Journal of Jilin University(Earth Science Edition) ›› 2017, Vol. 47 ›› Issue (2): 464-476.doi: 10.13278/j.cnki.jjuese.201702112

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Preliminary Study on Special Mineralization Environments of Niujiaotang Cadmium Ore Deposit

Gu Tuan   

  1. Research and Exploration Institute of Liaohe Oilfield Company, PetroChina, Panjin 124010, Liaoning, China
  • Received:2016-10-25 Online:2017-03-26 Published:2017-03-26
  • Supported by:
    Supported by National Natural Science Foundation of China(49633110)

Abstract: The cadmium contents in Niujiaotang associated cadmium ore deposit is five to six orders of magnitude higher than the Clark value, over ten times to near hundred times higher than the industrial grade. In the Qingxudong period of Early Cambrian, the Niujiaotang area was located in the shoal facies of platform margin, which had a set of algal domal in the upper part of the Qingxudong Formation. The dolomite which had algae, algal pellets, oncolites and bioclastic dolomite is the major ore-bearing rock of the Niujiaotang deposit. Ore bodies consistent with surrounding rock are generally stratoid, lenticular and vein-like. The distribution of cadmium ore bodies is jointly controlled by strome algal complex and lithofacies, and obviously controlled by of the strata, lithic facies and rock type. The algal domal formation may also provide partial ore source for mineralization. Abnormal enrichment and mineralization of cadmium have certain relationship with the evolution of the Majiang paleo oil reservoir. Firstly, the metallogenic epoch of Niujiaotang deposit is middle to Late Caledonian, from 433 to 510 Ma, which is the active period of Majiang ancient oil and gas reservoir. The early stage of evolution is roughly coincident with the mineralization of Niujiaotang cadmium ore depsoit, and the reservoir should be slightly earlier than the mineralization. The mineralization was accompanied by the ancient reservoir under the condition of liquid hydrocarbon, and continued until the reservoir was destroyed. Secondly, the fluid in the Majiang paleo reservoir had provided reductive ore-forming fluid and partial sulfur source. The research results in this paper demonstrate that both paleogeographic environment and paleo reservoir condition had played an important role in the cadmium concentration and mineralization.

Key words: mineralization environments, paleogeographic environment, Majiang paleo-oil reservoir, Niujiaotang cadmium ore deposit

CLC Number: 

  • P618.81
[1] 陈代演. 我国汞铊共生矿床中富铊矿体首次发现及其成因初步研究[J]. 贵州工学院学报, 1989, 18(2):1-19. Chen Daiyan. A Preliminary Study on the First Discovery of Mercury Thallium Deposit Rich Thallium Ore in China[J]. Journal of Guizhou University of Technology, 1989, 18(2):1-19.
[2] 骆耀南, 曹志敏. 四川发现世界首例独立碲矿床[J]. 中国地质,1994,21(2):27-29. Luo Yaonan, Cao Zhimin. The World's First Independent Tellurium Deposit in Sichuan,China[J]. Geology in China,1994,21(2):27-29.
[3] 曹志敏, 温春齐, 李保华, 等. 首例独立碲矿床成因探讨[J]. 中国科学:B辑, 1995, 25(6):647-654. Cao Zhimin, Wen Chunqi, Li Baohua, et al. Discussion on the Origin of the First Independent Tellurium Ore Deposit[J]. Science in China:Series B, 1995, 25(6):647-654.
[4] 温汉捷, 裘愉卓. 拉尔玛硒-金矿床元素有机/无机结合态及硒的赋存状态研究[J]. 中国科学:D辑, 1999, 29(5):426-432. Wen Hanjie, Qiu Yuzhuo. Study on Element Organic/Inorganic Binding and Occurrence State of Selenium in Laerma Selenium-Gold Deposit[J]. Science in China:Series D, 1999, 29(5):426-432.
[5] 谷团. 牛角塘独立镉矿床初步研究[D]. 贵阳:中国科学院地球化学研究所, 1999. Gu Tuan. Preliminary Study on the Niujiaotang Independent Cadmium Deposit(Master's Tthesis)[D]. Guiyang:Institute of Geochemistry Chinese Academy of Sciences, 1999.
[6] 谷团, 刘玉平, 李朝阳. 分散元素的超常富集与共生[J]. 矿物岩石地球化学通报, 2000, 19(1):60-63. Gu Tuan, Liu Yuping, Li Chaoyang. Super-Richening and Coexistence of Disperse Elements[J]. Bulletin of Mineralogica Petrology and Geochemistry, 2000, 19(1):60-63.
