaCl-H2O Fluid Inclusions(Salinity≤25wt%) and Their Applications[J]. Acta Mineralogical Sinica,1987,7(4):345-352. [23] Shepherd T J, RaKin A H, Alderton D H M. A Practical Guide to Fluid Inclusion Studies[M]. Glasgow & London: Blackie & Son Limited, 1985. [24] Roedder E, Bodnar R J. Geologic Pressure Deter-minations from Fluid Inclusion Studies[J]. Ann Rev Earth Planet Science, 1980, 8: 263-301. [25] 孙丰月, 金巍, 李碧乐, 等. 关于脉状热液金矿床成矿深度的思考[J]. 长春科技大学学报, 2000, 30(增刊): 27-30. Sun Fengyue, Jin Wei,Li Bile, et al. Considerations on the Mineralizing Depth of Hydrothermal Lode Gold Deposits[J]. Journal of Changchun University of Science and Technology, 2000,30(Sup.): 27-30. [26] 邵洁莲. 金矿找矿矿物学[M].北京:中国地质大学出版社,1990. Shao Jielian. Gold Prospecting Mineralogy[M]. Beijing:China University of Geosciences Press,1990. [27] 桂飞, 王力, 马芳. 三山岛金矿床流体包裹体研究[J]. 黄金地质, 2014, 35(11):27-32. Gui Fei, Wang Li, Ma Fang. Study on Fluid Inclusion in the Sanshandao Gold Deposit[J]. Gold Geology, 2014, 35(11):27-32. [28] 张理刚, 陈振胜, 刘敬秀, 等. 焦家式金矿水-岩交换作用:成矿流体氢氧同位素组成研究[J]. 矿床地质, 1994, 13(3):193-200. Zhang Ligang, Chen Zhensheng, Liu Jingxiu, et al. Water-Rock Exchange in the Jiaojia Type Gold Deposit: A Study of Hydrogen and Oxygen Isotopic Composition of Ore-Forming Fluids[J]. Mineral Deposits, 1994, 13(3):193-200. [29] 翟建平, 胡凯, 陆建军. 乳山金矿煌斑岩及流体和氢、氧、锶同位素研究[J]. 矿床地质, 1996, 15(4): 358-364. Zhai Jianping, Hu Kai, Lu Jianjun. Lamprophyres Ore-Forming Fluids and H, O, Sr Isotope Studies of the Rushan Gold Deposit[J]. Mineral Deposits, 1996, 15(4): 358-364. [30] 卢焕章, 袁万春, 张国平, 等. 玲珑-焦家地区主要金矿床稳定同位素及同位素年代学[J]. 桂林工学院学报, 1999, 19(1):1-8. Lu Huanzhang, Yuan Wangchun, Zhang Guoping, et al. Studies of Stable Isotopes and Isotopic Dating in the Major Gold Deposits: Linglong-Jiaojia Area[J]. Joumal of Guilin Institute of Technology, 1999, 19(1):1-8. [31] 刘连登, 姚凤良, 孔庆存, 等. 岩脉在热液矿床成因研究中的意义[J]. 长春地质学院学报, 1984,14(4): 13-28. Liu Liandeng, Yao Fengliang, Kong Qingcun,et al. The Significance About the Vein in Studying the Genesis of Hydrothermal Ore Deposits[J]. Journal of Changchun College of Geology, 1984,14(4): 13-28. [32] 黄德业. 胶东金矿成矿系列硫同位素研究[J]. 矿床地质, 1994, 13(1): 75-87. Huang Deye. Sulfur Isotope Studies of the Metaalogenic Series of Gold Deposits in Jiaodong (East Shandong) Area[J]. Mineral Deposits, 1994,13(1):75-87. [33] 姚凤良, 刘连登, 孔庆存, 等. 招掖金矿带稳定同位素地质及金矿床成因[J]. 长春地质学院学报, 1983,13(4):7-18. Yao Fengliang, Liu Liandeng, Kong Qingcun,et al. The Stability Isotopic Geology and the Origin of the Gold Deposit in the Zhaoyuan-Yexian Gold Belt,Shandong Province[J]. Journal of Changchun College of Geology, 1983,13(4): 7-18. [34] 李晓明. 山东三山岛金矿床氢氧碳稳定同位素研究及其应用[J]. 地质找矿论丛, 1988, 3(3): 62-71. Li Xiaoming. Study on H, O, C Stable Isotopes of Sanshandao Gold Deposit, Shandong Province and Their Application[J]. Journal of Geology and Exploration, 1988, 3(3): 62-71. [35] 陈光远, 邵伟, 孙岱生. 胶东金矿成因矿物学与找矿[M]. 重庆:重庆出版社,1989: 125-234. Chen Guangyuan, Shao Wei, Sun Daisheng. Genetic Mineralogy of Gold Deposit in Jiaodong Region with Emphasis on Gold Prospecting[M]. Chongqing: Chongqing Publising House, 1989: 125-234. [36] 毛景文, 赫英, 丁悌平.胶东金矿形成期间地幔流体参与成矿过程的碳氢氧同位素证据[J]. 矿床地质,2002, 21(2):121-128. Mao Jingwen,He Ying, Ding Tiping. Mantle Fluids Involved in Metallogenesis of Jiaodong(East Shandong)Gold District Evidence of C,O and H Isotopes Mineral Deposits[J]. Mineral Deposits, 2002, 21(2):121-128. [37] Mao Jingwen, Wang Yitian, Li Houmin, et al. There Lationship of Mantle-Derived Fluids to Gold Metallogenesis in the Jiaodong Peninsula: Evidence from D-O-C-S Isotope Systematics[J]. Ore Geology Reviews, 2008, 33: 361-381. [38] Fan Hongrui, Zhai Mingguo, Xie Yihan, et al. Ore-Forming Fluids Associated with Granite-Hosted Gold Mineralization at the Sanshandao Deposit, Jiaodong Gold Province, China[J]. Mineralium Deposits, 2003, 38: 739-750. [39] Yang Liqiang, Deng Jun, Zhang Jing,et al. Pre-liminary Studies of Fluid Inclusions in Damoqujia Gold Deposit Along Zhaoping Fault Zone,Shandong Province, China[J]. Acta Petrologica Sinica, 2007, 23(1):153-160. [40] 杨忠芳, 徐景奎, 赵伦山. 胶东区域地壳演化与金成矿作用地球化学[M]. 北京:地质出版社, 1998. Yang Zhongfang, Xu Jingkui, Zhao Lunshan. Crust Evolution and Geochemistry of Gold Deposits in Jiaodong[M]. Beijing: Geological Publishing House, 1998. [41] 徐金芳. 山东内生金矿矿床谱系及其致矿地质异常[J]. 山东地质, 2001, 17(2):32-36. Xu Jinfang. Spectrum of Endogenetic Gold Deposits and Its Ore-Generating Geological Anomalies in Shandong Province[J]. Shandong Geology, 2001, 17(2):32-36. [42] 王可勇, 姚书振, 吕新彪. 川西北马脑壳金矿床流体相分离作用及其成矿意义[J]. 地球学报, 2001, 22(1): 35-38. Wang Keyong, Yao Shuzhen, Lü Xinbiao. Phase Separation of Fluids in Manaoke Gold Deposit of Northwestern Sichuan and Its Mineralization Significance[J]. Acta Geoscientia Sinica, 2001, 22(1): 35-38. |
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