Journal of Jilin University(Earth Science Edition) ›› 2021, Vol. 51 ›› Issue (1): 81-94.doi: 10.13278/j.cnki.jjuese.20190117

Previous Articles    

Source of Ore-Forming Materials in Taoyuan Pb-Zn Deposit in Liaoning Province: Characteristics of S and Pb Isotopic Compositions

Lin Chenggui1,2, Yao Xiaofeng1,2, Cheng Zhizhong1,2, Yan Tingjie1,2, Li Shenghui3, Wang Wei3   

  1. 1. Development Research Center, China Geological Survey, Beijing 100037, China;
    2. Mineral Exploration Technical Guidance Center, Ministry of Natural Resources, Beijing 100083, China;
    3. 103 Brigade of Non-Ferrous Geological Bureau of Liaoning Province, Dandong, 118008, Liaoning, China
  • Received:2019-06-02 Published:2021-02-02
  • Supported by:
    Supported by the National Key R&D Program of China(2018YFC0603806) and the Project of China Geological Survey (DD20160052)

PDF (PC)

214

Abstract: Taoyuan Pb-Zn deposit is a newly discovered medium-sized Pb-Zn deposit in the central section of Qingchengzi ore concentration area in eastern Liaoning Province. The orebodies occur in the paleoproterozoic Dashiqiao Formation of Liaohe Group, which is controlled by the strata and fractures obviously. Due to the lack of research on the ore-forming material sources of the deposit, the genesis of the deposit is still unclear. Based on the field investigation and microscopic observation, the S and Pb isotopic characteristics of Taoyuan Pb-Zn deposit were studied in detail. The analysis results of sulfides show that the δ34S values of the sulfides from Taoyuan Pb-Zn deposit range from 3.5‰ to 8.9‰, with an average of 5.5‰, which indicates the characteristics of mantle source sulfur; the Pb isotopic ratios of 206Pb/204Pb are 17.969-18.309, with an average of 18.076; the Pb ratios of 207Pb/204Pb are 15.572-15.669, with an average of 15.617, and those of 208Pb/204Pb are 38.222-38.371, with an average of 38.312. The μ values range from 9.46 to 9.62 (average 9.55), most of them are lower than those of normal Earth. On the Pb isotopic discrimination diagram, the Pb isotopic values are located between the crust and mantle Pb isotopic evolution lines, showing the mixing characteristics of crust and mantle. The S and Pb isotopic compositions of Taoyuan Pb-Zn deposit are similar to those of Qingchengzi Pb-Zn-Au-Ag deposit and Indosinian intrusive rocks, indicating that the ore-forming hydrothermal fluid came from deep magma, but obviously different from those of the Liaohe Group surrounding rocks. It is concluded that Taoyuan Pb-Zn deposit is a magmatic hydrothermal type Pb-Zn deposit, which is related to the deep magmatic fluid activity.

Key words: S and Pb isotopic, source of ore-forming materials, Taoyuan Pb-Zn deposit, Qingchengzi ore concentration area, Liaodong area

CLC Number: 