[7] 陈代演, 王冠鑫, 邹振西,等. 新矿物:铊明矾[J]. 矿物学报, 2001, 21(3):271-277. Chen Daiyan, Wang Guanxin, Zou Zhenxi, et al. A New Mineral:Lanmuchangite[J]. Acta Mineralogica Sinica, 2001, 21(3):271-277.
[8] 刘家军, 冯彩霞, 李志明, 等. 湖北渔塘坝硒矿床中次生自然硒的特征与意义[J]. 现代地质, 2005, 19(4):531-537. Liu Jiajun,Feng Caixia,Li Zhiming,et al. The Research of Significance and Discovery of Secondary Native Selenium in the Yutangba Se Deposit, Western Hubei[J]. Geoscience, 2005, 19(4):531-537.
[9] 涂光炽, 高振敏. 分散元素成矿机制获重大进展[J]. 中国科学院院刊, 2003, 29(5):358-361. Tu Guangzhi, Gao Zhenmin. Significant Progress in Dispersed Element Mineralization Mechanism[J]. Bulletin of the Chinese Academy of Sciences, 2003, 29(5):358-361.
[10] 涂光炽, 高振敏, 胡瑞忠, 等. 分散元素地球化学及成矿机制[M]. 北京:地质出版社, 2004. Tu Guangzhi, Gao Zhenmin, Hu Ruizhong, et al. Disperse Element Geochemistry and Metallogenic Mechanism[M]. Beijing:Geological Publishing House, 2004.
[11] 中国大百科全书编写组. 中国大百科全书[M]. 北京:中国大百科全书出版社, 1993. The Writing Group of Chinese Encyclopedia. Encyclopedia of China[M]. Beijing:Encyclopedia of China Publishing House,1993.
[12] 刘铁庚, 叶霖. 都匀牛角塘大型独立镉矿床的地质地球化学特征[J]. 矿物学报, 2000, 20(3):279-285. Liu Tiegeng, Ye Lin. Geological-Geochemical Characteristics of Niujiaotang Independent Cadmium Deposit in Duyun, China[J]. Acta Minaralagical Sinica, 2000, 20(3):279-285.
[13] 刘铁庚, 张乾, 叶霖, 等. 自然界中ZnS-CdS完全类质同象系列的发现和初步研究[J]. 中国地质, 2004, 31(1):40-45. Liu Tiegeng, Zhang Qian,Ye Lin, et al. Discovery of the Complete Isomorphous Series of ZnS-CdS in Nature and Its Preliminary Study[J]. Geology in China, 2004, 31(1):40-45.
[14] 叶霖,刘铁庚,邵树勋. 富镉锌矿的成矿流体地球化学研究:以贵州都匀牛角塘富镉锌矿床为例[J]. 地球化学, 2000, 29(6):597-603. Ye Lin, Liu Tiegeng, Shao Shuxun. Geochemistry of Mineralizing Fluid of Cd-Rich Zinc Deposit:Taking Nujiaotang Cd-Rich Zinc Deposit, Duyun, Guizhou for Example[J]. Geochimica, 2000, 29(6):597-603.
[15] 刘铁庚,张乾,叶霖, 等. 贵州牛角塘镉锌矿床中发现原生硫镉矿[J]. 矿物学报, 2004, 24(2):191-196. Liu Tiegeng, Zhang Qian,Ye Lin, et al. Discoery of Primary Greenockite in Naturem, as Exemplified by the Niujiaotang Cadmium-Zinc Deposit, Guizhou[J]. Acta Minaralagical Sinica, 2004, 24(2):191-196.
[16] 刘铁庚,叶霖, 王兴理,等. 中国首次发现菱镉矿[J]. 中国地质, 2005, 32(3):443-446. Liu Tiegeng, Ye Lin, Wang Xingli, et al. First Discovery of Otavite in China[J]. Geology in China, 2005, 32(3):443-446.
[17] 顾雪祥, 王乾, 付绍洪,等. 分散元素超常富集的资源与环境效应:研究现状与发展趋势[J]. 成都理工大学学报(自然科学版), 2004, 31(1):15-21. Gu Xuexiang, Wang Qian, Fu Shaohong, et al. Resources and Environmental Effects of Abnormal Enrichment of Dispersed Elements:Research Situation and Tendency[J]. Journal of Chengdu University of Technology(Science & Technology Edition), 2004, 31(1):15-21.
