Journal of Jilin University(Earth Science Edition) ›› 2017, Vol. 47 ›› Issue (3): 734-750.doi: 10.13278/j.cnki.jjuese.201703108

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Trace and Rare Earth Elements Characteristics of Sphalerite in Dulong Super Large Sn-Zn Polymetallic Ore Deposit, Yunnan Province

Ye Lin1, Liu Yuping1, Zhang Qian1, Bao Tan1,2, He Fang1,2, Wang Xiaojuan1,2, Wang Dapeng1, Lan Jiangbo1   

  1. 1. Institute of Geochemistry/State Key Laboratory of Ore Deposit Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China;
    2. College of Earth Sciences,University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2016-11-13 Online:2017-05-26 Published:2017-05-26
  • Supported by:
    Supported by the National Natural Science Foundation of China (41173063, 41673056), Scientific Research Project of Yunnan Hualian Zinc and Indium Co. LTD. (KY20120910) and 12th Five-Year Plan Project of State Key Laboratory of Ore-Deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-02)

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Abstract: As one of the three largest Sn-Zn polymetallic ore deposits in China, the Dulong ore deposit is located within the southern Laojunshan Sn-Zn-W polymetallic mineralization province in south-eastern Yunnan. There are conflicts on ore genesis of this deposit. Researches on the trace and rare earth elements of sphalerite in the deposit, by ICP-MS, shows that the sphalerite is characterized by enrichment of Fe, Mn, In, Co, Sn and depleted in Cd, Ga, Ge, Ni, which is similar to that of the Bainiuchang Pb-Zn ore deposit (magmatic hydrothermal type deposit related to Late Yanshanian granite), and certainly different from that of the skarn type Pb-Zn deposit of distant origin (e.g. Hetaoping and Luziyuan, Yunnan), and is quite different from that of the massive sulfide Pb-Zn deposit (e.g. Laochang, Yunnan and Dabaoshan, Guangdong). The chondrite-normalized REE patterns of the sphalerite belong to the LREE-rich type, which are characterized by the higher LREE/HREE ratio, the obvious negative anomaly of Eu and the unconspicuous anomaly of Ce, corresponding to that of Late Yanshanian concealed granite. Research data in this paper show that, in this deposit, the ore-forming materials mainly came from the granite and the ore-forming temperature belongs to the medium-high temperature. In consideration of the vertical mineralization zoning and skarn alteration zoning, it is suggested that the Dulong Sn-Zn polymetallic ore deposit is a skarn type related to the Late Yanshanian granite, and the zoned mineralization and wall-rock alteration are controlled by the distance between the deposit and the concealed intrusion.

Key words: Dulong Sn-Zn polymetallic ore deposit, sphalerate, trace elements, rare earth elements, Late Yanshanian concealed granite

CLC Number: 

  • P618.2
[1] 周祖贵. 都龙矿区资源总价值[J]. 云南冶金,2002,31(5):62-64. Zhou Zugui. Total Value of Resource in Dulong Mine Area[J]. Yunnan Metallurgy, 2002,31(5): 62-64.
[2] 张世涛,冯明刚,吕伟. 滇东南温河变质核杂岩解析[J]. 中国区域地质,1998,17(4):390-397. Zhang Shitao, Feng Minggang, Lü Wei. Analysis the Nanwenhe Metamorphic Core Complex in Southeastern Yunnan[J]. Regional Geology of China, 1998, 17(4): 390-397.
[3] 颜丹平,周美夫,王焰. 都龙-Song Chay变质弯隆体变形与构造年代:南海盆地北缘早期扩张作用始于华南地块张裂的证据[J].地球科学:中国地质大学学报,2005,30(4):402-412. Yan Danping, Zhou Meifu, Wang Yan. Structural Styles and Chronological Evidences from Dulong-Song Chay Tectonic Dome: Earlier Spreading of South China Sea Basin du to Late Mesozoic to Early Cenozoic Extension of South China Block[J]. Earth Science:Journal of China University of Geosciences, 2005, 30(4): 402-412.
[4] 刘玉平,叶霖,李朝阳,等.滇东南发现新元古代岩浆岩:SHRIMP锆石U-Pb年代学和岩石地球化学证据[J].岩石学报,2006,22(4):916-926. Liu Yuping, Ye Lin, Li Chaoyang, et al. Discovery of the Neoproterozoic Magmatics in Southeastern Yunnan: Evidence from SHRIMP Zircon U-Pb Dating and Litho-Geochemistry[J]. Acta Petrological Sinica, 2006, 22(4): 916-926.
