J4 ›› 2012, Vol. 50 ›› Issue (4): 822-827.

• 化学 • 上一篇    

水环境中共存重金属对不同固相物质吸附镉和铜的影响

董会军1, 花修艺1, 贺丽1,2, 董德明1, 徐志璐1, 梁大鹏1, 郭志勇1   

  1. 1. 吉林大学 地下水资源与环境教育部重点实验室, 水资源与水环境吉林省重点实验室, 环境与资源学院, 长春 130012;
    2. 吉林工业职业技术学院 质量与安全系, 吉林 吉林 132013
  • 收稿日期:2012-01-05 出版日期:2012-07-01 发布日期:2012-09-07
  • 通讯作者: 花修艺;董德明 E-mail:huaxy@jlu.edu.cn;dmdong@mail.jlu.edu.cn

Influence of Coexisting Heavy Metals on the Adsorption of Cadmium
and Copper onto Different Types of Solid Materials in Aquatic System  

DONG Huijun 1, HUA Xiuyi 1, HE Li 1,2, DONG Deming 1,
XU Zhilu 1, LIANG Dapeng 1, GUO Zhiyong 1   

  1. 1. Key Lab of Groundwater Resources and Environment of |Ministry of Education, Key Lab of Water Resources and Aquatic
    Environment of Jilin Province, College of Environment and Resources, Jilin University, Changchun 130012, China;
    2. Department of Quality and Safety, Jilin Vocational College of Industry and Technology, Jilin 132013, Jilin Province, China
  • Received:2012-01-05 Online:2012-07-01 Published:2012-09-07
  • Contact: HUA Xiuyi ;DONG Deming E-mail:huaxy@jlu.edu.cn;dmdong@mail.jlu.edu.cn

摘要:

 利用采集的固相物质(生物膜、 悬浮颗粒物和沉积物)模拟水环境中多种固相物质共存吸附体系, 研究共存金属对固相物质吸附镉和铜的影响.  结果表明, 各固相物质对镉的吸附均受共存金属(铜和铅)的抑制作用. 当悬浮颗粒物吸附镉时, 铜和铅的浓度增大, 对镉吸附的抑制程度增强; 当生物膜和沉积物吸附镉时, 铅浓度的增加使得铅抑制镉的吸附作用增强, 不同浓度的铜对镉吸附作用的抑制程度差别较小. 共存铅对铜吸附有抑制作用, 当铅浓度增加时, 3种固相物质吸附铜所受的抑制作用均增强, 而共存镉对铜的吸附影响较小. 即在重金属总浓度较低时, 重金属间的相互影响较小; 随着重金属总浓度的增加, 重金属间的相互影响增强. 共存金属浓度变化对悬浮颗粒物吸附铜和镉受到的抑制程度影响较大, 共存金属浓度越大, 共存金属对悬浮颗粒物吸附镉和铜的抑制作用越强.

关键词:  生物膜, 悬浮颗粒物, 沉积物, 竞争吸附, 重金属

Abstract:

The influence of co\|existing heavy metals on the adsorption of cadmium and copper onto solid phases was investigated by simulating aquatic multiphase system comprising three types of solid phases, including biofilms, suspended particulate materials and sediments, in the absence and presence of co\|existing heavy metals. The results indicate that co\|existing metals (copper and lead) reduced the adsorption of cadmium to all solid phases remarkably. Under  the conditions of the adsorption of cadmium onto suspended particulate materials, the reduction effects increased as the initial concentration of copper and le
ad increased. Under the conditions of the adsorption of cadmium to biofilm and sediments, increasing lead initial concentration enhanced the reduction effects on cadmium adsorption, but increasing copper initial concentration had little influence on the reduction effects. The co-existing lead reduced the adsorption of c
opper to solid materials and these reduction effects increased with the increase of lead concentration for all the solid materials, while the co-existing cadmium had only a little effect on copper adsorption. Overall, the mpetitive adsorption between heavy metals was insignificant at low concentrations, and enhanced with the increasing of the concentration of co-existing heavy metals. The concentration of co-existing metals influenced the reduction of the adsorption of copper and cadmium to suspended particulate materials. The greater the concentrations of co-existing heavy metals were, the stronger the reduction of the adsorption of
 cadmium and copper to suspended particulate materials was.

Key words:  biofilms, suspended particulate materials, sediments, competitive adsorption, heavy metals

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