Me-MCP作直接甲醇燃料电池阴极催化剂

J4 ›› 2010, Vol. 48 ›› Issue (06): 1034-1038.

Me-MCP作直接甲醇燃料电池阴极催化剂

尹伟^1,2, 陈昌国^1,2, 法焕宝^1,3, 司玉军^2,4

1. 重庆大学化学与化工学院, 重庆 400030|2. 重庆大学材料科学与工程学院, 重庆 400030;3. 重庆大学生物工程学院, 重庆 400030|4. 四川理工学院化学与制药工程学院, 四川自贡 643000

收稿日期:2010-03-09 出版日期:2010-11-26 发布日期:2010-11-26
通讯作者: 陈昌国 E-mail:cgchen@cqu.edu.cn

Performance of MeMCP as Cathodic Catalyst inDirect Methanol Fuel Cell

YIN Wei^1,2, CHEN Changguo^1,2, FA Huanbao^1,3, SI Yujun^2,4

1. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China;2. School of Material Science and Engineering, Chongqing University, Chongqing 400030, China;3. College of Bioengineering, Chongqing University, Chongqing 400030, China|4. School of Chemistry andPharmaceutical Engineering, Sichuan University of Science &|Engineering, Zigong 643000, Sichuan Province, China

Received:2010-03-09 Online:2010-11-26 Published:2010-11-26
Contact: CHEN Changguo E-mail:cgchen@cqu.edu.cn

摘要/Abstract

摘要：

分别制备合成了碳载5单羧基10,15,20三苯基钴卟啉（CoMCP）、铁卟啉（FeMCP）、锰卟啉（MnMCP）、铜卟啉（CuMCP）和镍卟啉（NiM
CP）复合催化剂, 并通过线性电势扫描法研究该复合材料对氧还原的电催化性能和抗甲醇能力. 结果表明: MnMCP对氧还原有较高的电催化活性, 其氧还原起始电位为0.513 V, 催化性能最好; 其他金属复合材料按照CoMCP,FeMCP,CuMCP顺序降低, 而NiMCP的起始电位仅为0.198 V, 对氧还原的催化性能相对最弱; 在抗甲醇性能测试中, CoMCP,FeMCP,CuMCP,NiMCP的氧还原起始电位正移, 具有较好的抗甲醇能力.

关键词: 直接甲醇燃料电池；单羧基金属卟啉；催化氧还原；线性电势扫描(LSV)

Abstract:

Carbonsupported CoMCP,FeMCP,MnMCP,CuMCP,NiMCP as cathodic catalyst were prepared. And the performance of MeMCP electrocatalysts was investigated by linear sweep vol\|tammetry(LSV). The electrochemical measurements demonstrate that MeMCP catalysts have good catalytic activity. The initial potential of MnMCP is 0.513 V, which has better catalytic performance. However, the initial potential of NiMCP is 0.198 V, which is the lowest among the five central metal catalysts. DMFC test shows that CoMCP,FeMCP,CuMCP and NiMCP have good catalytic performance in the DMFC.

Key words: direct methanol fuel cell, MeMCP, catalytic oxygen reduction, linear sweep voltammetry(LSV)

中图分类号:

O646

尹伟, 陈昌国, 法焕宝, 司玉军. Me-MCP作直接甲醇燃料电池阴极催化剂[J]. J4, 2010, 48(06): 1034-1038.

YIN Wei, CHEN Chang-Guo, FA Huan-Bao, CI Yu-Jun. Performance of MeMCP as Cathodic Catalyst inDirect Methanol Fuel Cell[J]. J4, 2010, 48(06): 1034-1038.

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