吉林大学学报(地球科学版) ›› 2018, Vol. 48 ›› Issue (1): 234-240.doi: 10.13278/j.cnki.jjuese.20160339
董军, 徐暖, 刘同喆, 管锐, 邓俊巍
Dong Jun, Xu Nuan, Liu Tongzhe, Guan Rui, Deng Junwei
摘要: 以天然细砂为微生物来源,模拟研究了乳化植物油强化原位生物修复中高浓度Cr(Ⅵ)污染地下水的可行性,考察了修复效果及修复过程中地下水质变化及产物的稳定性。结果表明,反应77 d后,Cr(Ⅵ)质量浓度分别从20.0、30.0、50.0、80.0、110.0 mg/L降低到0.0、5.8、19.0、43.6、65.8 mg/L,去除率分别为100.0%、80.7%、61.9%、45.5%、40.2%。反应后介质中Cr形态分析表明,其主要以能在自然条件下稳定存在的铁锰结合态和有机结合态形式存在。此外,随反应进行,实验体系逐渐呈弱酸性环境,pH为5.80~6.70。当Cr被完全还原后,体系会发生异化铁还原,Fe(Ⅱ)质量浓度逐渐升高,最高可达117.0 mg/L,最终形成二价铁矿物。综上所述,天然细砂介质中的土著微生物能够利用乳化植物油强化并还原地下水中的中、高浓度Cr(Ⅵ),且产物能够在自然状态下稳定存在,修复过程对地下环境的影响较小。
中图分类号:
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