吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (5): 1378-1393.doi: 10.13278/j.cnki.jjuese.20170163

• 地质与资源 • 上一篇    下一篇

江西相山铀矿田含铀碎斑熔岩中电气石化学成分及硼同位素组成特征

戴加祺1, 黎广荣1,2, 郭福生1, 王超1, 王哲1, 张万良3, 于玉帅4   

  1. 1. 放射性地质与勘探技术国防重点学科实验室/东华理工大学地球科学学院, 南昌 330013;
    2. 内生金属矿床成矿机制研究国家重点实验室/南京大学地球科学与工程学院, 南京 210093;
    3. 核工业270研究所, 南昌 330200;
    4. 中国地质调查局武汉地质调查中心, 武汉 430205
  • 收稿日期:2017-12-06 发布日期:2018-11-20
  • 通讯作者: 黎广荣(1979-),男,讲师,主要从事构造地质学及矿物学方面的研究,E-mail:liguangrong0086@ecit.edu.cn E-mail:liguangrong0086@ecit.edu.cn
  • 作者简介:戴加祺(1993-),男,硕士研究生,主要从事地球化学、区域地质与铀成矿规律方面的研究,E-mail:137965365@qq.com
  • 基金资助:
    国家自然科学基金项目（41402028，41572185）；中国地质调查局项目（DD20160134，121201009000150007）

Chemical Components and Boron Isotopic Composition of Tourmaline of Uranium Bearing Porphyroclastic Lava in Xiangshan, Jiangxi

Dai Jiaqi1, Li Guangrong1,2, Guo Fusheng1, Wang Chao1, Wang Zhe1, Zhang Wanliang3, Yu Yushuai4   

  1. 1. Fundamental Science on Radioactive Geology and Exploration Technology Laboratory/School of Earth Sciences, East China University of Technology, Nanchang 330013, China;
    2. State Key Laboratory for Mineral Deposits Research/School of Earth Sciences and Engineering, Nanjing University, Nanjing 210093, China;
    3. Research Institute No. 270, CNNC, Nanchang 330200, China;
    4. Wuhan Center of China Geological Survey, Wuhan 430205, China
  • Received:2017-12-06 Published:2018-11-20
  • Supported by:
    Supported by the National Natural Science Foundation of China (41402028,41572185) and Project of China Geological Survey (DD20160134,121201009000150007)

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摘要： 相山铀矿田是我国最大的火山岩型铀矿田，其赋矿围岩主要为流纹英安岩、碎斑熔岩和部分前寒武纪变质岩和中生代花岗斑岩。碎斑熔岩的边缘亚相中发育直径10~20 cm的球形电气石囊包，其主要的矿物组合为电气石、石英以及少量长石、萤石，伴生少量晶质铀矿，另可见电气石交代早期的长石。利用显微镜、电子探针、激光剥蚀多接收等离子质谱仪等分析仪器，对相山如意亭地区碎斑熔岩中电气石囊包进行了详细的矿物学研究工作。电子探针成分分析显示，碎斑熔岩中电气石为典型的黑电气石，以富含Na、Fe等元素为特征，电气石中挥发性组分较高；其中，B2O3质量分数为9.38%~10.04%，F质量分数为0.10%~1.77%。成矿流体中高质量分数的B、F等挥发性组分及岩浆早期阶段的较高氧逸度环境使得U元素更易形成络合物，更利于U的迁移与富集。利用LA-MC-ICP-MS硼同位素微区原位分析法对碎斑熔岩中电气石的硼同位素进行分析测试，结果显示，电气石中的δ11 B质量分数为（-13.15±0.72）‰~（-12.28±0.63）‰，均值为（-12.72±0.94）‰，指示相山火山-侵入杂岩体主要来源于相山底部地壳基底岩石的部分熔融。

关键词: 硼同位素, 电气石, 碎斑熔岩, 相山铀矿田

Abstract: The Xiangshan uranium ore-field is the largest volcanic uranium ore-field in China, its ore-hosting rock is mainly of rhyodacite and porphyroclastic lava with a small amount of the Precambrian metamorphic rocks and Mesozoic granite porphyry. The porphyroclastic lava sub-facies yielde spherical tourmaline nodules with diameters of 10-20 cm, in which the main mineral assemblage is of tourmaline, quartz and minor feldspar, mixed with a small amount of uraninite. Tourmaline alterated early formed feldspar. A detailed mineralogical study for the tourmaline in porphyroclastic lava of the Ruyiting area in Xiangshan was performed by means of the microscope, electron probe, laser ablation multi-collector inductively coupled plasma mass spectrometry. The electron microprobe analysis shows that the tourmaline in porphyroclastic lava is the typical schorl characterized by the enrichment of Na, Fe. The volatile components are high in the tourmaline, of which the content of B2O3 is 9.38%-10.04%, and F is 0.10%-1.77%. The high volatile components such as B and F in ore-forming fluid with high oxygen fugacity in early stage of magma evolution made the U element more actively to form complex, which is more conducive to U migration and enrichment. The analysis of boron isotope in tourmaline from two porphyroclastic lava samples was performed by means of in-situ microanalysis of boron isotopes (LA-MC-ICP-MS). The results show that the content of δ11 B in tourmaline is (-13.15±0.72) ‰-(-12.28±0.63) ‰ with the mean value of (-12.72±0.94) ‰; which indicates that the Xiangshan volcano intrusive complex mainly comes from the partial melting of the Xiangshan crustal basement rocks.

Key words: boron isotope, tourmaline, porphyroclastic lava, Xiangshan uranium ore-field

中图分类号: 

  • P619.14
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