吉林大学学报(地球科学版) ›› 2017, Vol. 47 ›› Issue (3): 719-733.doi: 10.13278/j.cnki.jjuese.201703107

• 地质与资源 • 上一篇    下一篇

云南会泽矿山厂铅锌矿床流体包裹体特征及成矿物理化学条件

张艳1, 韩润生1, 魏平堂2, 邱文龙1   

  1. 1. 昆明理工大学国土资源工程学院/有色金属矿产地质调查中心西南地质调查所, 昆明 650093;
    2. 中国冶金地质总局昆明地质勘查院, 昆明 650024
  • 收稿日期:2016-11-13 出版日期:2017-05-26 发布日期:2017-05-26
  • 通讯作者: 韩润生(1964),男,研究员,博士生导师,主要从事流体地球化学及隐伏矿预测方面的研究,E-mail:554670042@qq.com E-mail:554670042@qq.com
  • 作者简介:张艳(1981-),女,在站博士后,主要从事矿产普查与勘探方面的研究,E-mail:78598874@qq.com
  • 基金资助:
    国家自然科学基金项目（U1133602，40863002，41572060）；云南省自然科学基金重点项目（2010CC005）；中国地质调查局典型矿集区潜力评价示范项目（2015）；国家危机矿山矿床成矿规律研究专项（20089943）；云南省矿产资源预测与评价重点工程实验室项目（2010）；云南省地质过程与矿床资源创新团队项目（2010）；昆明理工大学创新团队项目（2008）

Fluid Inclusion Features and Physicochemical Conditions of the Kuangshanchang Pb-Zn Deposit, Huize, Yunnan Province

Zhang Yan1, Han Runsheng1, Wei Pingtang2, Qiu Wenlong1   

  1. 1. Faculty of Land and Resource Engineering, Kunming University of Science and Technology/Southwest Institute of Geological Survey, Geological Survey Center for Non-Ferrous Mineral Resources, Kunming 650093, China;
    2. Kunming Geological Prospecting Institute, China Metallurgical Geological Bureau, Kunming 650024, China
  • Received:2016-11-13 Online:2017-05-26 Published:2017-05-26
  • Supported by:
    Supported by the National Natural Science Foundation of China (U1133602, 40863002, 41572060), Main Program for the Natural Science Foundation of Yunnan Province (2010CC005), Demonstration Project of Potential Evaluation of Typical Concentration Area of China Geological Survey (2015), Special Exploration Program for National Crisis Mines (20089943), Project of Key Laboratory of Mineral Resources Prediction and Evaluation of Yunnan Province (2010),Project of Innovation Team of Geological Processes and Mineral Resources of Yunnan Province (2010) and Project of Innovation Team of Kunming University of Science and Technology (2008)

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摘要： 通过会泽矿山厂铅锌矿床闪锌矿流体包裹体显微测温和成矿物理化学条件参数计算，结合前人研究结果，得出以下认识：会泽矿山厂铅锌矿床闪锌矿流体包裹体均一温度为126~280 ℃，具有较宽的变化区间，盐度（w（NaCl））为3.2%~22.8%； 白云石流体包裹体均一温度为86~163 ℃，大部分盐度较低，为1.1%~14.8%。3个成矿阶段闪锌矿和白云石中流体包裹体均一温度和盐度具有较明显的分布特征：从热液成矿期I阶段→Ⅱ阶段→Ⅲ阶段→围岩蚀变，流体呈现中高温-高盐度→中温-中高盐度→中低温-中高盐度→中低温-低盐度的演化规律。在整个热液成矿过程中，有两种不同盐度的流体参与了作用，流体混合可能是矿物沉淀的主要机制。pH值计算结果表明，迁移阶段时，成矿流体呈酸性，从成矿阶段I—IV，流体pH逐渐增大，主成矿阶段II—III时，闪锌矿和方铅矿在中性、弱碱性下大量析出。受控于CO、CO2、O2间逸度平衡的CO2-3和HCO-3缓冲对调节了成矿流体的pH值，碳酸盐岩在铅锌的运移沉淀中起了至关重要的作用。

