地下水系统中镍污染和天然胶体共迁移特征

doi:10.13278/j.cnki.jjuese.20180267

吉林大学学报(地球科学版) ›› 2020, Vol. 50 ›› Issue (1): 226-233.doi: 10.13278/j.cnki.jjuese.20180267

地下水系统中镍污染和天然胶体共迁移特征

杨悦锁^1,2, 朱一丹¹, 张文卿¹, 武宇辉¹, Yu Tong³, 张大志⁴

1. 地下水资源与环境教育部重点实验室(吉林大学), 长春 130021;
2. 区域污染环境生态修复教育部重点实验室(沈阳大学), 沈阳 110044;
3. 巴黎萨克雷大学土壤力学、结构和材料实验室, 法国伊维特河畔吉夫 91190;
4. 黑龙江省生态地质调查研究总院, 哈尔滨 150030

收稿日期:2018-09-19 出版日期:2020-01-26 发布日期:2020-02-11
作者简介:杨悦锁(1962-),男,教授,博士生导师,主要从事地下水科学与工程、土壤污染防控和修复方面的研究,E-mail:yangyuesuo@jlu.edu.cn
基金资助:
国家自然科学基金项目（41472237）；沈阳市科技计划项目（Z17-5-079）；黑龙江省生态地质专项（201507）

Co-Migration of Nickel and Natural Colloids in Groundwater System

Yang Yuesuo^1,2, Zhu Yidan¹, Zhang Wenqing¹, Wu Yuhui¹, Yu Tong³, Zhang Dazhi⁴

1. Key Laboratory of Groundwater Environment and Resources, Ministry of Education(Jilin University), Changchun 130021, China;
2. Key Laboratory of Regional Environment and Eco-Restoration, Ministry of Education(Shenyang University), Shenyang 110044, China;
3. Laboratory of Soil Mechanics, Structures and Materials, University of Paris-Saclay, 91190, Gif sur Yvette, France;
4. General Institute of Eco-Geologic Survey of Heilongjiang Province, Harbin 150030, China

Received:2018-09-19 Online:2020-01-26 Published:2020-02-11
Supported by:
Supported by National Natural Science Foundation of China (41472237),Shenyang Sci-Tech Program (Z17-5-079) and Heilongjiang EcoGeo Major Project(201507)

摘要/Abstract

摘要： 为了对地下水系统中天然胶体与Ni²⁺的共迁移特征进行研究，通过静态吸附实验和石英砂模拟含水层介质柱实验研究了土壤胶体对Ni²⁺在地下水中运移的影响，以及pH、离子强度（IS）、有机质等对土壤胶体吸附Ni²⁺的影响。结果表明：随着pH值升高，土壤胶体对Ni²⁺的吸附量增加；离子强度的增加会显著地降低土壤胶体吸附Ni²⁺的能力；腐殖酸（HA）的存在会增强胶体对Ni²⁺的吸附能力；在有胶体的情况下，Ni²⁺穿透砂柱的时间会缩短，吸附能力增强，吸附量增加，但当离子强度增加时，虽然Ni²⁺穿透砂柱的时间也被缩短，但是吸附量却降低。

关键词: 重金属, 镍, 吸附, 共迁移, 胶体, 地下环境

Abstract: In order to study the co-migration characteristics of natural soil colloids and Ni²⁺ in a groundwater system, the effect of natural soil colloids on the migration of Ni²⁺ in groundwater and the influence of pH, ionic strength (IS), and organic matter on the adsorption of Ni²⁺ by soil colloids were analyzed by means of static adsorption experiments and column technique of quartz sand simulation medium. The results show that the adsorption of heavy metals on soil colloids was increased by increasing pH, but reduced significantly by the increase of ionic strength; the adsorption capacity of colloids on Ni²⁺ was increased by the presence of humic acid; in the presence of colloids, the time of the Ni²⁺ penetrating sand column was shortened, the adsorption capacity of soil colloids was enhanced, and the amount of adsorption was increased; however, when the ionic strength increased, although the time of Ni²⁺ penetrating through the sand column was shortened, the amount of adsorption was decreased.

Key words: heavy metal, nickel, adsorption, co-migration, colloids, subsurface environment

中图分类号:

杨悦锁, 朱一丹, 张文卿, 武宇辉, Yu Tong, 张大志. 地下水系统中镍污染和天然胶体共迁移特征[J]. 吉林大学学报(地球科学版), 2020, 50(1): 226-233.

Yang Yuesuo, Zhu Yidan, Zhang Wenqing, Wu Yuhui, Yu Tong, Zhang Dazhi. Co-Migration of Nickel and Natural Colloids in Groundwater System[J]. Journal of Jilin University(Earth Science Edition), 2020, 50(1): 226-233.

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地下水系统中镍污染和天然胶体共迁移特征

Co-Migration of Nickel and Natural Colloids in Groundwater System

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