[5] 冯佳睿,毛景文,裴荣富,等. 云南瓦渣钨矿区老君山花岗岩体的SHRIMP锆石U-Pb定年、地球化学特征及成因探讨[J]. 岩石学报,2010,26(3):845-857. Feng Jiarui, Mao Jingwen, Pei Rongfu, et al. SHRIMP Zircon U-Pb Dating and Geochemical Characteristics of Laojunshan Granite Intrusion from the Wazha Tungsten Deposit, Yunnan Province and Their Implications for Petrogenesis[J]. Acta Petrologica Sinica, 2010, 26(3) : 845-857.
[6] 冯佳睿,毛景文,裴荣富,等. 滇东南老君山地区印支期成矿事件初探:以新寨锡矿床和南秧田钨矿床为例[J]. 矿床地质,2011,30(1):57-73. Feng Jiarui, Mao Jingwen, Pei Rongfu, et al. A Tentative Discussion on Indosinian Ore-Forming Events in Laojunshan Area of Southeastern Yunnan: A Case Study of Xinzhai Tin Deposit and Nanyangtian Tungsten Deposit[J]. Mineral Deposits, 2011, 30(1):57-73.
[7] 张斌辉,丁俊,任光明,等. 云南马关老君山花岗岩的年代学、地球化学特征及地质意义[J]. 地质学报,2012,86(4):587-601. Zhang Binhui, Ding Jun, Ren Guangming, et al. Geochronology and Geochemical Characteristics of the Laojunshan Granites in Maguan County, Yunnan Province, and Its Geological Implications[J]. Acta Geologica Sinica, 2012, 86(4): 587-601.
[8] 宋焕斌.云南东南部都龙锡石-硫化物型矿床的成矿特征[J].矿床地质,1989,8(4):29-38. Song Huanbin. Ore-Froming Characteristics of the Dulong Cassiterite-Sulfide Type Ore Deposit in Southeastern Yunnan[J]. Mineral Deposits, 1989, 8(4): 29-38.
[9] 范承钧.云南锡矿带之划分及其区域成矿地质特点[J].云南地质,1988,7(1):1-12. Fan Chengjun. The Division and Their Regional Metallogenic Characteristics of Yunnan Tin Ore Deposit[J]. Yunnan Geology, 1988, 7(1): 1-12.
[10] 秦德先,刘春学. 矿产资源经济学[M].北京:科学出版社,2002. Qin Dexian, Liu Chunxue. Mineral Resource Economics[M]. Beijing: Science Press, 2002.
[11] 缪应理,张世奎,韦文彪,等. 云南都龙锡多金属矿床金石坡矿段钨铜钼矿化特征及地质意义[J].矿物学报,2013,33(4):510-514. Miao Yingli, Zhang Shikui, Wei Wenbiao, et al. Geological Features and Its Significances of W-Cu-Mo Mineralization in the Jinshipo Ore Block, Dulong Sn Poly-Metals Deposit, Yunnan Province, China[J]. Acta Mineralogica Sinica, 2013, 33(4):510-514.
[12] 张世奎,缪应理,郭跃进. 云南马关都龙辣子寨碳酸盐岩型铅锌矿体的发现及其地质意义[J].矿物学报,2013,33(4):456-461. Zhang Shikui, Miao Yingli, Guo Yuejin. Discovery and Its Geological Significance of Carbonate-Hosted Pb-Zn Ore-Bodies in the Lazizhai Ore Block, Dulong Sn Poly-Metals Deposit, Yunnan Province, China[J]. Acta Mineralogica Sinica, 2013, 33(4):456-461.
[13] 曾志刚,李朝阳,刘玉平. 老君山锡锌多金属成矿区变质成因矽卡岩的地质地球化学特征[J]. 矿物学报,1999,19(1):48-55. Zeng Zhigang, Li Chaoyang, Liu Yuping. Geology and Geochemistry of Metamorphogenic Skarn from Laojunshan Metallogebic Province[J]. Acta Mineralogica Sinica, 1999, 19(1): 48-55.
[14] 刘玉平,李朝阳,刘家军.都龙矿床含矿层状矽卡岩成因的地质地球化学证据[J].矿物学报,2000,20(4):378- 384. Liu Yuping, Li Chaoyang, Liu Jiajun. Characteristics and Genesis of Stratiform Skarn from Dulong Tin-Zinc Polymetallic Deposit, Yunnan[J]. Acta Mineralogica Sinica, 2000, 20(4): 378-384.
