吉林大学学报(理学版) ›› 2025, Vol. 63 ›› Issue (4): 1212-1218.

• • 上一篇    

Y3+掺杂的钼酸铋钠电极制备及降解西地那非反应机理

孙嘉鸿1, 李佳依1, 付中东2, 王洪宁2, 冯威1   

  1. 1. 吉林大学 新能源与环境学院, 长春 130021; 2. 吉林省拓达环保设备工程有限公司, 长春 130062
  • 收稿日期:2024-09-18 出版日期:2025-07-26 发布日期:2025-07-26
  • 通讯作者: 冯威 E-mail:weifeng@jlu.edu.cn

Preparation of Y3+-Doped Sodium Bismuth Molybdate Electrode and  Degradation Mechanism of Sildenafil

SUN Jiahong1, LI Jiayi1, FU Zhongdong2, WANG Hongning2, FENG Wei1   

  1. 1. College of New Energy and Environment,  Jilin University,  Changchun 130021, China;  2. Jilin Tuoda Environmental Protection Equipment Engineering Co., Changchun 130062, China
  • Received:2024-09-18 Online:2025-07-26 Published:2025-07-26

摘要: 通过压片法制备NaBi(MoO4)2电极, 通过掺杂Y3+对其进行改性, 采用X射线衍射(XRD)、 扫描电子显微镜(SEM)、 透射电子显微镜(TEM)、 紫外可见漫反射光谱(UV-Vis-DRS)和电子自旋共振(ESR)等方法对电极形貌、 结构和电化学性能进行表征, 并研究光-电协同催化氧化降解西地那非的性能和反应机理. 实验结果表明: NaBi(MoO4)2基电极为片层结构, 具有较高的纯净度, 尺寸约为37.5~24.6 nm; 在浓度为0.5 mol/L的最佳电解质Na2SO4溶液中, 最佳偏压为1.5 V, 70 min时可完全去除西地那非. 

关键词: 钼酸铋钠, 西地那非, 光电催化, 压片电极

Abstract: The NaBi(MoO4)2 electrode was prepared by the pressed sheet method,  and the material was modified by doping with Y3+. The morphology,  structure and electrochemical properties of the electrodes were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), ultraviolet-visible-diffuse reflectance spectrum (UV-Vis-DRS) and electron spin resonance (ESR),  and the performance and reaction mechanism of the photocatalytic degradation of sildenafil were also investigated. The experimental results show that the NaBi(MoO4)2-based electrode  has a lamellar structure and high purity,  with the size ranging from about 37.5 nm to 24.6 nm. In the optimal electrolyte Na2SO4 solution with a concentration of 0.5 mol/L  and the optimal bias voltage of 1.5 V, sildenafil  can be completely removed after 70 min.

Key words: sodium bismuth molybdate,  , sildenafil,  , photocatalysis,  , pressed sheet electrode

中图分类号: 

  • X522