  • P618.4
[1] Ma Yubo, Bagas Leon, Xing Shuwen, et al. Genesis of the Stratiform Zhenzigou Pb-Zn Deposit in the North China Craton:Rb-Sr and C-O-S-Pb Isotope Constraints[J]. Ore Geology Reviews, 2016, 79:88-104.
[2] Duan Xiaoxia, Zeng Qingdong, Wang Yongbin,et al. Genesis of the Pb-Zn Deposits of the Qingchengzi Ore Field, Eastern Liaoning, China:Constraints from Carbonate LA-ICP-MS Trace Element Analysis and C-O-S-Pb Isotopes[J]. Ore Geology Reviews, 2017, 89:752-771.
[3] 王玉往, 解洪晶, 李德东, 等. 矿集区找矿预测研究:以辽东青城子铅锌-金-银矿集区为例[J]. 矿床地质, 2017, 36(1):1-24. Wang Yuwang, Xie Hongjing, Li Dedong, et al. Prospecting Prediction of Ore Concentration Area Exemplified by Qingchengzi Pb-Zn-Au-Ag Ore Concentration Area, Eastern Liaoning Province[J]. Mineral Deposits, 2017, 36(1):1-24.
[4] Liu Jun, Liu Fuxing, Li Shenghui, et al. Genesis of the Xiaotongjiapuzi Gold Deposit of the Liaodong Gold Province, Northeast China:Fluid Inclusion Thermometry and S-Pb-H-O-He Isotope Constraints[J]. Geological Journal, 2019, 54(1):1-18.
[5] Liu Jun, Liu Fuxing, Li Shenghui, et al. Formation of the Baiyun Gold Deposit, Liaodong Gold Orovince, NE China:Constraints from Zircon U-Pb Age, Fluid Inclusion, and C-H-O-Pb-He Isotopes[J]. Ore Geology Reviews, 2019, 104:686-706.
[6] 方俊钦, 聂凤军, 张可, 等. 辽宁姚家沟钼矿床辉钼矿Re-Os同位素年龄测定及其地质意义[J]. 岩石学报, 2012, 28(2):372-378. Fang Junqin, Nie Fengjun, Zhang Ke, et al. Re-Os Isotopic Dating on Molybdenite Separates and Its Geological Dignificance from the Yaojiagou Molybdenum Deposit, Liaoning Province[J]. Acta Petrologica Sinica, 2012, 28(2):372-378.
[7] 张朋, 李斌, 李杰, 等. 辽东裂谷白云金矿载金黄铁矿Re-Os定年及其地质意义[J]. 大地构造与成矿学, 2016, 40(4):731-738. Zhang Peng, Li Bin, Li Jie, et al. Re-Os Isotopic Dating and Its Geological Implication of Gold Bearing Pyrite from the Baiyun Gold Deposit in Liaodong Rift[J]. Geotectonica et Metallogenia, 2016, 40(4):731-738.
[8] 陈冬, 张朋, 缪柏虎, 等. 青城子姚家沟钼矿床硫、铅同位素组成及其地质意义[J]. 有色金属, 2016, 68(3):25-33. Chen Dong,Zhang Peng, Miu Baihu, et al. Characteristics and Geological Significance of Sulfur and Lead Isotope Compositions of Yaojiagou Molybdenum Deposit in Qingchengzi[J]. Non-Ferrous Metal, 2016, 68(3):25-33.
[9] 邓功全. 辽东中部辽河群层控铅锌矿床类型及其主要控矿因素[J]. 辽宁地质学报, 1983, 1:53-70. Deng Gongquan. Types and Main Ore Controlling Factors of the Liaohe Group in the Middle of Liaodong[J]. Liaoning Acta Geologica Sinica, 1983, 1:53-70.
[10] 王郁, 金成洙, 关广岳. 辽宁青城子铅锌矿田成矿机理研究[J]. 地质与勘探, 1985, 3(9):10-14. Wang Yu, Jin Chengzhu, Guan Guangyue. Study on Ore-Forming Mechanism of Qingchengzi Lead-Zinc Deposit Liaoning Province[J]. Geology and Exploration, 1985, 3(9):10-14.
[11] 蒋少涌. 辽宁青城子铅锌矿床的铅同位素组成及其地质特征[J]. 北京大学学报(自然科学版), 1987,23(4):112-119. Jiang Shaoyong. Pb-Isotope Composition at Qingchengzi Lead-Zinc Deposit and Its Geological Application[J]. Universitatis Pekinensis(Acta Scientiarum Naturalium), 1987,23(4):112-119.
[12] 蒋少涌. 辽宁青城子铅-锌矿床氧、碳、铅、硫同位素地质特征及矿床成因[J].地质论评, 1988,34(6):515-523. Jiang Shaoyong. Atable Isotope Geological Characteristics of Oxygen, Carbon, Lead, and Surfur and Metallogenesis of the Qingchengzi Lead-Zinc Deposit, Liaoning Province[J]. Geological Review, 1988,34(6):515-523.