[15] 廖震,刘玉平,李朝阳,等. 都龙锡锌矿床绿泥石特征及其成矿意义[J].矿床地质,2010,29(1):169-176. Liao Zhen, Liu Yuping, Li Chaoyang, et al. Characteristics of Chlorites from Dulong Sn- Zn Deposit and Their Metallogenic Implications[J]. Mineral Deposits, 2010, 29(1): 169-176.
[16] 刘玉平,李正祥,李惠民,等.都龙锡锌矿床锡石和锆石U-Pb年代学:滇东南白垩纪大规模花岗岩成岩成矿事件[J].岩石学报,2007,23(5):967-976. Liu Yuping, Li Zhengxiang, Li Huimin, et al. U-Pb Geochronology and Zircon from the Dulong Sn-Zn Deposit: Evidence for Cretaceous Large-Scal Granitic Magmatism Events in Southeastern Yunnan Province, China[J]. Acta Petrologica Sinica, 2007, 23(5): 967-976.
[17] 廖震. 滇东南都龙锡锌多金属矿床矿物学及年代学[D]. 贵阳:中国科学院地球化学研究所,2008. Liao Zhen. Mineralogy and Geochronology of the Dulong Tin-Zinc Ploymetallic Deposit, Southeastern Yunnan Province, China[D]. Guiyang: Institute of Geochemistry,Chinese Academy of Sciences, 2008.
[18] 王小娟,刘玉平,缪应理,等. 都龙锡锌多金属矿床LA-MC-ICPMS锡石U-Pb测年及其意义[J].岩石学报,2014,30(3):867-876. Wang Xiaojuan, Liu Yuping, Miao Yingli, et al. In-Situ LA-MC-ICP-MS Cassiterite U-Pb Dating of Dulong Sn-Zn Polymetallic Deposit and Its Significance[J]. Acta Petrologica Sinica, 2014, 30(3): 867-876.
[19] 宋焕斌, 金世昌. 滇东南都龙锡矿床的控矿因素及区域找矿方向[J]. 云南地质, 1987,6(4): 298-303. Song Huanbin, Jin Shichang. The Ore Control Factors and the Direction of Regional Prospecting of the Dulong Tin Ore Deposit in Southeastern Yunnan[J]. Yunnan Geology, 1987, 6(4): 298-303.
[20] 李文尧. 云南麻栗坡新寨锡矿物化探异常特征[J]. 云南地质,2002,21(1):72-82. Li Wenyao. Geophysical and Geochemical Characteristics of Xinzhai Tin Ore Deposit of Malipo, Yunnan [J]. Yunnan Geology, 2002, 21(1): 72-82.
[21] 张春红,黎应书,王金良,等. 云南马关都龙锡锌多金属矿床成矿控制条件[J].有色金属,2008,60(4):140-143. Zhang Chunhong, Li Yingshu, Wang Jinliang, et al. Ore-Body Controlloing Factors of Dulong Tin-Zinc Polymetallic Ore Deposit at Maguan of Yunnan in China[J]. Nonferrous Metals, 2008, 60(4): 140-143.
[22] 周建平,徐克勤,华仁民. 滇东南锡多金属矿床成因商榷[J].云南地质,1997,16(4):309-349. Zhou Jianping, Xu Keqin, Hua Renmin. A Discussion on Genesis of the Tin Polymetallic Sulfide Deposits of Southeastern Yunnan[J]. Yunnan Geology, 1997, 16(4): 309-349.
[23] 周建平,徐克勤,华仁民.滇东南喷流沉积硫化物块状硫化物特征与矿床成因[J]. 矿物学报,1998,18(2):158-168. Zhou Jianping, Xu Keqin, Hua Renmin. Characteristics and Genesis of Exhalative Sedimentary Massive Sulfides in Southeastern Yunnan Province[J]. Acta Mineralogica Sinica, 1998, 18(2): 158-168.
[24] 刘玉平. 一个受后期改造和热液叠加的块状硫化物矿床:都龙超大型锡锌多金属矿床[J].矿物岩石地球化学通报,1998,17(1):22-24. Liu Yuping. Geochemistry of Dulong Superlarge Tin-Zinc-Polymetallic Deposit, Yunnan[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 1998, 17(1): 22-24.
[25] 刘英俊,曹励明,李兆麟.等. 元素地球化学[M]. 北京:地质出版社,1984. Liu Yingjun, Cao Liming, Li Zhaolin, et al. Element Geochemistry[M]. Beijing: Geological Publishing House, 1984.