关键词: 闪锌矿流体包裹体, 物理化学条件, 成矿流体, 会泽矿山厂铅锌矿床, 滇东北矿集区

Abstract: Systematic researches on fluid inclusions in the sphalerite and calculation of the ore-forming physicochemical conditions, combining with previous research results, lead to the conclusions that the homogenization temperature of fluid inclusions in the sphalerite grains from the Kuangshanchang lead-zinc deposit vary from 131 to 280 ℃, with a greater change range, the salinity(w(NaCl)) between 3.2% and 22.7 %. The homogenization temperatures of fluid inclusions in the dolomite vary from 86 to 163 ℃, the salinity of most fluid inclusions vary from 1.1% to 14.8 %. There are obvious regular characteristics of homogenization temperature and salinity of fluid inclusions in the sphalerite precipitated in three metallogenic stages and the dolomite. Namely, from the hydrothermal mineralization stage I, stage Ⅱ, stage Ⅲ to the altered wall rock, the ore-forming fluid is characterized by high-moderate temperature and high salinity, moderate temperature and high-moderate salinity, moderate-low temperature and high-moderate salinity, as well as moderate-low temperature and low salinity. Moreover, there are two kinds of fluids with different salinity participating in the hydrothermal ore-forming process. The mixing of the fluids is likely to be the major mineralization mechanism. The calculated pH values show that ore-forming fluid is acidic in migration stage, whereas, from metallogenic stage I to IV, the pH value of the fluid increases gradually. In major metallogenic stage, II and III, a large number of sphalerite and galena minerals precipitated under neutral-weak alkaline condition. CO2-3 and HCO-3 buffer pair, which is controlled by the fugacity balance among CO, CO2, O2, adjusts the pH value of the ore-forming fluid. The carbonate plays a vital role in migration and precipitation of metallogenic elements of the lead and zinc.

Key words: fluid inclusion in sphalerite, physicochemical conditions, ore-forming fluid, Kuangshanchang lead-zinc deposit in Huize, northeastern Yunnan ore concentration area

中图分类号: 

