吉林大学学报(地球科学版) ›› 2020, Vol. 50 ›› Issue (6): 1766-1775.doi: 10.13278/j.cnki.jjuese.20190204
• 地质与资源 • 上一篇
李玉超, 王诚煜, 于成广
Li Yuchao, Wang Chengyu, Yu Chengguang
摘要: 以辽宁省丹东市富硒(Se)土壤为研究对象,依据表层土壤、土壤剖面及成土母岩的调查数据,研究了土壤中Se元素质量分数、分布规律及其影响因素。结果表明:研究区表层土壤中Se质量分数变化范围为(0.028~0.910)×10-6,高于全国土壤Se质量分数平均值;Se元素空间分布受辽河群影响,显示出表层富集特征。研究区土壤中Se元素富集主要有以下原因:Se元素来源于盖县岩组和高家峪岩组变质岩,其富集受成土过程影响较大,棕壤土层中黏粒或铁氧化物等聚集,易与Se结合发生聚集;区内表生环境地球化学作用对表层土壤中Se元素起到一定的富集作用,土壤中S、N与Se相互吸附固定,有利于土壤Se的富集,此外Al、Fe氧化物对Se具有很强的吸附能力;研究区土壤中Se质量分数与pH值具有显著的负相关关系,土壤中pH值越小,Se质量分数越高。总体上,研究区土壤硒质量分数与有机碳、铝铁氧化物、S、N质量分数具有较好的相关性,这与广州、江西丰城、湖北恩施等地开展的富硒研究相一致。
中图分类号:
[1] Navarro-Alarcón M, López-Martínez M C. Essentiality of Selenium in the Human Body:Relationship with Different Diseases[J]. Science of the Total Environment, 2000, 249(1/2/3):347-371. [2] Keshavarzi B, Moore F, Najmeddin A, et al. The Role of Selenium and Selected Trace Elements in the Etiology of Esophageal Cancer in High Risk Golestan Province of Iran[J]. Science of the Total Environment, 2012, 433:89-97. [3] 李永华,王五一. 硒的土壤环境化学研究进展[J]. 土壤通报,2002, 33(3):230-233. Li Yonghua, Wang Wuyi. Process on the Study Soil Environmental Chemistry of Selenium[J]. Chinese Journal of Soil Science, 2002, 33(3):230-233. [4] 余涛,杨忠芳,王锐,等. 恩施典型富硒区土壤硒与其他元素组合特征及来源分析[J]. 土壤, 2018, 50(6):1119-1125. Yu Tao, Yang Zhongfang, Wang Rui, et al. Characteristics and Sources of Soil Selenium and Other Elements in Typical High Selenium Soil Area of Enshi[J]. Soils, 2018, 50(6):1119-1125. [5] Lü Yaoyao, Yu Tao, Yang Zhongfang, et al. Constraint on Selenium Bioavailability Caused by Its Geochemical Behavior in Typical Kaschin-Beck Disease Areas in Aba, Sichuan Province of China[J]. Science of the Total Environment, 2014, 493:737-749. [6] 王锐,余涛,杨忠芳,等. 富硒土壤硒生物有效性及影响因素研究[J]. 长江流域资源与环境, 2018, 28(7):1647-1654. Wang Rui, Yu Tao, Yang Zhongfang, et al. Bioavailability of Soil Selenium and Its Influencing Factors in Selenium-Enriched Soil[J]. Resources and Environment in the Yangtze Basin,2018, 28(7):1647-1654. [7] Li Zhe, Liang Dongli, Peng Qin, et al. Interaction Between Selenium and Soil Organic Matter and Its Impact on Soil Selenium Bioavailability:A Review[J]. Geoderma, 2017, 295:69-79. [8] 布和敖斯尔,张东威,刘力.土壤硒区域环境分异及安全阈值的研究[J].土壤学报,1995,32(2):186-193. Buber Aoseer, Zhang Dongwei, Liu Li. Regional Environmental Differentiation and Regional Safety Threshold of Soil Selenium[J]. Acta Pedologica Sinica, 1995, 32(2):186-193. [9] 曾庆良,余涛,王锐. 