Journal of Jilin University(Earth Science Edition) ›› 2017, Vol. 47 ›› Issue (3): 734-750.doi: 10.13278/j.cnki.jjuese.201703108

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Trace and Rare Earth Elements Characteristics of Sphalerite in Dulong Super Large Sn-Zn Polymetallic Ore Deposit, Yunnan Province

Ye Lin1, Liu Yuping1, Zhang Qian1, Bao Tan1,2, He Fang1,2, Wang Xiaojuan1,2, Wang Dapeng1, Lan Jiangbo1   

  1. 1. Institute of Geochemistry/State Key Laboratory of Ore Deposit Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China;
    2. College of Earth Sciences,University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2016-11-13 Online:2017-05-26 Published:2017-05-26
  • Supported by:
    Supported by the National Natural Science Foundation of China (41173063, 41673056), Scientific Research Project of Yunnan Hualian Zinc and Indium Co. LTD. (KY20120910) and 12th Five-Year Plan Project of State Key Laboratory of Ore-Deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-02)

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Abstract: As one of the three largest Sn-Zn polymetallic ore deposits in China, the Dulong ore deposit is located within the southern Laojunshan Sn-Zn-W polymetallic mineralization province in south-eastern Yunnan. There are conflicts on ore genesis of this deposit. Researches on the trace and rare earth elements of sphalerite in the deposit, by ICP-MS, shows that the sphalerite is characterized by enrichment of Fe, Mn, In, Co, Sn and depleted in Cd, Ga, Ge, Ni, which is similar to that of the Bainiuchang Pb-Zn ore deposit (magmatic hydrothermal type deposit related to Late Yanshanian granite), and certainly different from that of the skarn type Pb-Zn deposit of distant origin (e.g. Hetaoping and Luziyuan, Yunnan), and is quite different from that of the massive sulfide Pb-Zn deposit (e.g. Laochang, Yunnan and Dabaoshan, Guangdong). The chondrite-normalized REE patterns of the sphalerite belong to the LREE-rich type, which are characterized by the higher LREE/HREE ratio, the obvious negative anomaly of Eu and the unconspicuous anomaly of Ce, corresponding to that of Late Yanshanian concealed granite. Research data in this paper show that, in this deposit, the ore-forming materials mainly came from the granite and the ore-forming temperature belongs to the medium-high temperature. In consideration of the vertical mineralization zoning and skarn alteration zoning, it is suggested that the Dulong Sn-Zn polymetallic ore deposit is a skarn type related to the Late Yanshanian granite, and the zoned mineralization and wall-rock alteration are controlled by the distance between the deposit and the concealed intrusion.

Key words: Dulong Sn-Zn polymetallic ore deposit, sphalerate, trace elements, rare earth elements, Late Yanshanian concealed granite

CLC Number: 

  • P618.2
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