  • P57
[1] 戴自希.世界铅锌资源的分布、类型和勘查准则[J].世界有色金属, 2005 (3): 15-23. Dai Zixi. The Distributions, Types and Rules of Exploration of Lead and Zinc all over the World [J]. World Nonferrous Metals, 2005 (3): 15-23.
[2] 韩润生,王峰,胡煜昭,等.会泽型(HZT)富锗银铅锌矿床成矿构造动力学研究及年代学约束[J]. 大地构造与成矿学, 2014, 38(4): 758-771. Han Runsheng, Wang Feng, Hu Yuzhao, et al. Metallogenic Tectonic Dynamics and Chronology Constrains on the Huize-Type(HZT) Germanium-Rich Silver-Zinc-Lead Deposits [J]. Geotectonic et Metallogenia, 2014,38(4): 758-771.
[3] 谢家荣. 论矿床的分类[M]. 北京: 科学出版社, 1963. Xie Jiarong. A Discussion on the Deposits Classify [M]. Beijing: Science Press, 1963.
[4] 张位及.试论滇东北铅锌矿床的沉积成因和成矿规律[J]. 地质与勘探, 1984 (7): 11-16. Zhang Weiji. A Preliminary Discussion on the Sedimentary Origin and Metallogenic Rule of Pb-Zn Deposits in Northeastern Yunnan [J]. Geology and Exploration, 1984 (7): 11-16.
[5] 涂光炽. 中国层控矿床地球化学 [M]. 北京: 科学出版社, 1984: 13-69. Tu Guangchi. Geochemical of Strata Bound Ore Deposits in China [M]. Beijing: Science Press, 1984:13-69.
[6] 廖文.滇东黔西铅锌金属区硫铅同位素组成特征与成矿模式探讨[J]. 地质·矿床, 1984 (1): 1-6. Liao Wen. The Features of S and Pb Isotope and the Discussion on Model of Metallogenic in Eastern of Yunnan and Western of Guizhou [J]. Geology·Deposit, 1984 (1): 1-6.
[7] 周朝宪.滇东北麟麒厂锌铅矿床成矿金属来源、成矿流体特征和成矿机理研究[D]. 贵阳:中国科学院地球化学研究所,1996. Zhou Chaoxian. The Source of Mineralizing Metals, Geochemical Characterization of Ore Forming Solution, and Metallogenetic Mechanism of Qilingchang Pb-Zn Deposit, Northeastern Yunnan Province, China [D]. Guiyang: Institute of Geochemistry Chinese Academy of Sciences, 1996.
[8] 周朝宪. 滇东北麟麒厂锌铅矿床成矿金属来源, 成矿流体特征和成矿机理研究[J]. 矿物岩石地球化学通报, 1998, 17(1): 34-36. Zhou Chaoxian. The Source of Mineralizing Metals, Geochemical Characterization of Ore-Forming Solution, and Metallogenetic Mechanism of Qilingchang Pb-Zn Deposit, Northeastern Yunnan Province, China [J]. Bulletin of Mineralogy, Petrology and Geochemistry, 1998, 17(1): 34-36.
[9] Zhou Chaoxian, Wei Chunsheng, Guo Jicun, et al. The Source of Metals in the Qilingchang Pb-Zn Deposit, Northeastern Yunnan, China: Pb-Sr Isotope Constraints[J]. Econ Geol, 2011, 96: 583-598.
[10] Huang Zhilong, Li Wenbo, Chen Jin, et al. C and O Isotope Constraints on the Mantle Fluids Join the Mineralization of the Huize Super-Large Pb-Zn Deposits, Yunnan Province, China [J]. Geochem Explor,2003, 78: 637-642.
[11] 黄智龙,陈进,韩润生,等.云南会泽超大型铅锌矿床地球化学及成因:兼论峨眉山玄武岩与铅锌成矿的关系[M]. 北京: 地质出版社, 2004: 1-187. Huang Zhilong, Chen Jin, Han Runsheng, et al. Geochemistry and Ore Gensis of Huize Super-Large Lead-Zinc Deposit, Yunnan Province, Concurrently Discuss the Relationship Between Emeishan Basalt and Lead-Zinc Deposits[M]. Beijing: Geological Publishing House, 2004:1-187.
[12] 李文博,黄智龙,王银喜.会泽超大型铅锌矿田方解石Sm-Nd等时线年龄及其地质意义[J]. 地质论评, 2004, 50(2) : 189-195. Li Wenbo, Huang Zhilong, Wang Yinxi. Age of the Giant Huize Zn-Pb Deposits Determined by Sm-Nd Dating of Hydrothermal Calcite [J]. Georgica Review, 2004, 50(2) : 189-195.