[26] 涂光炽,高振敏,胡瑞忠,等.分散元素地球化学及成矿机制[M]. 北京:地质出版社,2003:1-424. Tu Guangchi, Gao Zhenmin, Hu Ruizhong, et al. Geochemistry and Mineralization Mechanism of Dispersed Elements[M]. Beijing: Geological Publishing House, 2003: 1-424.
[27] Zhang Qian. Trace Elements in Galena and Sphalerite and Their Geochemical Significance in Distinguishing the Genetic Types of Pb-Zn Ore Deposits[J]. Chinese Journal of Geochemistry, 1987, 6: 177-190.
[28] Beaudoin G. AcicularSphalerite Enriched in Ag, Sb, and Cu Embedded Within Colour Banded Sphalerite from the Kokanee Range, BC[J]. Canadian Mineralogist, 2000, 38: 1387-1398.
[29] Di Benedetto F, Bernardini G P, Costagliola P, et al. Compositional Zoning in Sphalerite Crystals[J]. American Mineralogist, 2005, 90:1384-1392.
[30] Ishihara S, Hoshino K, Murakami H, et al. Resou-rce Evaluation and some Genetic Aspects of Indium in the Japanese Ore Deposits[J]. Resource Geology, 2006, 56 :347-364.
[31] Martín J D, Gil A S I. An Integrated Thermodynamic Mixing Model for Sphalerite Geobarometry from 300 to 850 ℃ and Up to 1 GPa[J]. Geochim Cosmochim Acta, 2005, 69: 995-1006.
[32] Gottesmann W, Kampe A. Zn/Cd Ratios in Calcsi-licate-Hosted Sphalerite Ores at Tumurtijn-Ovoo, Mongolia[J]. Chemie der Erde, 2007, 67:323-328.
[33] Ishihara S, Endo Y. Indium and Other Trace Ele-ments in Volcanogenic Massive Sulphide Ores from the Kuroko, Besshi and Other Types in Japan[J]. Bulletin, Geological Survey of Japan, 2007, 58: 7-22.
[34] Cook N J, Ciobanu C L, Pring A, et al. Trace and Minor Ele-Ments in Sphalerite: A LA-ICP-MS Study[J]. Geochimica et Cosmochimica Acta, 2009, 73: 4761-4791.
[35] Cook N J, Ciobanu C L, Williams T. The Mineralogy and Mineral Chemistry of Indium in Sulphide Deposits and Implications for Mineral Processing[J]. Hydrometallurgy, 2011, 108(3/4): 226-228.
[36] Cook N J, Sundblad K, Valkama M, et al. Indium Mineralisation in A-Type Granites in Southeastern Finland: Insights into Mineralogy and Partitioning Between Coexisting Minerals[J]. Chemical Geology, 2011, 284:62-73.
[37] Ye L, Cook N J, Ciobanu C L,et al. Trace and Minor Elements in Sphalerite from Base Metal Deposits in South China: A LA-ICPMS Study[J]. Ore Geology Review, 2011, 39:188-217.
[38] 叶霖,高伟,杨玉龙,等. 云南澜沧老厂铅锌多金属矿床闪锌矿微量元素组成[J].岩石学报,2012,28(5):1362-1372. Ye Lin, Gao Wei, Yang Yulong, et al. Trace Elements in Sphalerite in Laochang Pb-Zn Polymetallic Deposit, Lancang, Yunnan Province[J]. Acta Petrologica Sinica, 2012, 28(5) : 1362-1372.
[39] 鲍谈. 云南都龙矽卡岩型锡锌多金属矿床成矿流体及成矿机制研究[D]. 贵阳:中国科学院地球化学研究所,2014. Bao Tan. The Ore-Forming Fluid and Metallogenic Mechanism of the Dulong Skarn Sn-Zn Pollymetallic Deposit[D]. Guiyang: Instistitute of Geochemistry,Chinese Academy of Sciences, 2014.
[40] Qi L, Hu J, Gregoire D C. Determination of Trace Elements in Granites by Inductively Coupled Plasma Mass Spectrometry[J]. Talanta, 2000, 51(3): 507-513.
[41] Sun S S, Mcdonough W F. Chemical and Isotopic Systematics of Oceanic Basalts: Implications for Mantle Composition and Processes[C]// Saunders A D, Norry M J. Magmatism in the Ocean Basins. London:Geological Society Special Publications, 1989, 42(1) : 313-345.
