Journal of Jilin University(Earth Science Edition) ›› 2019, Vol. 49 ›› Issue (4): 1121-1128.doi: 10.13278/j.cnki.jjuese.20180045

Previous Articles     Next Articles

Polymer Modified FeS Migration Performance in Saturated Porous Media

Hong Mei, Yang Huiping, Chen Shaoyin   

  1. Key Lab of Groundwater Resources and Environment(Jilin University), Ministry of Education, Changchun 130021, China
  • Received:2018-03-09 Online:2019-07-26 Published:2019-07-26
  • Supported by:
    Supported by National Natural Science Foundation of China (41530636) and Project Agreement for Science &Technology Development, Jilin Province (20150204045SF)

PDF (PC)

221

Abstract: Nano-FeS was modified by sodium carboxymethyl cellulose (CMC) and guar gum to improve its performance of stability and migration. The sedimentation properties, migration properties, and deposition rates of three kinds of ferrous sulfide (CMC-FeS, GG-FeS, and Nano-FeS) were studied experimentally. According to the theory of colloid filtration, the maximum migration distances of the three kinds of FeS in different media were calculated. The results showed that the anti-settling property was CMC-FeS > GG-FeS >> Nano-FeS, and the polymer improved the suspending stability of FeS. The penetration curves showed that the penetrating ability (the ratio of outflow concentration ρi to injection concentration ρ0) of the three kinds of FeS in three media was CMC-FeS > GG-FeS > Nano-FeS, and the penetration ability of CMC-FeS was higher than that of GG-FeS in coarse and medium sand, but was similar to that of GG-FeS in fine sand. It shows that the shear thinning property of guar gum is more conducive to the migration of GG-FeS in fine granular media. With the increase of FeS concentration,more FeS will be deposited in the medium, but polymer modification can significantly reduce the deposition rate:GG-FeS

Key words: FeS, porous media, FeS concentration, migration

CLC Number: 