[13] 李文博, 黄智龙, 张冠.云南会泽铅锌矿田成矿物质来源: Pb、S、C、H、O、Sr同位素制约[J]. 岩石学报, 2006, 22(10): 2567-2580. Li Wenbo, Huang Zhilong, Zhang Guan. Sources of the Ore of the Huize Ore Field in Yunnan Province: Constraints from Pb, S, C, H, O and Sr Isotope Geochemistry [J]. Acta Petrologica, 2006, 22(10): 2567-2580.
[14] 张志斌, 李朝阳, 涂光炽, 等. 川、滇、黔接壤地区铅锌矿床产出的大地构造演化背景及成矿作用[J]. 大地构造与成矿学, 2006, 30(3): 343-354. Zhang Zhibin, Li Chaoyang, Tu Guangchi, et al. Geotectonic Evolution Background and Ore-Forming Process of Pb-Zn Deposits in Chuan-Dian-Qian Area of Southwest China[J]. Geotectonica et Metallogenia, 2006, 30(3): 343-354.
[15] 韩润生, 邹海俊, 胡彬, 等. 云南毛坪铅锌(银、锗)矿床流体包裹体特征及成矿流体来源[J]. 岩石学报, 2007, 23(9): 2109-2118. Han Runsheng, Zou Haijun, Hu Bin, et al. Features of Fluid Inclusions and Sources of Ore-Forming Fluid in the Maoping Carbonate-Hosted Zn-Pb-(Ag-Ge) Deposit, Yunnan, China[J]. Acta Petrological Sinica, 2007, 23(9):2109-2118.
[16] Han R S, Liu C Q,Huang Z L. Sources of Ore-Forming Fluid in Huize Zn-Pb-(Ag-Ge) District, Yunnan, China [J]. Acta Geologica Sinica, 2004, 78(2): 583-591.
[17] Han R S, Liu C Q, Emmanuel J M C, et al. REE Geochemistry of Altered Tectonites in the Huize Base-Metal District, Yunnan, China [J]. Geochemistry: Exploration, Environment, Analysis, 2012, 12: 127-146.
[18] 张振亮, 黄智龙, 饶冰, 等. 会泽铅锌矿床成矿流体研究[J]. 地质找矿论丛, 2005, 20(2):115-121. Zhang Zhenliang, Huang Zhilong, Rao Bing, et al. Study on the Ore Forming Fluid Characteristics of Huize Pb-Zn Ore Deposits [J]. Geological Prospecting Review, 2005, 20(2): 115-121.
[19] 李波.滇东北地区会泽、松梁铅锌矿床流体地球化学与构造地球化学研究[D]. 昆明:昆明理工大学,2010. Li Bo. The Study of Fluid Inclusions Geochemistry and Tectonic Geochemistry of Lead-Zinc Deposits: Taking Huize and Songliang Lead-Zinc Deposits for Examples, in the Northeast of Yunnan Province, China [D]. Kunming: Kunming University of Science and Technology,2010.
[20] 韩润生, 刘丛强, 黄智龙, 等.论云南会泽富铅锌矿床成矿模式[J]. 矿物学报, 2001, 21(4): 674-680. Han Runsheng, Liu Congqiang, Huang Zhilong, et al. Study on the Metallogenic Model of the Huize Pb-Zn Deposit in Yunnan Province [J]. Acta Mineralogica Sinica, 2001, 21(4), 674-680.
[21] Han Runsheng, Li Wenchang, Qiu Wenlong. Typical Geological Features of Rich Zn-Pb-(Ge-Ag) Deposits in Northeastern Yunnan, China [J]. Acta Geological Sinica, 2014, 88(Sup.2): 160-162.
[22] 韩润生,陈进,黄智龙,等.构造成矿动力学及隐伏矿定位预测:以云南会泽铅锌(银、锗)矿床为例[M]. 北京: 科学出版社, 2006:1-200. Han Runsheng, Chen Jin, Huang Zhilong, et al. Dynamics of Tectonic Ore-Forming Process and Localization-Prognosis of Concealed Orebodies:As Exemplified by the Huize Surper-Large Zn-Pb-(Ag-Ge) District, Yunnan[M]. Beijing: Science Press, 2006: 1-200.
[23] 陈世杰. 黔西滇东北铅锌矿床的沉积成因探讨[J]. 贵州地质, 1984, 8(3): 56-62. Chen Shijie. A Discussion on the Sedimentary Origin of Pb-Zn Deposits in Western Guizhou and Northeastern Yunnan [J]. Guizhou Geology, 1984, 8(3): 56-62.
[24] 赵准. 滇东、滇东北地区铅锌矿床的成矿模式[J]. 云南地质, 1985, 14(4):350-354. Zhao Zhun. Metallogenic Model of Pb-Zn Deposits in Eastern and Northeastern Yunnan [J]. Yunnan Geology, 1985, 14(4):350-354.