土壤硒含量影响因素及富硒土地资源区划研究:以湖北恩施沙地为例[J]. 现代地质, 2018, 32(1):105-112. Zeng Qingliang, Yu Tao, Wang Rui. The Influencing Factors of Selenium in Soils and Classifying the Selenium-Rich Soil Resources in the Typical Area of Enshi, Hubei[J]. Geoscience, 2018, 32(1):105-112. [10] Supriatin S, Weng L, Comans R N J. Selenium-Rich Dissolved Organic Matter Determines Selenium Uptake in Wheat Grown on Low-Selenium Arable Land Soils[J]. Plant and Soil, 2016, 408(1/2):73-94. [11] 段国正, 马力, 郝立波, 等. 大兴安岭地区火山岩风化过程中的微量元素均一化[J]. 吉林大学学报(地球科学版), 2003,33(4):434-436. Duan Guozheng, Ma Li, Hao Libo,et al. The Trace Element Homogenizition in Weathering Process of Volcanic Rocks, in the Greater Xing'an Mountains[J]. Journal of Jilin University(Earth Science Edition), 2003, 33(4):434-436. [12] 王冬艳, 杨园园, 李月芬,等. 吉林西部土壤有机碳含量与元素地球化学特征[J]. 吉林大学学报(地球科学版), 2011,41(增刊1):333-338. Wang Dongyan, Yang Yuanyuan, Li Yuefen, et al. Content of Soil Organic Carbon and Characteristics of Elemental Geochemistry in West of Jilin Province[J]. Journal of Jilin University(Earth Science Edition), 2011, 41(Sup.1):333-338. [13] 魏华玲, 周国华, 孙彬彬,等. 浙江省东部土壤元素地球化学特征及意义[J]. 吉林大学学报(地球科学版), 2013, 43(2):564-572. Wei Hualing, Zhou Guohua, Sun Binbin, et al. Significance and Characteristics of Soil Trace Elements Geochemistry in the Eastern of Zhejiang Province, China[J]. Journal of Jilin University(Earth Science Edition), 2013, 43(2):564-572. [14] 杨琼, 侯青叶, 顾秋蓓, 等. 广西武鸣县典型土壤剖面Se的地球化学特征及其影响因素研究[J]. 现代地质, 2016, 30(2):455-462. Yang Qiong, Hou Qingye, Gu Qiubei, et al. Study of Geochemical Characteristics and Influencing Factors of Soil Selenium in the Typical Soil Profiles in Wuming County of Guangxi[J]. Geoscience, 2016, 30(2):455-462. [15] 沈骁, 姬丙艳, 许光, 等. 青海西宁-乐都富硒土壤成因探讨[J]. 中国矿业, 2016, 25(增刊1):382-385,389. Shen Xiao, Ji Bingyan, Xu Guang, et al. Discussion on the Genetic Type of Selenium-Rich Area in Xining-Ledu[J]. China Mining Magazine, 2016, 25(Sup.1):382-385,389. [16] 魏振山, 涂其军, 唐蜀虹, 等. 天山北坡乌鲁木齐至沙湾地区富硒土壤地球化学特征及成因探讨[J]. 物探与化探, 2016, 40(5):893-898. Wei Zhenshan, Tu Qijun, Tang Shuhong, et al. A Discussion on the Geochemical Features and Origin of Selenium-Rich Soil on the Northern Slope of the Tianshan Mountains from Urumqi to Shawan County[J]. Geophysical & Geochemical Exploration, 2016, 40(5):893-898. [17] 商靖敏, 罗维, 吴光红, 等. 洋河流域不同土地利用类型土壤硒(Se)分布及影响因素[J]. 