[18] 司荣军, 顾雪祥, 庞绪成,等. 云南省富乐铅锌多金属矿床闪锌矿中分散元素地球化学特征[J]. 矿物岩石, 2006, 26(1):75-80. Si Rongjun, Gu Xuexiang, Pang Xucheng, et al. Geochemical Character of Dispersed Element in Sphalerite from Fule Pb-Zn Polymetal Deposit, Yunnan Province[J]. Journal of Minerology and Petrology, 2006, 26(1):75-80.
[19] 王乾, 顾雪祥, 付绍洪, 等. 云南会泽铅锌矿床分散元素镉锗镓的富集规律[J]. 沉积与特提斯地质, 2008, 28(4):69-73. Wang Qian, Gu Xuexiang, Fu Shaohong, et al. Enrichment of the Dispersed Elements Cd, Ge and Ga in the Huize Lead-Zinc Deposit, Yunnan[J]. Sedimentary Geology and Tethyan Geology, 2008, 28(4):69-73.
[20] 周家喜, 黄智龙, 周国富,等. 贵州天桥铅锌矿床分散元素赋存状态及规律[J]. 矿物学报, 2009, 29(4):471-480. Zhou Jiaxi, Huang Zhilong, Zhou Guofu, et al. The Occurrence States and Regularities of Dispersed Elements in Tianqiao Pb-Zn Ore Deposit, Guizhou Province, China[J]. Acta Mineralogica Sinica, 2009, 29(4):471-480.
[21] 王乾, 安匀玲, 顾雪祥,等. 四川大梁子铅锌矿床分散元素镉、锗、镓的富集规律[J]. 沉积与特提斯地质, 2010, 30(1):78-84. Wang Qian, An Yunling, Gu Xuexiang, et al. Enrichment of the Dispersed Elements Cd, Ge and Ga in the Daliangzi Lead-Zinc Deposit, Huidong, Sichuan[J]. Sedimentary Geology and Tethyan Geology, 2010, 30(1):78-84.
[22] 司荣军,顾雪祥,谢良鲜, 等. 云南省富乐分散元素多金属矿床地质特征:铅锌矿床中的分散元素与超常富集[J]. 地质与勘探, 2013, 49(2):313-322. Si Rongjun, Gu Xuexiang, Xie Liangxian, et al. Geological Characteristics of the Fule Polymetallic Deposit in Yunnan Province:A Pb-Zn Deposit with Dispersed Elements and Unusual Enrichment[J]. Geology and Prospecting, 2013, 49(2):313-322.
[23] 毛光武, 朱玉磷, 胡明安. 福建省龙岩中甲铁矿矿床特征及分散元素铟镉的富集规律[J]. 地质与勘探, 2013, 49(1):130-143. Mao Guangwu,Zhu Yulin,Hu Ming'an. Geological Characteristics and Enrichment Regularities of the Dispersed Elements Indium and Cadmium in the Zhongjia Iron Ore Deposit of Longyan City,Fujian Province[J]. Geology and Exploration, 2013, 49(1):130-143.
[24] 朱传威, 温汉捷, 张羽旭, 等. 铅锌矿床中的Cd同位素组成特征及其成因意义[J]. 中国科学:D辑:地球科学, 2013, 43(11):1847-1856. Zhu Chuanwei, Wen Hanjie, Zhang Yuxu, et al. Cadmium Isotpe Composition Characteristics and Its Genesis in the Pb Zn Ore Deposit.[J]. Science China:Series D:Earth Ccience, 2013, 43(11):1847-1856.
[25] 姜凯, 燕永锋, 朱传威,等. 云南金顶铅锌矿床中铊、镉元素分布规律研究[J]. 矿物岩石地球化学通报, 2014, 33(5):753-758. Jiang Kai, Yan Yongfeng, Zhu Chuanwei, et al. The Research on Distributions of Thallium and Cadmium in the Jinding Lead-Zinc Deposit, Yunnan Province[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2014, 33(5):753-758.
[26] 王华云, 梁福谅, 曾鼎权, 等. 贵州铅锌矿地质[M]. 贵阳:贵州科学技术出版社, 1996. Wang Huayun, Liang Fuliang, Zeng Dingquan, et al. Pb-Zn Ore Geology in Gui Zhou[M]. Guiyang:Guizhou Science and Technology Press, 1996.