[25] 柳贺昌, 林文达. 滇东北铅锌银矿床规律研究[M]. 昆明: 云南大学出版社, 1999. Liu Hechang, Lin Wenda. Metallogenic Rules of Zn-Pb-(Ag) Deposits in Northeastern Yunnan [M]. Kunming: Yunnan University Publishing House, 1999.
[26] 陈进. 麒麟厂铅锌硫化物矿床成因及成矿模式探讨[J]. 有色金属矿产与勘查, 1993 (2): 85-90. Chen Jin. A Discussion on the Genesis and Metallogenic Model of the Qilinchang Pb-Zn Sulfide Deposit [J]. Non-Ferrous Mineral Resources and Exploration, 1993 (2): 85-90.
[27] 张长青. 中国川滇黔交界地区密西西比型铅锌矿床成矿模型[D]. 北京:中国地质科学院, 2008:1-159. Zhang Changqing. The Genetic Model of Mississippi Valley-Type Deposits in the Boundary Area of Sichuan, Yunnan and Guizhou Provinces, China [D]. Beijing: Chinese Academy of Geological Sciences, 2008:1-159.
[28] 高德荣. 会泽铅锌矿床成矿地质条件及找矿方向[J]. 昆明理工大学学报, 2000, 25(4): 19-24. Gao Derong. The Ore -Forming Geological Condition and the Ore Prospecting Direction of Huize Lead Zinc Deposit [J]. Journal of Kunming University of Science and Technology, 2000, 25(4): 19-24.
[29] 陈进, 高德荣, 吴代城, 等. 云南省会泽县麒麟厂矿区八号锌铅矿体地质勘探报告[R]. 会泽: 会泽铅锌矿, 2001. Chen Jin, Gao Derong, Wu Daicheng, et al. The Report of the Geology Exploration of 8# Ore Body in Qilinchang Pb-Zn Deposit, Huize, Yunnan[R]. Huize: Huize Lead-Zinc Deposit, 2001.
[30] 韩润生, 胡煜昭, 王学琨, 等. 滇东北富锗银铅锌多金属矿集区矿床模型[J]. 地质学报, 2012, 86(2): 280-294. Han Runsheng, Hu Yuzhao, Wang Xuekun, et al. Mineralization Model of Rich Ge-Ag-Bearing Zn-Pb Polymetallic Deposit Concentrated District in Northeastern Yunnan, China[J]. Acta Geologica Sinica, 2012, 86(2): 280-294.
[31] Han R S, Liu C Q,Huang Z L. Geological Features and Origin of the Huize Carbonate-Hosted Zn-Pb-(Ag) District, Yunnan [J]. Ore Geology Reviews, 2007, 31: 360-383.
[32] 张长青, 毛景文, 吴锁平, 等. 川滇黔地区MVT铅锌矿床分布、特征及成因[J]. 矿床地质, 2005, 24(3): 336-348. Zhang Changqing, Mao Jingwen, Wu Suoping, et al. Distribution, Characteristics and Genesis of Mississippi Valley-Type Lead-Zinc Deposits in Sichuan-Yunnan-Guizhou Area[J]. Mineral Deposits, 2005, 24(3): 336-348.
[33] 张长青, 芮宗瑶, 陈毓川, 等.中国铅锌矿资源潜力和主要战略接续区[J]. 中国地质, 2013, 40(1): 248-272. Zhang Changqing, Rui Zongyao, Chen Yuchuan, et al. The Main Successive Strategic Bases of Resources for Pb-Zn Deposits in China [J]. Geology in China, 2013, 40(1): 248-272.
[34] 唐忠, 李文昌, 王长兵, 等. 滇东北Pb-Zn-(Ag) 多金属矿床找矿突破关键基础地质问题[J]. 吉林大学学报(地球科学版), 2016, 46(3): 722-735. Tang Zhong, Li Wenchang, Wang Changbing, et al. Critical Geological Issues About Ore-Prospecting Breakthrough of Pb-Zn-(Ag) Polymetallic Deposit in Northeast Yunnan[J]. Journal of Jilin University (Earth Science Edition), 2016, 46(3): 722-735.
[35] 陈大. 扬子地台西缘铅锌矿床分布规律及矿源层探讨[J]. 吉林大学学报(地球科学版), 2016, 46(5): 1365-1383. Chen Da. Space-Time Distribution, Source Bed and Stratabound Mechanisms of Zn-Pb Deposits in Western Margin of Yangtze Platform [J]. Journal of Jilin University (Earth Science Edition), 2016, 46(5): 1365-1383.
[36] 王奖臻, 李朝阳, 李泽琴, 等. 川滇地区密西西比河谷型铅锌矿床成矿地质背景及成因探讨[J]. 地质地球化学, 2001, 29(2): 41-45. Wang Jiangzhen, Li Chaoyang, Li Zeqin,et al. The Geological Setting, Characters and Origin of Mississippi Valley-Type Pb-Zn Deposits in Sichuan and Yunnan Provinces[J]. Geology-Geochemistry, 2001, 29(2):41-45.