  • X523
[1] Paknikar K M, Nagpal V, Pethkar A V, et al. Degradation of Lindane from Aqueous Solutions Using Iron Sulfide Nanoparticles Stabilized by Biopolymers[J]. Science and Technology of Advanced Materials, 2005, 6(3):370-374.
[2] 王夏琳, 李睿华. 利用FeS去除水中硝基苯的试验研究[J]. 环境科学, 2012, 33(12):4346-4351. Wang Xialin, Li Ruihua. Investigation of Nitrobenzene Removal by Iron Sulfide(FeS)[J]. Chinese Journal of Environmental Science, 2012, 33(12):4346-4351.
[3] 陈凡. 纳米FeS的制备及其在含铬污水处理中的应用研究[D]. 上海:同济大学, 2004. Chen Fan. Preparation of Iron Sulfide Nanoparticls and Study on Removal of Chromium(VI) from Wastewater[D]. Shanghai:Tongji University, 2004.
[4] Wolthers M, Charlet L, Weijden C H V D, et al. Arsenic Mobility in the Ambient Sulfidic Environment:Sorption of Arsenic(V) and Arsenic(Ⅲ) onto Disordered Mackinawite[J]. Geochimica et Cosmochimica Acta, 2005, 69(14):3483-3492.
[5] Zhong Xiong, He Feng, Zhao Dongye, et al. Immobilization of Mercury in Sediment Using Stabilized Iron Sulfide Nanoparticles[J]. Water Research, 2009, 43(20):5171-5179.
[6] Zhao Xiao, Liu Wen, Cai Zhengqing, et al. An Overview of Preparation and Applications of Stabilized Zero-Valent Iron Nanoparticles for Soil and Groundwater Remediation[J]. Water Research, 2016, 100:245-266.
[7] Cushing B L, Kolesnichenko V L, Charles J O. Recent Advances in the Liquid-Phase Syntheses of Inorganic Nanoparticles[J]. Chemical Reviews, 2004, 104(9):3893-3946.
[8] He Feng, Zhao Dongye. Manipulating the Size and Dispersibility of Zerovalent Iron Nanoparticles by Use of Carboxymethyl Cellulose Stabilizers[J]. Environmental Science and Technology, 2007, 41(17):6216-6221.
[9] Mitzel M R, Tufenkji N. Transport of Industrial PVP-Stabilized Silver Nanoparticles in Saturated Quartz Sand Coated with Pseudomonas Aeruginosa PAO1 Biofilm of Variable Age[J]. Environmental Science and Technology, 2014,48(5):2715-2723.
[10] Alberto T, Loon C K, Rajandrea S, et al. Reduced Aggregation and Sedimentation of Zero-Valent Iron Nanoparticles in the Presence of Guar Gum[J]. Journal of Colloid and Interface Science, 2008, 3249(1):71-79.
[11] 董军, 徐暖, 刘同喆, 等. 乳化植物油强化土著微生物修复中高浓度Cr(Ⅵ)污染地下水[J]. 吉林大学学报(地球科学版), 2018, 48(1):234-240. Dong Jun, Xu Nuan, Liu Tongzhe, et al. Indigenous Microbial Remediation of Middle-High Concentration Cr(Ⅵ) Contaminated Groundwater Enhanced by Emulsified Vegetable Oil[J]. Journal of Jilin Unviersity(Earth Science Edition), 2018, 48(1):234-240.
[12] He Feng, Zhang Man, Qian Tianwei, et al. Transport of Carboxymethyl Cellulose Stabilized Iron Nanoparticles in Porous Media:Column Experiments and Modeling[J]. Journal of Colloid and Interface Science, 2009, 334(1):96-102.
[13] He Feng, Zhao Dongye, Liu Juncheng, et al. Stabilization of Fe-Pd Nanoparticles with Sodium Carboxymethyl Cellulose for Enhanced Transport and Dechlorination of Trichloroethylene in Soil and Groundwater[J]. Industrial and Engineering Chemistry Research, 2007, 46(1):29-34.
[14] Zhong Xiong, He Feng, Zhao Dongye. Immobilization of Mercury in Sediment Using Stabilized Iron Sulfide Nanoparticles[J]. Water Research, 2009, 43(20):5171-5179.
[15] Wang Xianbiao, Liu Jin, Zhao Donglin, et al. Preparation of CMC-Stablized FeS Nanoparticles and Their Enhanced Performance for Cr(VI) Removal[J]. Advanced Materials Research, 2011, 287:96-99.
[16] Chen Juan, Chen Ri, Hong Mei. Influence of pH on Hexavalent Chromium Reduction by Fe(Ⅱ) and Sulfide Compounds[J]. Water Sci Technol, 2015,72(1):22-28.
[17] Gong Yanyan, Liu Yuanyuan, Zhong Xiong, et.al. Immobilization of Mercury in Field Soil and Sediment Using Carboxymethyl Cellulose Stabilized Iron Sulfide Nanoparticles[J]. Nanotechnology, 2012, 23(29):294007-294019.
[18] 刘伟. 瓜尔豆胶稳定纳米铁的制备及其去除水体中六价铬的研究[D]. 天津:南开大学, 2013. Liu Wei. Synthesis of Guar Gum Stabilized Nanoscale Zero-Valent Iron and Application for Cr(Ⅵ)Removal in Water[D]. Tianjin:Nankai University, 2013.
