吉林大学学报(理学版) ›› 2018, Vol. 56 ›› Issue (5): 1273-1277.

• 化学 • 上一篇    下一篇

自乳化环氧树脂成膜剂的制备

马晓坤, 冯旭, 李峰, 贾宏菲, 杨春才   

  1. 吉林化工学院 化学与制药工程学院, 吉林 吉林 132022
  • 收稿日期:2017-11-17 出版日期:2018-09-26 发布日期:2018-11-23
  • 通讯作者: 杨春才 E-mail:2941883707@qq.com

Preparation of Self-emulsifying Epoxy Resin Film-Forming Agent

MA Xiaokun, FENG Xu, LI Feng, JIA Hongfei, YANG Chuncai   

  1. School of Chemistry and Pharamaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, Jilin Province, China
  • Received:2017-11-17 Online:2018-09-26 Published:2018-11-23

摘要: 以环氧树脂为疏水基团, 聚乙二醇为亲水基团, 在三氟化硼乙醚作用下反应制备一种自乳化环氧树脂成膜剂, 并利用红外光谱、 扫描
电镜和激光粒度仪对其进行分析测试. 结果表明: 该成膜剂含有亲水的羟基和长链的环氧基团; 自乳化后的乳液粒度为70~150 nm; 该自乳化成膜剂稳定性良好, 其贮存稳定性可超过30 d; 离心3 h后的乳液仍保持稳定.

关键词: 自乳化, 环氧树脂, 乳液, 成膜剂

Abstract: A self-emulsifying epoxy resin film\|forming agent was prepared by using epoxy resin as hydrophobic group and polyethylene glycol as hydrophilic group under the action of boron trifluoride ethyl ether. The film-forming agent was analyzed by infrared spectrum, scanning electron microscope and laser particle size analyzer. The results show that film-forming agent contains hydrophilic hydroxyl and long chain epoxy groups. And the particle size of emulsion after self-emulsifying is 70—150 nm. The self-emulsifying film-forming agent has good stability, and its storage stability can be more than 30 d. The emulsion can remain stable after centrifugation for 3 h.

Key words: self-emulsifying, epoxy resin, emulsion, film-forming agent

中图分类号: 

  • O631