[27] 王育民, 朱家鳌, 余琼华. 湖南铅锌矿地质[M]. 北京:地质出版社, 1988. Wang Yumin, Zhu Jiaao, Yu Qionghua. Pb-Zn Ore Deposit Geology in Hunan[M]. Beijing:Geological Publishing House, 1998.
[28] 贵州地质矿产局. 贵州省区域地质志[M]. 北京:地质出版社, 1987. Guizhou Bureau of Geology and Mineral Resources. Regional Geology of Guizhou Province[M]. Beijing:Geological Publishing House, 1987.
[29] 周琦. 松桃嗅脑铅锌矿田藻丘微相特征及控矿规律探讨[J]. 贵州地质, 1995, 12(4):311-315. Zhou Qi. Discussion on Algal Mound Microfacies Characteristics and Ore Controlling Regularity of Pb-Zn Ore Field in Songtao, Guizhou[J]. Guizhou Geology, 1995, 12(4):311-315.
[30] Boyle R W. Speculation on the Source of Zinc, Cad-mium, Lead, Copper and Sulfur in Mississippi Valley and Similar Types of Lead-Zinc Deposits[J]. Economic Geology, 1968, 63(2):420-422.
[31] 刘志礼, 刘雪娴, 李朋富. 藻类及其有机质的成矿作用试验[J]. 沉积学报, 1999, 17(1):9-18. Liu Zhili, Liu Xuexian, Li Pengfu. Mineralization Tests Made by Algae and Its Organic Matters[J]. Acta Sedimentologica Sinica, 1999, 17(1):9-18.
[32] 涂光炽. 成煤、成油、成盐和成金属矿之间的关系[J]. 有色金属矿产与勘察, 1994, 3(1):1-3. Tu Guangzhi. Coal, Oil, Salt and a Relationship Between the Metal Mine[J]. Nonferrous Metal Mineral Resources and Exploration, 1994, 3(1):1-3.
[33] Rickard D T. Hydrocarbons Associated with Lead-Zinc Ores at Laisvall, Sweden[J]. Nature, 1975, 225:131-132.
[34] 李朝阳. 中国低温矿床集中分布区的一些地质特点[J]. 地学前缘, 1999, 6(1):163-170. Li Chaoyang. Some Geological Characteristics of Epithermal Deposit in Concentrated Distribution Area, China[J]. Earth Science Frontiers, 1999, 6(1):163-170.
[35] 施继锡, 王华云, 林青. 有机质与Au、Sb、Hg成矿关系的证据[C]//低温地球化学. 北京:科学出版社, 1998:115-122. Shi Jixi, Wang Huayun, Lin Qing. The Relationship Between Organic Matter and Au, Sb, Hg Mineralization[C]//Epithermal Geochemisty. Beijing:Science Press, 1998:115-122..
[36] 刘华,蒋有录,徐浩清,等. 东营凹陷民丰地区深层裂解气藏成因类型与成藏模式[J]. 吉林大学学报(地球科学版), 2012, 42(6):1638-1646. Liu Hua, Jiang Youlu, Xu Haoqing,et al. Genetic Types and Accumulation Model of the Deep Cracked Gas Pools of Minfeng Area in Dongying Sag[J]. Journal of Jilin University(Earth Science Edition), 2012, 42(6):1638-1646.
[37] 李天义,何治亮,何生,等. 中扬子北缘京山二叠系古油藏特征及石油地质意义[J]. 吉林大学学报(地球科学版), 2013, 43(6):1740-1752. Li Tianyi, He Zhiliang, He Sheng, et al. Characteristics and Its Petroleum Geological Significance of the Permian Paleo-Oil Reservoir of Jingshan Area, the North Edge of the Central Yangtze Block[J]. Journal of Jilin University(Earth Science Edition), 2013, 43(6):1740-1752.
[38] 杨平, 汪正江, 印峰, 等. 麻江古油藏油源识别与油气运聚分析:来自油气地球化学的证据[J]. 中国地质,2014, 41(3):982-994. Yang Ping, Wang Zhengjiang, Yin Feng,et al. Identification of Oil Resource and Analysis of Hydrocarbon Migration and Accumulation of Majiang Paleo-Reservoir:Evidence from Oil-Gas Geochemistry[J]. Geology in China,2014, 41(3):982-994.
[39] 韩世庆, 王守德, 胡惟之. 黔东麻江古油藏的发现及其石油地质意义[J]. 石油与天然气地质, 1982, 3(4):17-25. Han Shiqing, Wang Shoude, Hu Weizhi. The Discovery of Majiang Paleo Oil Reservoir and Its Petroleum Geology Significance, Eastern Guizhou[J]. Oil and Gas Geology, 1982, 3(4):17-25.
