Journal of Jilin University(Earth Science Edition) ›› 2016, Vol. 46 ›› Issue (4): 1191-1198.doi: 10.13278/j.cnki.jjuese.201604205

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Treatment Research of Polyvinyl Alcohol Wastewater by Ozone/Ultrasound Oxidation Process

Dong Deming, Cao Zhen, Yan Zhengchu, Hua Xiuyi, Zhu Lei, Xu Yang, Guo Zhiyong, Liang Dapeng   

  1. Key Laboratory of Groundwater Resource and Environment of Ministry of Education/Key Laboratory of WaterResource and Aquatic Environment of Jilin Province/College of Environment and Resource, Jilin University, Changchun 130012, China
  • Received:2016-02-27 Online:2016-07-26 Published:2016-07-26
  • Supported by:

    Supported by the Major Science and Technology Program for Water Pollution Control and Treatment in China (2012ZX07202-009)and the Science and Technique Plan Key Project of Jilin Province (20140204035SF)

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Abstract:

The present work investigates the treatment of polyvinyl alcohol (PVA) wastewater by using ozone/ultrasound(US) oxidation process. The effects of initial PVA mass concentration, the flow rate of ozone, initial pH, ultrasonic power, ultrasonic frequency, and raction time have been studied. The optimal treatment conditions for PVA and COD removal were obtained using orthogonal experiments. The results showed that ultrasonic frequency has a remarkable influence on the removal efficiency,the initial PVA mass concentration plays an important role, while reaction time, ultrasonic power, the flow rate of ozone and initial pH have minor effects in order. The maximum removal of COD and PVA could be reached under the following conditions: initial PVA mass concentration was 100 mg/L, initial pH was 9, ozone dosage was 4 g/h, ultrasonic power was 320 W, ultrasonic frequency was 40 kHz, and the reaction time was 20 minutes. Under these conditions,the removal efficiency of COD and PVA was 86.4% and 99.3%,respectively. Compared O3 with O3/US, different types of technology were operated at the same final condition to show the difference between them, the PVA removal efficiency of O3/US was 5.1% higher than O3, the COD removal efficiency of O3/US was 19.4% higher than that with the treatment of only O3 under the same optimal conditions.

Key words: ozone, ultrasound, polyvinyl alcohol wastewater, effect factors, degradation

CLC Number: 

  • X131.2

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