[19] 乐兰. 绿色聚合物改性纳米零价铁及其对六价铬去除[D]. 昆明:昆明理工大学, 2016. Le Lan.Green Polymer Modified Nano Zero Valent Iron for Removal of Chromium (Ⅵ)[D]. Kunming:Kunming University of Science and Technology, 2016.
[20] Alberto T, Rajandrea S. Enhanced Transport of Zerovalent Iron Nanoparticles in Saturated Porous Media by Guar Gum[J]. Journal of Nanoparticle Research, 2009, 11:635-645.
[21] Velimirovic M, Simons Q, Bastiaens L. Guar Gum Coupled Microscale ZVI for in Situ Treatment of CAHs:Continuous-Flow Column Study[J]. Journal of Hazardous Materials, 2014, 265:20-29.
[22] Velimirovic M, Tosco T, Uyttebroek M, et al. Field Assessment of Guar Gum Stabilized Microscale Zerovalent Iron Particles for In-Situ Remediation of 1,1,1-Trichloroethane[J]. Journal of Contaminant Hydrology, 2014, 164:88-99.
[23] Gastone F, Tosco T, Sethi R. Guar Gum Solutions for Improved Delivery of Iron Particles in Porous Media:Part 1:Porous Medium Rheology and Guar Gum-Induced Clogging[J]. Journal of Contaminant Hydrology, 2014, 166:23-33.
[24] Kerzschmar R, Barmettler K, Grolimund D, et al. Experimental Determination of Colloid Deposition Rates and Collision Efficiencies in Natural Porous[J]. Water Resource Research, 1997, 33(5):1129-1137.
[25] Leconanet H F, Bottero J Y, Wiesner M R. Laboratory Assessment of the Mobility of Nanomaterials in Porous Media[J]. Environmental Science and Technology, 2004, 38(19):5164-5169.
[26] Rajagopalan R, Tien C. Comment on Correlation Equation for Predicting Single-Collector Efficiency in Physicochemical Filtration in Saturated Porous Media[J]. Environmental Science and Technology, 2005,39(14):5494-5495.
[27] Yao K M, Habibian M T, O'Melia C R. Water and Waste Filtration, Concepts and Applications[J]. Environmental Science Teehnology, 1971, 5(11):1105-1112.
[28] 苏燕. 包气带NAPLs污染的表面活性剂泡沫强化修复实验研究[D]. 吉林:吉林大学, 2015. Su Yan. Study on Enhanced Remediation of NAPLs Contaminated Vadose Zone with Surfactant Foams[D]. Jilin:Jilin University, 2015.
[1] Zhou Jinju, Wang Deli, Li Bowen, Li Qiang, Wang Rui. Application of Wavefield Decomposition Based on Decoupled Propagation in Elastic RTM for VTI Media [J]. Journal of Jilin University(Earth Science Edition), 2018, 48(3): 909-921.
[2] Shan Gangyi, Han Liguo, Zhang Lihua. Pre-Stack Depth Migration Based on Model Confined Kirchhoff Integration [J]. Journal of Jilin University(Earth Science Edition), 2018, 48(2): 379-383.
[3] Zhang Huanxu, Chen Shijia, Lu Jungang, Liu Chaowei, Chen Juan, Li Yong, Xu Kun. Migration of Oil in Tight Sandstones:Discussion from the Dynamics [J]. Journal of Jilin University(Earth Science Edition), 2017, 47(5): 1341-1351.
[4] Liu Junqiao, Lü Yanfang, Fu Guang, Sun Tongwen, Li Jiaxing. Transporting Models of Oil-Gas Migration by Normal Fault and Its Controlling Effect to Oil-Gas Distribution [J]. Journal of Jilin University(Earth Science Edition), 2016, 46(6): 1672-1683.
[5] Wei Danning, Fu Guang. Quantitative Explanation of Mechanism About Lower Wall of Antithetic Faults Accumulating More Oil-Gas than Upper Wall of Consequent Faults [J]. Journal of Jilin University(Earth Science Edition), 2016, 46(3): 702-710.
[6] Wang Jianjun, Li Haowu, Hu Xiangyu, Wang Qing, Wang Bin, Yang Cang. Geological Characteristics and Hydrocarbon Accumulation of Ucayali Basin, Peru [J]. Journal of Jilin University(Earth Science Edition), 2016, 46(3): 639-650.
[7] Chen Suihai, Han Runsheng, Shentu Liangyi, Wu Peng, Qiu Wenlong, Wen Dexiao. Alteration Zoning and Geochemical Element Migration in Alteration Rock of Zhaotong Lead-Zinc Deposit in Northeastern Yunnan Mineralization Concentration Area [J]. Journal of Jilin University(Earth Science Edition), 2016, 46(3): 711-721.
[8] Han Wei, Ren Zhanli, Lu Jincai, Wei Jianshe, Zhang Yunpeng. Discussion on Hydrocarbon Migration Based on Characteristics of Inclusions in Carboniferous- Permian of Yin'e Basin [J]. Journal of Jilin University(Earth Science Edition), 2015, 45(5): 1342-1351.