[40] 武蔚文. 贵州若干古油藏的形成和破坏[J]. 贵州地质, 1989, 6(1):9-19. Wu Weiwen. The Formation and Destruction of Paleo-Oil Reservoir in Guizhou[J]. Guizhou Geology, 1989, 6(1):9-19.
[41] 向才富, 汤良杰, 李儒峰, 等. 叠合盆地幕式流体活动:麻江古油藏露头与流体包裹体证据[J]. 中国科学:D辑:地球科学,2008, 38(增刊1):70-77. Xiang Caifu, Tang Liangjie,Li Rufeng,et al. Episodic-fluid Activity in Composite Basin:Evidence fron Majiang Paleo-Oil Reservoir Outcrop and Fluid Inclusion[J]. Science in China:Series D:Earth Sciences, 2008, 38(Sup.1):70-77.
[42] 陈玲, 马昌前, 凌文黎, 等. 中国南方存在印支期的油气藏:Re-Os同位素体系的制约[J]. 地质科技情报, 2010, 29(2):95-99. Chen Ling, Ma Changqian, Lin Wenli, et al. Indosinian Hydrocarbon Accumulationin South China:A Re-Os Isotope Constrain[J]. Geological Science and Technology Information, 2010, 29(2):95-99.
[43] 李双建, 高波, 沃玉进, 等. 中国南方海相油气藏破坏类型及其时空分布[J]. 石油实验地质, 2011, 33(1):43-55. Li Shuangjian, Gao Bo, Wo Yujin, et al. Destruction Types and Temporal-Spatial Distribution of Marine Hydrocarbon Reservoirs in South China[J]. Petroleum Geology an Experiment, 2011, 33(1):43-55.
[44] 高波, 沃玉进, 周雁, 等. 贵州麻江古油藏成藏期次[J]. 石油与天然气地质, 2012, 33(3):417-423. Gao Bo, Wo Yujin, Zhou Yan, et al. Hydrocarbon Accumulation Phases of Majiang Paleo-Oil Reservoir in Guizhou[J]. Oil and Gas Geology, 2012, 33(3):417-423.
[45] 余开富, 王守德. 贵州南部的都匀运动及其古构造特征和石油地质意义[J]. 贵州地质, 1995, 12(3):225-232. Yu Kaifu, Wang Shoude. Duyun Movement in South Guizhou Provinee and Its Paleostrueture, and Their Significanee in Petroleum Geology[J]. Guizhou Geology, 1995, 12(3):225-232.
[46] 王华云, 施继锡. 贵州丹寨、三都、都匀地区低温成矿系列的成矿物质来源和分异条件[J]. 矿物学报, 1997, 17(4):491-500. Wang Huayun,Shi Jixi. Sources of Ore-Forming Materials and Controls Over Depositional Diffrentiation in the Epithermal Mineralazation Series in the Danzhai-Sandu-Duyun Area of Guizhou Province[J]. Acta Mineralogica Sinica, 1997, 17(4):491-500.
[47] 刘岩, 钟宁宁, 田永晶, 等. 中国最老古油藏:中元古界下马岭组沥青砂岩古油藏[J]. 石油勘探与开发, 2011, 38(4):503-512. Liu Yan, Zhong Ningning,Tian Yongjing,et al. The Oldest Oil Accumulation in China:Meso-Proterozoic Xiamaling Formation Bituminous Aandstone Reservoirs[J]. Petroleum Exploration and Development, 2011, 38(4):503-512.
[48] 刘文均, 郑荣才, 李元林, 等. 花垣铅锌矿床中沥青的初步研究[J]. 沉积学报, 1999, 17(1):19-23. Liu Wenjun, Zheng Rongcai,Li Yuanlin,et al. Study of Bitumen in the Huayuan Lead-Zinc Deposit[J]. Acta Sedimentologica Sinica, 1999, 17(1):19-23.
[49] 严均平. 贵州汞矿地质[M]. 北京:地质出版社, 1989. Yan Junping. Guizhou Mercury Mine Geology[M]. Beijing:Geological Publishing House, 1989.
[50] Brookins G. Geochemical Behavior of Antimony, Ar-senic, Cadmium and Thallium:Eh-pH Diagram for 25 Degrees, 1 Bar Pressure[J]. Chemical Geology, 1986, 54(3/4):271-278.
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