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Characteristics of Fluid Inclusions and Metallogenic Model of Tianbaoshan Polymetallic Ore Field,Yanbian,China
Zhang Yong, Sun Jing-gui, Chen Dong, Xing Shu-wen, Song Quan-heng, Zhao Zhi,Zhao Ke-qiang, Bai Ling-an, Han Shi-jiong
Journal of Jilin University(Earth Science Edition). 2012, 42 (6):
1665-1675.
The Tianbaoshan polymetallic ore field is composed of Xinxing lead-zinc deposit, Lishan lead-zinc-copper deposit and Dongfeng lead-zinc-copper-molybdenum deposit. Both Xinxing and Lishan are hosted in contact zone between Jurassic granodiorite, diorite and Paleozoic marine volcanic rocks-sedimentary rock and the Dongfeng deposit occurs in rock bodies. The research on the geological features of these ore deposits shows that the Xinxing lead-zinc deposit is featured by filling of quartz sulfide in breccia pipe, similar to alteration characteristics of the mesothermal magmatic ore deposit; Dongfeng lead-zinc-copper-molybdenum deposit develops disseminated sulfide orebodies, quartz sulfide veins and molybdenite-quartz vein, showing characteristic of contact metasomatic-hydrothermal deposit; while a lot of magnetite, galena, sphalerite and other metal sulfides are found in Xinxing lead-zinc deposit, which suggests it be a representative contact metasomatic skarn deposit. Based on the research of fluid inclusions in quartz from main mineralizing stages and late ore-forming stage, it can be concluded that ore-forming process of the Xinxing deposit can be divided into three stages, quartz-pyrite, quartz-sphalerite-galena-chalcopyrite and quartz-carbonate. Homogenization temperatures of fluid inclusion formed in these three atages are 270-340 ℃, 190-260 ℃, 130-160 ℃, respectively. The salinity(w(NaCl)) of the inclusion changes from 0.62% to 9.86%, the density from 0.37 g/cm3 to 1.00 g/cm3 and the pressure from 37.31 MPa to 87.69 MPa. Laser Raman spectroscopy analysis of the fluid inclusions reveals they mainly consist of CO2 and H2O, with minor CH4 and N2. The mineralization of the Dongfeng deposit went through three stages: quartz-molybdenite(280-337 ℃), quartz-sphalerite-galena-chalcopyrite(200-260 ℃) and quartz-carbonate(101-190 ℃), salinity and density of fluid inclusions for Dongfeng deposit range from 7.16% to 23.95%, and from 0.96 g/cm3 to 1.12 g/cm3, respectively, with the pressure raging from 28.23 MPa to 56.64 MPa, and analysis from Laser Raman spectroscopy shows the major compositions in the inclusions is H2O. The mineralization of the Lishan lead-zinc-copper deposit can be divided into three stages, they are magnetite-quartz(210-240 ℃), quartz-galena-sphalerite-chalcopyrite(170-200 ℃) and quartz-carbonate(126-160 ℃), salinity and density of fluid inclusions from that deposit range from 2.07% to 9.47%, and from 0.89 g/cm3 to 0.92 g/cm3, respectively, with the pressure of 33.88-59.72 MPa, the study on Laser Raman spectroscopy showes that the component of fluid inclusions is mainly composed of CO2 and CH4. Combined with the geological features of ore deposit, properties and sources of the metallogenic fluids, the metallogenic model of the Tianbaoshan polymetallic ore field has been constructed.
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