Journal of Jilin University Science Edition ›› 2020, Vol. 58 ›› Issue (4): 997-1002.
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LIN Hongyan, LI Jiahui, ZENG Ling, WANG Qinglin
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Abstract: Using the 3-(1H-tetrazole-1-acetic acid amido) pyridine (TAAP), Andersontype polyoxoanions and copper chloride as raw materials, we synthesized a new Anderson-type polyoxometalate-based copper complex {H2Cu12(Trz)12[CrMo6(OH)6O18]2(OH)8(H2O)4}·12H2O. (HTrz=1Htetrazole). The crystal structure analysis shows that the complex is a twodimensional metalorganic layer formed by Trz ligand and Cu2+ ions. The terminal oxygen atoms of the[CrMo6(OH)6O18]-3- polyoxoanions is connected to the Cu2+ ions to further form a threedimensional coordination framework. In situ conversion of TAAP ligand to Trz during the hydrothermal synthesis. The synthesized complex has good electrocatalytic reduction effect on H2O2, and good catalytic degradation effect on methylene blue and crystal violet under ultraviolet light.
Key words: Anderson-type polyoxometalate, copper complex, hydrothermal synthesis, electrocatalytic property, photocatalytic performance
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LIN Hongyan, LI Jiahui, ZENG Ling, WANG Qinglin. Synthesis and Property of AndersonType PolyoxometalateBasedCopper Complex Hybridized by a Tetrazole[J].Journal of Jilin University Science Edition, 2020, 58(4): 997-1002.
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http://xuebao.jlu.edu.cn/lxb/EN/Y2020/V58/I4/997
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