[13] 蒋少涌, 魏菊英. 青城子铅锌矿床的地球化学[J]. 矿床地质, 1989, 8(4):20-28. Jiang Shaoyong,Wei Juying. Geochemistry of the Qingchengzi Lead-Zinc Deposit[J]. Mineral Deposits, 1989, 8(4):20-28.
[14] Chen Jiangfeng, Yu Gang, Xue Chunji, et al. Pb Isotope Geochemistry of Lead, Zinc, Gold and Silver Deposit Clustered Region, Liaodong Rift Zone, Northeastern China[J]. Science in China:Series D, 2005, 48(4):467-476.
[15] 刘红霞, 孔含泉, 杨言辰. 辽宁小佟家堡子金矿床地质特征及成因研究[J]. 黄金, 2006, 27(5):13-16. Liu Hongxia, Kong Hanquan, Yang Yanchen. Geologic Characteristics and Genesis of Xiaotongjiapuzi Gold Deposit, Liaoning Province[J]. Gold, 2006, 27(5):13-16.
[16] 沙德喜, 刘洪津, 李国树. 辽宁省青城子铅锌矿田成矿特征与矿床成因探讨[J]. 地质与资源, 2011, 20(4):258-264. Sha Dexi, Liu Hongjin, Li Guoshu. Discussion on the Metallogeny and Genesis of the Lead-Zinc Deposis in Qingchengzi Orefield, Liaoning Province[J]. Geology and Resources, 2011, 20(4):258-264.
[17] 王秀福, 刘培栋, 杨桂莲, 等. 青城子铅锌矿田地质特征[J]. 有色矿冶, 2010, 26(2):2-6,21. Wang Xiufu, Liu Peidong, Yang Guilian, et al. Analyzing the Geological Features of the Qingchengzi Pb-Zn Ore Field[J]. Non-Ferrousmining and Metallurgy, 2010, 26(2):2-6,21.
[18] 刘国平, 艾永富. 辽宁小佟家堡子金矿床成矿时代探讨[J]. 矿床地质, 2002, 21(3):53-57. Liu Guoping, Ai Yongfu. Study on Ore-Forming Epoch of Xiaotongjiapuzi Gold Deposit, Liaoning Province[J]. Mineral Deposits, 2002, 21(3):53-57.
[19] 薛春纪, 陈毓川, 路远发, 等. 辽东青城子矿集区金、银成矿时代及地质意义[J]. 矿床地质, 2003, 22(2):177-184. Xue Chunji, Chen Yuchuan, Lu Yuanfa, et al. Metallogenic Epochs of Au and Ag Deposits in Qingchengzi Ore-Clustered Area, Eastern Liaoning Province[J]. Mineral Deposits, 2003, 22(2):177-184.
[20] Yu Gang, Chen Jiangfeng, Xue Chunji, et al. Geochronological Framework and Pb, Sr Isotope Geochemistry of the Qingchengzi Pb-Zn-Ag-Au Orefield, Northeastern China[J]. Ore Geology Reviews, 2009, 35:367-382.
[21] Duan Xiaoxia, Zeng Qingdong, Wang Yongbin, et al. Sources of Qingchengzi Pb-Zn Orefield:Implications from Pb Isotope[J]. Acta Geologica Sinica (English Edition), 2014, 88(Sup.2):1604-1606.
[22] 杨凤超, 宋运红, 张朋, 等. 辽宁青城子矿集区金银矿成矿流体特征和成矿物质来源示踪[J]. 地质学报, 2016, 90(10):2775-2785. Yang Fengchao, Song Yunhong, Zhang Peng,et al. Forming Fluid Characterisitics and Tracing of Ore-Forming Source Materials of Gold-Silver Deposit in the Qingchengzi Ore Concentration Area[J]. Acta Geologica Sinica, 2016, 90(10):2775-2785.
[23] 宋运红, 杨凤超, 闫国磊, 等.辽宁青城子铅锌矿成矿流体特征和成矿物质来源示踪[J]. 地质与勘探, 2017, 53(2):259-269. Song Yunhong, Yang Fengchao, Yan Guolei, et al. Characteristics of Mineralization Fluids and Tracers of Mineralization Material Sources of the Qingchengzi Lead-Zinc Deposit in Liaoning Province[J]. Geology and Exploration, 2017, 53(2):259-269.
[24] 郝立波, 赵昕, 赵玉岩. 辽宁白云金矿床稳定同位素地球化学特征及矿床成因[J]. 吉林大学学报(地球科学版), 2017, 47(2):442-451. Hao Libo, Zhao Xin, Zhao Yuyan. Stable Isotope Characteristics and Ore Genesis of the Baiyun Gold Deposis, Liaoning Province[J]. Journal of Jinlin University(Earth Science Edition), 2017, 47(2):442-451.
[25] 周国超, 王玉往, 李德东, 等. 辽东白云金矿区脉岩锆石的U-Pb年代学研究[J]. 矿物岩石地球化学通报, 2017, 36(4):620-627. Zhou Guochao, Wang Yuwang, Li Dedong, et al. LA-ICP-MS Zircon U-Pb Dating of Dykes from the Baiyun Gold Deposit in Eastern Liaoning[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2017, 36(4):620-627.