[9] Wu Juan, Chen Xiaohong, Bai Min. Viscoacoustic Gaussian Beam Prestack Depth Migration [J]. Journal of Jilin University(Earth Science Edition), 2015, 45(5): 1530-1538.
[10] Lü Yanfang, Wei Danning, Sun Yonghe, Hu Ming, Liu Zhe, Sun Tongwen, Wang Haixue, Xu Chenlu. Control Action of Faults on Hydrocarbon Migration and Accumulation in the Middle and Upper Oil-Bearing Group in Nanpu Sag [J]. Journal of Jilin University(Earth Science Edition), 2015, 45(4): 971-982.
[11] Li Yang, Wang Qing, Wang Tanhua. Numerical Solution and Test of Results for a Hydrothermal Coupled Model About Frozen Soil [J]. Journal of Jilin University(Earth Science Edition), 2015, 45(1): 207-213.
[12] Zhang Zhenbo, Xuan Yihua, Liu Bin. The  Pre-Stack Seismic Data Proc4 Structure [J]. Journal of Jilin University(Earth Science Edition), 2014, 44(3): 1031-1038.
[13] Ren Xianjun，Shan Xuanlong，Wang Jianbo. Recognition of Oil Accumulation in Putaohua Oil Layer of the Shangjia Oilfield，Songliao Basin [J]. Journal of Jilin University(Earth Science Edition), 2014, 44(1): 38-44.
[14] Huang Jianping，Xue Zhiguang，Bu Changcheng，Li Zhenchun，Wang Changbo, Gao Guochao，Cao Xiaoli， Li Guolei. The Study of Least-Squares Migration Method Based on Split-Step DSR [J]. Journal of Jilin University(Earth Science Edition), 2014, 44(1): 369-374.
[15] Feng Chong，Huang Zhilong，Tong Chuanxin，Zhu Jiancheng，Zou Huayao，Fan Hongche. Overpressure Evolution and Its Relationship with Migration and Accumulation of Gas in Yinggehai Basin [J]. Journal of Jilin University(Earth Science Edition), 2013, 43(5): 1341-1350.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
[1] KUANG Li-xiong,GUO Jian-hua, MEI Lian-fu, TONG Xiao-lan, YANG Li. Study on the Upheaval of the Bogeda Mountain Block from Angle of Oil and Gas Exploration[J]. J4, 2005, 35(03): 346 -0350 .
[2] ZHANG Guang-xin, DENG Wei, HE Yan, RAMSIS Salama. An Application of Hydrological Response Units in Assessment of Soil Salinization Risks[J]. J4, 2005, 35(03): 356 -0360 .
[3] XUE Yong-chao，CHENG Lin-song，FU Guang. Comprehensive Evaluation of Gas Sealing Ability of the Lower DengloukuFormation (K1d2) Mudstone Caprock in the East of the Daqing Placanticline[J]. J4, 2005, 35(05): 626 -631 .
[4] TANG Jian-sheng, XIA Ri-yuan, ZOU Sheng-zhang, LIANG Bin. Characteristics of Karst Medium System and Its Hydrogeologic Effect in the South Tianshan, Xinjiang[J]. J4, 2005, 35(04): 481 -0486 .
[5] QIN Li-juan, CAO Jian-feng,PING Jian-hua,JIANG Ji-yi, WANG Nan, SHEN Yuan-yuan, LI Sheng. Application of Fuzzy Mathematics in Evaluation of Water Resources Value in Zhengzhou City[J]. J4, 2005, 35(04): 487 -0490 .
[6] HUANG Ji-guo, WEI Hai-juan,WANG Li-jun，WANG Tie-jun,YU Shuang, HUANG Guo-xin. Beer Wastewater Treatment Using Three-Phase Biofluidized Bed[J]. J4, 2005, 35(04): 510 -0514 .
[7] ZHAO Xing-min, HUA Xiu-yi, ZHANG Jing-jing, DONG De-ming, LI Yu. Selective Extraction of Fe and Mn Oxides from Biofilms Collected in Natural Waters[J]. J4, 2005, 35(04): 505 -0509 .
[8] XIONG Bin. Inverse Spline Interpolation for the Calculation of All-Time Resistivity for the Large-Loop Transient Electromagnetic Method[J]. J4, 2005, 35(04): 515 -0519 .
[9] QIN Ru-fu, XU Hui-ping, YE Na,OU Shao-jia，LU Yan. Management System Design of China Lithosphere 3D Structure Database Based on GIS[J]. J4, 2005, 35(04): 529 -0534 .
[10] YU Ping， LI Rui-lei， FU Lei， HAO Xue， ZHANG Xiang-jun，LIAN Guo-fen. Regional Tectonic Characteristics and Significance of North Harbin Area in Songliao Basin: Evidenced from Long Seismic Profiles[J]. J4, 2005, 35(05): 611 -615 .
Copyright © Journal of Jilin University(Earth Science Edition), All Rights Reserved.
Tel: +86-431-88502374；13756165364　E-mail: xuebao1956@jlu.edu.cn
Powered by Beijing Magtech Co. Ltd