[37] 王奖臻, 李朝阳, 李泽琴, 等. 川、滇、黔交界地区密西西比河谷型铅锌矿床与美国同类型矿床的对比[J]. 矿物岩石地球化学通报, 2002, 21(2):127-132. Wang Jiangzhen, Li Chaoyang, Li Zeqin,et al. The Comparison of Mississippi Valley-Type Lead-Zinc Deposits in Southwest of China and in Mid-Continent of United States [J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2002, 21(2): 127-132.
[38] 涂光炽.我国西南地区两个别具一格的成矿带(域) [J]. 矿物岩石地球化学通报, 2002, 21(1): 1-2. Tu Guangchi. Two Unique Mineralization Areas in Southwest China [J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2002, 21(1): 1-2.
[39] 韩润生,李波,倪培,等.闪锌矿流体包裹体显微红外测温及其矿床成因意义: 以云南会泽超大型富锗银铅锌矿床为例[J].吉林大学学报(地球科学版), 2016, 46(1): 91-104. Han Runsheng, Li Bo, Ni Pei, et al. Infrared Micro-Thermometry of Fluid Inclusions in Sphalerite and Geological Significance of the Huize Super-Large Zn-Pb-(Ge-Ag) Deposit, Yunnan Province[J]. Journal of Jilin University(Earth Science Edition), 2016, 46(1): 91-104.
[40] 张德会. 成矿流体中金属沉淀机制研究综述[J].地质科技情报,1997, 16(3):53-58. Zhang Dehui. Overview of Research on the Ore Depositional Mechanisms in Ore Forming Fluid [J]. Geological Science and Technology Information, 1997, 16(3):53-58.
[41] 蒋少涌, 丁梯平, 万德芳, 等. 东胜铅锌矿床流体包裹体和稳定同位素地球化学研究[J]. 辽宁地质, 1991 (l): 43-54. Jiang Shaoyong, Ding Tiping, Wan Defang, et al. The Fluid Inclusion and Stable Isotope Geochemistry of Dongsheng Lead-Zinc Deposit, Liaoning Province, China [J]. Liaoning Geology, 1991 (l): 43-54.
[42] 温春齐, 蔡建明, 刘文固, 等. 金顶铅锌矿床流体包裹体地球化学特征[J]. 矿物岩石, 1995, 15(4): 78-84. Wen Chunqi, Cai Jianming, Liu Wengu, et al. Geochemical Characteristics of Fluid Inclusions in the Jinding Lead-Zinc Deposit, Yunnan, China [J]. Minerals and Rocks,1995, 15(4):78-84.
[43] 杨斌, 李骏青. 广西东桃铅锌矿床喷流-沉积地球化学特征[J]. 矿产与地质, 2000, 14(5): 333-336. Yang Bin, Li Junqing. Exhalative-Sedimentary Geochemical Features of Guangxi Dongtao Lead-Zinc Deposit [J]. Mineral Resources and Geology, 2000, 14(5): 333-336.
[44] 刘文均, 郑荣才. 花垣铅锌矿床成矿流体特征及动态[J]. 矿床地质, 2000, 19(2): 173-181. Liu Wenjun, Zheng Rongcai. Characteristics and Movement of Ore-Forming Fluids in the Huayuan Lead-Zinc Deposit [J]. Mineral Deposit, 2000, 19(2): 173-181.
[45] 叶水泉, 曾正海. 南京栖霞山铅锌矿床流体包裹体研究[J]. 火山地质与矿产, 2000, 21(4): 266-274. Ye Shuiquan, Zeng Zhenghai. A Study on Fluid Inclusions in Qixiashan Lead and Zinc Ore Deposit, Nanjing [J]. Volcanology & Mineral Resources, 2000, 21(4): 266-274.
[46] 张术根, 周建普, 黄满湘, 等. 广东凡口铅锌(银)矿床成矿流体来源研究[J]. 矿产与地质, 2002, 16(4): 199-202. Zhang Shugen, Zhou Jianpu, Huang Manxiang, et al. The Origin of Ore-Forming Fluid of Fankou Pb、Zn(Ag) Deposit, Guangdong[J]. Mineral Resources and Geology, 2002, 16(4): 199-202.
[47] 卢焕章, 范宏瑞, 倪培, 等. 流体包裹体[M]. 北京: 科学出版社, 2004. Lu Huanzhang, Fan Hongrui, Ni Pei, et al. Fluid Inclusions [M]. Beijing: Science Press, 2004.
[48] Roedder E. Fluid Inclusion[J]. Mineralogy, 1984, 12: 337-359, 413-471.
[49] 王天刚, 倪培, 王国光, 等. 甘肃厂坝铅锌矿富甲烷流体包裹体的发现及其意义[J]. 岩石学报, 2008, 24(9): 2105-2112. Wang Tiangang, Ni Pei, Wang Guoguang, et al. Identification and Significance of Methane-Rich Fluid Inclusions in Changba Pb-Zn Deposit, Gansu Province [J]. Acta Petrologica Sinica, 2008, 24(9): 2105-2112.