[26] 宋运红, 郝立波, 杨凤超. 辽宁青城子铅锌金银矿矿集区围岩原岩恢复及其构造背景[J]. 地质与资源, 2015, 24(3):205-214. Song Yunhong, Hao Libo, Yang Fengchao. Protolith Restoration and Tectonic Setting of the Wall Rocks in the Qingchengzi Lead-Zinc-Gold-Silver Ore Concentration Area in Liaoning Province[J]. Geology and Resources, 2015, 24(3):205-214.
[27] 张秋生. 辽东半岛早元古宙地壳的演化[J]. 中国地质科学院院报, 1987, 9(2):155-163. Zhang Qiusheng. Early Proterozoic Crustal Evolution of the East Liaoning Peninsula[J]. Bulletin of the Chinese Academy of Geological Sciences, 1987, 9(2):155-163.
[28] 段晓侠, 刘建明, 王永彬, 等. 辽宁青城子铅锌多金属矿田晚三叠世岩浆岩年代学、地球化学及地质意义[J]. 岩石学报, 2012, 28(2):595-606. Duan Xiaoxia, Liu Jianming, Wang Yongbin, et al. Geochronology, Geochemistry and Geological Significance of Late Triassic Magmatism in Qingchengzi Orefield, Liaoning[J]. Acta Petrologica Sinica, 2012, 28(2):595-606.
[29] 杨凤超, 宋运红, 郝立波, 等. 辽东三家子地区晚侏罗世花岗岩SHRIMP U-Pb年龄、Hf同位素特征及地质意义[J]. 地质学报, 2015, 89(10):1773-1782. Yang Fengchao, Song Yunhong, Hao Libo, et al. Late Jurassic SHRIMP U-Pb Age and Hf Isotopic Characteristics of Granite from the Sanjiazi Area in Liaodong and Their Geological Significance[J]. Acta Geologica Sinica, 2015, 89(10):1773-1782.
[30] 董存杰, 张洪涛, 张宝琛. 青城子铅锌矿床成因分析[J]. 地质与勘探, 2010, 46(1):59-69. Dong Cunjie, Zhang Hongtao, Zhang Baochen. Analysis of the Metallogenesis of Qingchengzi Pb-Zn Ore Deposit[J]. Geology and Exploration, 2010, 46(1):59-69.
[31] 刘志远, 徐学纯. 辽东青城子金银多金属成矿区综合信息找矿模型及找矿远景分析[J]. 吉林大学学报(地球科学版), 2007, 37(3):437-443. Liu Zhiyuan, Xu Xuechun.Synthetic Information Models and Analyses of Prospecting Perspective of the Qingchengzi Polymetal Metallogenic Mine in Eastern Liaoning Province[J]. Journal of Jilin University(Earth Science Edition), 2007, 37(3):437-443.
[32] 伍登浩, 高顺宝, 郑有业, 等. 西藏班公湖-怒江成矿带南侧矽卡岩型铜多金属矿床S、Pb同位素组成及成矿物质来源[J]. 吉林大学学报(地球科学版), 2018, 48(1):70-86. Wu Denghao, Gao Shunbao, Zheng Youye, et al. Sulfur and Lead Isotopic Composition and Their Ore-Forming Material Source of Skarn Copper Polymetallic Deposits in Southern Tibet Bangonghu-Nujiang Metallogenic Belt[J]. Journal of Jilin University (Earth Science Edition), 2018, 48(1):70-86.
[33] Ohmoto H, Rye R D. Isotopes of Sulfur and Carbon[C]//Barnes H L. Geochemistry of Hydrothermal Ore Deposits. New York:Wiley, 1979:509-567.
[34] Ohmoto H. Systematics of Sulfur and Carbon Isotopes in Hydrothermal Ore Deposits[J]. Economic Geology, 1972, 67(5):551-578.
[35] Ohmoto H. Stable Isotope Geochemistry of Ore Deposits[J]. Reviews in Mineralogy and Geochemistry, 1986, 16(1):491-559.
[36] 赵广繁, 孙立民. 青城子矿田小佟家堡子金矿床地质特征及成因机制[J]. 有色金属矿产与勘查, 1997, 6(4):21-26. Zhao Guangfan, Sun Limin. Geology and Ore Forming Mechanism of the Xiaotongjiapuzi Gold Deposit, Qingchengzi[J].Geological Exploration for Non-Ferrous Metals, 1997, 6(4):21-26.
[37] 迟永坤. 青城子矿田成矿元素地球化学特征[J]. 地质与资源, 2002, 11(2):109-118. Chi Yongkun. Geochemical Characteristics of Ore-Forming Elements of the Qingchengzi Orefield[J]. Geology and Resources, 2002, 11(2):109-118.