[42] Shannon R D. Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides[J]. Acta Cryst,1976, A32:751-767.
[43] Bau M, Dulski P. Comparing Yttrium and Rare Earths in Hydrothermal Fluids from the Mid-Atlantic Ridge:Implications for Y and REE Behavior During Near-Vent Mixing and for the Y/Ho Ratio of Proterozoic Seawater[J]. Chem Geol, 1999, 155: 77-90.
[44] Douville E, Bienvenu P, Charlou J I. Yttrium and Rare Earth Elements in Fluids from Various Deep-Sea Hydrothermal Systerns [J]. Geochimica et Cosmochimica Acta,1999, 63: 627-643.
[45] 叶霖,杨玉龙,高伟,等. 陕南铜厂铜矿床成矿物质来源探讨[J].吉林大学学报(地球科学版),2012,42(1):92-103. Ye Lin, Yang Yulong, Gao Wei, et al. Discussion on Ore-Forming Materials of Tongchang Copper Ore Deposit, Southern Shaanxi Province, China[J]. Journal of Jilin University(Earth Science Edition), 2012, 42(1):92-103.
[46] 韩照信. 秦岭泥盆系铅锌成矿带中闪锌矿的标型特征[J].西安地质学院学报,1994,16(1):12-17. Han Zhaoxin. The Typomorphic Characteristic of the Sphalerite in the Qinling Devonian System Lead-Zinc Metallogenic Belt[J]. Journal of Xi’ an College of Geology, 1994, 16(1):12-17.
[47] 蔡劲宏,周卫宁,张锦章.江西银山铜铅锌多金属矿床闪锌矿的标型特征[J]. 桂林工学院学报,1996,16(4):370-375. Cai Jinhong, Zhou Weining, Zhang Jinzhang. Typomorphic Characteristics of Sphalerites in the Yinshan Copper, Lead and Zinc Polymetallic Deposit, Jiangxi[J]. Journal of Guilin Institute of Technology, 1996, 16(4): 370-375.
[48] Ghaderi M, Palin J M, Sylvester P J, et al. Rare Earth Element System Atics in Scheelite from Hydrothermal Gold Deposits in the Kalgoorlie-Norseman Region, Western Australia[J]. Econ Geol, 1999, 94: 423-438.
[49] Meinert L D, Dipple G M, Nicolescu A S. World Skarn Deposits[J]. Society of Economic Geologists, 2005, 100:299-336.
[50] 朱赖民,袁海华,栾世伟.金阳底苏会东大梁子铅锌矿床内闪锌矿微量元素标型特征及其研究意义[J].四川地质学报,1995,15(1):49-55. Zhu Laimin, Yuan Haihua, Luan Shiwei. Typomorphic Characteristics and Their Significance of Minor Elements of Sphalerite from Disu and Daliangzi Pb-Zn Deposits, Sichuan[J]. Acta Geologica Sichuan, 1995, 15(1): 49-55.
[51] 李开文,张乾,王大鹏,等. 云南蒙自白牛厂多金属矿床锡石原位LA-MC-ICP-MS U-Pb年代学[J]. 矿物学报,2013,3(2):523-528. Li Kaiwen, Zhang Qian, Wang Dapeng, et al. LA-MC-ICP-MS U-Pb Geochronology of Cassiterite from the Bainiuchang Polymetallic Deposit, Yunnan Province, China [J]. Acta Mineralogica Sinica, 2013, 3(2): 523-528.
[52] 程彦博,毛景文,陈小林,等. 滇东南薄竹山花岗岩的LA-ICP-MS锆石U-Pb定年及地质意义[J]. 吉林大学学报(地球科学报),2010,40(4): 869-878. Cheng Yanbo, Mao Jingwen, Chen Xiaolin, et al. LA-ICP-MS Zircon U-Pb Dating and the Bozhushan Granite in Southeastern Yunnan Province and Its Significance[J]. Journal of Jilin University(Earth Science Edition), 2010, 40(4): 869-878.
[53] 石学法,李兵,鄢全树,等.西太平洋岛弧-弧后盆地热液活动及成矿作用[J].吉林大学学报(地球科学版),2016,46(4):1124-1138. Shi Xuefa, Li Bing, Yan Quanshu, et al. Hydrothermal Activities and Mineralization in the Arc and Back-Arc Basin Systems, Western Pacific[J]. Journal of Jilin University (Earth Science Edition), 2016, 46(4): 1124-1138.
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