[50] Bodnar R J.A Method of Calculating Fluid Inclusion Volumes Based on Vapor Bubble Diameters and PVTX Properties of Inclusion Fluids. [J]. Econ Geol,1983, 78: 535-542.
[51] 刘斌, 沈昆. 流体包裹体热力学[M]. 北京: 地质出版社, 1999. Liu Bin, Shen Kun. Thermodynamics of the Fluid Inclusion [M]. Beijing: Geology Press, 1999.
[52] 柳贺昌. 滇川黔成矿区的铅锌矿源层(岩) [J]. 地质与勘探, 1996, 32(2): 12-18. Liu Hechang. Pb-Zn Source Beds (Rocks) of Dian-Chuan-Qian Metallogenic Region [J]. Geology and Exploration, 1996, 32(2): 12-18.
[53] 张文淮, 陈紫英. 流体包裹体地质学[M]. 武汉:中国地质大学出版社,1993: 123-154. Zhang Wenhuai, Chen Ziying. Geology of the Fluid Inclusion [M]. Wuhan: China University of Geosciences Press, 1993: 123-154.
[54] 张振亮. 云南会泽铅锌矿床成矿流体性质和来源:来自流体包裹体和水岩反应实验的证据[D].贵阳: 中国科学院地球化学研究所, 2006:1-128. Zhang Zhenliang. Feature and Sources of Ore-Forming Fluid in the Huize Lead-Zinc Ore Deposit, Yunnan Province, China: Evidence from Fluid Inclusions and Water-Rock Reaction Experiments[D]. Guiyang: Institute of Geochemistry Chinese Academy of Sciences, 2006:1-128.
[55] 杨书桐. 黄铁矿的环带结构与金矿源的关系:以皖南东至金矿化区为例[J]. 地质找矿论丛, 1993, 8(2): 53-60. Yang Shutong. Implication of the Zonal Texture of Gold-Bearing Pyrites on Gold Source:An Example from Dongzhi Gold Metallogenic Field, Southern Anhui [J]. Geology and Exploration Review, 1993, 8(2): 53-60.
[56] 刘铁庚, 裘愉卓, 叶霖. 闪锌矿的颜色、成分和硫同位素之间的密切关系[J]. 矿物学报, 1994, 14(2): 199-205. Liu Tiegeng, Qiu Yuzhuo, Ye Lin. Relationship Between Color, Chemical Composition and Sulfur Isotopic Composition of Sphalerite [J]. Atca Mineralogical Sinca, 1994, 14(2): 199-205.
[57] 崔天顺, 齐金钟. 山东界河金矿黄铁矿环带及导型结构的研究[J]. 矿物学报, 1995, 15(4): 398-403. Cui Tianshun, Qi Jinzhong. A Study on the Zonation and Structure of Conduct-Types in Pyrite from the Jiehe Gold Deposit, Shandong Province [J]. Atca Mineralogical Sinca, 1995, 15(4): 398-403.
[58] 马建秦, 李朝阳, 张复新. 秦岭煎茶岭金矿床含金富砷黄铁矿增生环带研究[J]. 矿物学报, 1999, 19(2): 139-147. Ma Jianqin, Li Chaoyang, Zhang Fuxin. The Status Quo of Research on the Occurrence of Invisible Gold [J]. Atca Mineralogical Sinca, 1999, 19(2):139-147.
[59] 刘斌. 简单体系水溶液包裹体pH和Eh的计算[J].岩石学报, 2011,21(5): 1533-1542. Liu Bin. Calculation of pH and Eh for Aqueous Inclusions Simple System [J]. Acta Petrologica Sinca, 2011,21(5): 1533-1542.
[60] Reed M H, Palandri J. Sulfide Mineral Precipitation from Hydrothermal Fluids[J]. Reviews in Mineralogy & Geochemistry, 2006, 61: 609-631.
[61] 张艳, 韩润生, 魏平堂, 等.云南昭通铅锌矿pH-logfO2和pH-loga相图对铅锌共生分异的制约[J]. 中国地质, 2015,42(2): 607-620. Zhang Yan, Han Runsheng, Wei Pingtang, et al. pH-logfo2 and pH-loga for Pb-Zn Paragenesis and Separation in the Zhaotong Lead-Zinc Deposit [J]. Geology in China, 2015, 42(2): 607-620.
[62] 徐文炘. 矿物包裹体中水溶气体成分的物理化学参数图解[J]. 矿产与地质, 1991, 5(22): 200-207. Xu Wenxin. Figures of Physicochemical Parameter of Water-Soluble Gas Composition in Inclusions of Minerals [J]. Mineral Resources and Geology, 1991, 5(22): 200-207.
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