[38] 丁悌平, 蒋少涌, 万德芳, 等. 华北元古宙铅锌成矿带稳定同位素研究[M]. 北京:科学技术出版社, 1992:36-60. Ding Tiping, Jiang Shaoyong, Wan Defang,et al. Stable Isotope Studies on the Proterozoic Pb-Zn Mineral Belt of Northern China[M]. Beijing:Science and Technology Publishing House, 1992:36-60.
[39] 陈江峰, 喻钢, 薛春纪. 辽东裂谷带铅锌金银矿集区Pb同位素地球化学[J]. 中国科学:D辑:地球科学版, 2004, 34(5):404-411. Chen Jiangfeng, Yu Gang, Xue Chunji. Liaodong Rifting with Lead-Zinc and Silver Ore District Pb Isotope Geochemistry[J]. Science in China:Series D:Earth Science, 2004, 34(5):404-411.
[40] 李金祥, 邓军, 吴文根, 等. 山东招远金矿集中区矿床及围岩中硫和铅同位素的研究[J]. 现代地质, 2004, 18(2):187-192. Li Jinxiang, Deng Jun, Wu Wengen, et al. Study on the Sulfur-Lead Isotope of Zhaoyuan Gold Mineralization Area and Wall Rocks[J]. Geoscience, 2004, 18(2):187-192.
[41] 梁婷, 王登红, 蔡明海, 等. 广西大厂锡多金属矿床S、Pb同位素组成对成矿物质来源的示踪[J]. 地质学报, 2008, 82(7):967-977. Liang Ting, Wang Denghong, Cai Minghai, et al. Sulfur and Lead Isotope Composition Tracing for the Sources of Ore-Forming Material in Dachang Tin-Polymentallic Orefield, Guangxi[J]. Acta Geologica Sinica, 2008, 82(7):967-977.
[42] Canals A, Cardellach E. Ore Lead and Sulphur Isotope Pattern from the Low-Temperature Veins of the Catalonian Coastal Ranges (NE Spain)[J]. Mineralium Deposit, 1997, 32(3):243-249.
[43] 侯明兰, 丁昕, 蒋少涌. 胶东蓬莱河西金矿床铅、硫同位素地球化学特征[J]. 地球学报, 2004, 25(2):145-150. Hou Minglan, Ding Xin, Jiang Shaoyong. Lead and Sulfur Isotope Geochemistry of the Hexi Gold Deposit in Penglai, Eastern Shandong[J]. Acta Geoscientica Sinica, 2004, 25(2):145-150.
[44] 蒋少涌, 杨涛, 李亮, 等. 大西洋洋中脊TAG热液区硫化物铅和硫同位素研究[J]. 岩石学报, 2006, 22(10):2597-2602. Jiang Shaoyong, Yang Tao, Li Liang, et al. Lead and Sulfur Isotopic Compositions of Sulfides from the TAG Hydrothermal Field, Mid-Atlantic Ridge[J]. Acta Petrologica Sinica, 2006, 22(10):2597-2602.
[45] Zartman R E, Doe B R. Plumb Tectonics:The Model[J]. Tectonophysics, 1981, 75(1/2):135-162.
[46] 朱炳泉. 地球科学中同位素体系理论与应用:兼论中国大陆壳幔演化[M]. 北京:科学出版社, 1998:1-330. Zhu Bingquan. The Theory and Practice of Isotope System in Geoscience:Concurrent Discussion of the Continental Crust and Mantle Evolvements in China[M]. Beijing:Science Press, 1998:1-330.
[47] 马玉波,邢树文,张增杰,等. 辽宁青城子榛子沟脉状铅锌矿成矿流体地球化学初探[J]. 矿床地质, 2012, 31(3):569-578. Ma Yubo, Xing Shuwen, Zhang Zengjie, et al. Preliminary Study of Geochemical Characteristics of Ore-Forming Fluid in Zhenzigou Veined Pb-Zn Deposit, Qingchengzi, Liaoning Province[J]. Mineral Deposit, 2012, 31(3):569-578.
[48] 芮宗瑶, 施林道, 方如恒. 华北陆块北缘及邻区有色金属矿床地质[M]. 北京:地质出版社, 1994:1-576. Rui Zongyao, Shi Lindao, Fang Ruheng. Geology of Non-Ferrous Deposits in North Margin of the North China Craton and Its Adjacent Areas[M]. Beijing:Geological Publishing House, 1994:1-576.
[1] XIE Lin, YANG Yu-long, GAO Wei, LIU Tie-Geng. Source of Ore-Forming Materials of Tongchang Copper Ore Deposit in Southern Shaanxi Province, China [J]. J4, 2012, 42(1): 92-103.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
Copyright © Journal of Jilin University(Earth Science Edition), All Rights Reserved.
Tel: +86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
Powered by Beijing Magtech Co. Ltd