吉林大学学报(理学版) ›› 2025, Vol. 63 ›› Issue (2): 647-0654.

• • 上一篇    

 FeAl-LDH@FeSx-NBC光催化降解水中的对氨基苯甲酸

王琬玥,  濮宇豪, 夏睿笛,  黄嘉诚,  任新,  赵雪松   

  1. 吉林师范大学 工程学院,  吉林 四平 136000
  • 收稿日期:2024-02-27 出版日期:2025-03-26 发布日期:2025-03-26
  • 通讯作者: 任新 E-mail:renxin_hit@126.com

Photocatalytic Degradation of p-Aminobenzoic Acid in Water by FeAl-LDH@FeSx-NBC

WANG Wanyue,  PU Yuhao,  XIA Ruidi, HUANG Jiacheng, REN Xin, ZHAO Xuesong   

  1. College of Engineering,  Jilin Normal University,  Siping 136000,  Jilin Province,  China
  • Received:2024-02-27 Online:2025-03-26 Published:2025-03-26

摘要: 针对对氨基苯甲酸(PABA)结构稳定且难以分解, 长期存在会导致水体污染的问题, 采用水热法制备以生物质炭(BC)为基底的三维层状FeAl-LDH@FeSx-NBC催化剂, 构建光催化降解体系, 降解水中的PABA. 结果表明:  FeAl-LDH@FeSx成功负载在掺杂N元素的生物质炭(NBC)上;  当催化剂用量为0.3 g/L, pH=5时 光催化体系降解PABA的效果最佳, 210 min后去除率可达95.4%;  在5次循环实验后,FeAl-LDH@FeSx-NBC仍对PABA有较高的去除率, 即可重复利用率较好. 在该体系中主要降解作用的自由基为超氧根自由基(O-2)和光生空穴(h+). 光照射使催化剂表面光生电子(e-)与h+分离, e-被氧气捕获生成O-2, h+被氢氧根捕获生成羟基自由基(.OH), 进而促进整个体系的活性组分产生. 

关键词:  , 对氨基苯甲酸, FeAl-LDH@FeSx-NBC, 光催化降解体系

Abstract: Aiming at the problem of the structural stability and difficulty in decomposition of p-aminobenzoic acid (PABA), its long-term existence could lead to water pollution, we prepared   a three-dimensional layered FeAl-LDH@FeSx-NBC catalyst based on biochar (BC)  by  using  hydrothermal method, and constructed  photocatalytic degradation system to degrade  PABA in water. The results show that FeAl-LDH@FeSx is successfully loaded onto biochar doped with N element.  When the catalyst dosage is 0.3 g/L and the  pH=5, the photocatalytic system exhibits the best degradation effect of PABA, with a removal rate of 95.4% after 210 min. After 5 cycle tests,  FeAl-LDH@FeSx-NBC still has  a high removal rate of PABA,  indicating good repeatable utilization. The main free radicals for  degradation in this system are superoxide radical (O-2),  photogenerated hole (h+),   light irradiation causes the separation of  photogenerated electrons (e-) and h+ on the catalyst surface,  where e- is captured by oxygen to form O-and h+ is captured by hydroxide ions to form hydroxyl radical (.OH),  thereby promoting the generation of active components in  the entire system.

Key words: p-aminobenzoic acid,  , FeAl-LDH@FeSx-NBC,  , photocatalytic degradation system

中图分类号: 

  • X703