不对称卟啉配体及其锌配合物的合成与电化学性质

J4 ›› 2012, Vol. 50 ›› Issue (03): 571-.

不对称卟啉配体及其锌配合物的合成与电化学性质

庄长福¹, 王瑛¹, 张加研¹, 吴春华¹, 田珩¹, 秦永剑¹, 师同顺²

1. 西南林业大学材料工程学院, 昆明 650224|2. 吉林大学化学学院, 长春 130021

收稿日期:2011-09-28 出版日期:2012-05-26 发布日期:2012-05-28
通讯作者: 王瑛 E-mail:yingwang_2009@163.com

Synthesis and Electrochemical Property of an UnsymmetricalPorphyrin and Its Zn Compound

ZHUANG Changfu¹, WANG Ying¹, ZHANG Jiayan¹, WU Chunhua¹,TIAN Heng¹, QIN Yongjian¹, SHI Tongshun²

1. Institute of Material Engineering, Southwest Forestry University, Kunming 650224, China;2. College of Chemistry, Jilin University, Changchun
130021, China

Received:2011-09-28 Online:2012-05-26 Published:2012-05-28
Contact: WANG Ying E-mail:yingwang_2009@163.com

摘要/Abstract

摘要：

采用直接缩合法合成了新型含有肽键的不对称5-［4-(3,5-二-十二烷氧基苯甲酰亚胺基)苯基］-10,15,20-三苯基卟啉配体（DDTPP）及其锌配合物（DDTPPZn）, 并通过元素分析、紫外可见光谱、红外光谱和核磁共振氢谱等测试方法对化合物的结构进行确认, 利用循环伏安法研究了其电化学性质.

关键词: 卟啉；配合物；合成；电化学

Abstract:

A new 5-［4-(3,5-dicetyloxybenzoylamino)phenyl］-10,15,20-triphenylporphyrin (DDTPP) and its relative zinc compound (DDTPPZn) were
synthesized and characterized by means of elemental analyses, UVVis, IR and ¹H NMR spectroscopies. Furthermore, and the oxidation and reduction properties of the compounds were studied by the cyclic voltammetry, and the oxidationreduction potentials were obtained.

Key words: porphyrin, compound, synthesis, electrochemistry

中图分类号:

O641.2

庄长福, 王瑛, 张加研, 吴春华, 田珩, 秦永剑, 师同顺. 不对称卟啉配体及其锌配合物的合成与电化学性质[J]. J4, 2012, 50(03): 571-.

PENG Chang-Fu, WANG Ying, ZHANG Jia-Xing, TUN Chun-Hua, TIAN Hang, QIN Yong-Jian, SHI Tong-Shun. Synthesis and Electrochemical Property of an UnsymmetricalPorphyrin and Its Zn Compound[J]. J4, 2012, 50(03): 571-.