镍铬合金表面的微弧氧化陶瓷膜对镍离子析出的影响

J4 ›› 2012, Vol. 50 ›› Issue (05): 1029-1032.

镍铬合金表面的微弧氧化陶瓷膜对镍离子析出的影响

于维先^1,2, 张玉凤³, 张影杰⁴, 张鑫佳², 王闻天⁵, 刘歆婵^{6 }

1. 吉林大学口腔医学院牙发育及颌骨重塑与再生省重点实验室, 长春 130021|2. 哈尔滨工业大学 |材料科学与工程学院, 哈尔滨 150090|3. 吉林大学口腔医学院修复科, 长春 130021|4. 吉林大学中日联谊医院手术室, 长春 130033|5. 吉林大学口腔医学院麻醉科, 长春 130021|6. 北华大学口腔医学院, 吉林吉林 132013

收稿日期:2011-09-21 出版日期:2012-09-26 发布日期:2012-09-29
通讯作者: 张影杰 E-mail:zhangyingjie@163.com

Effect of |Microarc Oxidation Ceramic Membrane on NiCr Alloy on the Release of Ni Ions

YU Weixian^1,2, ZHANG Yufeng³, ZHANG Yingjie⁴, ZHANG Xinjia², WANG Wentian⁵, LIU Xinchan^6

1. Laboratory of Mechanism of Tooth Development and Bone Remodeling and Regeration, School of Stomatology, Jilin University, |Changchun 130021, China|2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150090, China|3. Department of Prosthodontics, School of Stomatology, Jilin University, Changchun 130021, China|4. Department of Operating Room ChinaJapan Union Hospital, Jilin University, Changchun 130033, China|5. Department of Anesthesiology, School of Stomatology, Jilin University, Changchun 130021, China|6. School of Stomatology, Beihua University, Jilin 132013, Jilin Province, China

Received:2011-09-21 Online:2012-09-26 Published:2012-09-29
Contact: ZHANG Yingjie E-mail:zhangyingjie@163.com

摘要/Abstract

摘要：

采用微弧氧化技术, 以NaAlO₂和Na₅P₃O₁₀为电解液体系, 在镍铬合金表面制备微弧氧化陶瓷膜, 研究镍铬合金表面形成的微弧氧化陶瓷膜对镍离子析出的影响. 用扫描电子显微镜(SEM)及X射线衍射(XRD)对膜层进行表征, 用等离子体发射光谱仪及电化学方法检测成膜前后镍铬合金中镍离子在人工唾液中的析出量及合金的耐腐蚀性能. 实验结果表明, 镍铬合金表面形成的主晶相为γ-Al₂O₃的微弧氧化陶瓷膜可有效阻止镍离子析出, 提高了镍铬合金的耐腐蚀性能.

关键词: 镍铬合金, 微弧氧化, 陶瓷膜, 镍离子, 析出, 耐腐蚀性

Abstract:

The effect of microarc oxidation ceramic membrane on NiCr alloy on the release of Ni ions by means of microarc oxidation was studied with NaAlO₂and Na₅P₃O₁₀ as electrolytes. The membrane was characterized by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The corrosion resistance and the release of Ni ions from NiCr alloy were analyzed by electrochemical test and ICP-OES. The results indicate that the major crystalline phase on NiCr alloy is γ-Al₂O₃, which can prevent Ni ions from release and improve the corrosion resistance of NiCr alloy.

Key words: NiCr alloy, microarc oxidation, ceramic coating, Ni ion, release, corrosion resistance

中图分类号:

TB383

于维先, 张玉凤, 张影杰, 张鑫佳, 王闻天, 刘歆婵. 镍铬合金表面的微弧氧化陶瓷膜对镍离子析出的影响[J]. J4, 2012, 50(05): 1029-1032.

XU Wei-Xian, ZHANG Yu-Feng, ZHANG Ying-Jie, ZHANG Xin-Jia, WANG Wen-Tian, LIU Xin-Chan. Effect of |Microarc Oxidation Ceramic Membrane on NiCr Alloy on the Release of Ni Ions[J]. J4, 2012, 50(05): 1029-1032.

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