环境科学, 2015, 36(1):301-308. Shang Jingmin, Luo Wei, Wu Guanghong, et al. Spatial Distribution of Se in Soils from Different Land Use Types and Its Influencing Factors Within the Yanghe Watershed, China[J].Environmental Science, 2015, 36(1):301-308. [18] 多目标地球化学调查规范:DZ/T 0258-2014[S].北京:中国标准出版社,2014. Sepcification of Multi-Purpose Regional Geochemical Survey:DZ/T 0258-2014[S]. Beijing:Standards Press of China,2014. [19] 黎彤. 化学元素的地球丰度[J]. 地球化学, 1976,5(3):167-174. Li Tong. Chemical Element Abundances in the Earth and Its Major Shells[J]. Geochimica, 1976,5(3):167-174. [20] 鄢明才,迟清华.中国东部地壳与岩石的化学组成[M].北京:地质出版社,1997. Yan Mingcai, Chi Qinghua. Chemical Composition of Crust and Rocks in Eastern China[M]. Beijing:Geological Publishing House, 1997. [21] Goldschmidt. Geochemistry[M]. Fair Lawn:Oxford University Press, 1954. [22] Vinogradov A P. Detection and Analysis of Rare Elements[M]. London:Oldbourne Press, 1962. [23] Taylor S R. Trace Element Abundances and the Chondritic Earth Model[J]. Geochimica et Cosmochimica Acta, 1964, 28(12):1989-1998. [24] Taylor S R, Mclennan S M. The Continental Crust:Its Composition and Evolution[J]. The Journal of Geology, 1985, 94(4):57-72. [25] Wedepohl K H. The Composition of the Continental Crust[J]. Geochimica et Cosmochimica Acta, 1995, 59(7):1217-1232. [26] 郦逸根, 董岩翔, 郑洁, 等. 浙江富硒土壤资源调查与评价[J]. 第四纪研究, 2005,25(3):323-330. Li Yigen, Dong Yanxiang, Zheng Jie, et al. SELENIUM:Abundant Soil Survey and Assessment in Zhejiang[J]. Quaternary Sciences, 2005, 25(3):323-330. [27] 杨忠芳,余涛,侯青叶,等. 海南岛农田土壤Se的地球化学特征[J]. 现代地质,2012, 26(5):837-849. Yang Zhongfang, Yu Tao, Hou Qingye, et al. Geochemical Characteristics of Soil Selenium in Farmland of Hainan Island[J]. Geoscience, 2012, 26(5):837-849. [28] 章海波,骆永明,吴龙华,等. 香港土壤研究:Ⅱ:土壤硒的含量、分布及其影响因素[J]. 土壤学报, 2005, 42(3):404-410. Zhang Haibo, Luo Yongming, Wu Longhua, et al. Hong Kong Soil Researches:Ⅱ:Distribution and Content of Selenium in Soils[J]. Acta Pedologica Sinica, 2005, 42(3):404-410. [29] 杨志强,李杰,郑国东,等. 广西北部湾沿海经济区富硒土壤地球化学特征[J]. 物探与化探, 2014, 38(6):1260-1264. Yang Zhiqiang, Li Jie, Zheng Guodong, et al. Geochemical Characteristics of Selenium-Rich Soil in Beibu Gulf Coastal Economic Zone of Guangxi[J]. Geophysical and Geochemical Exploration, 2014, 38(6):1260-1264. [30] 侯少范,王丽珍,李德珠,等. 控制土壤硒化学行为因素的探讨[J]. 地理研究,1991, 10(4):12-18. Hou Shaofan, Wang Lizhen, Li Dezhu, et al.The Study of the Controlling Factors of Selenium Chemical Behaviour in Soil[J]. Geographical Research, 1991, 10(4):12-18. [31] 王五一,王大成,王卫中,等. 我国土壤中硒的淋溶[J]. 地理研究, 1992, 11(2):34-40. Wang Wuyi, Wang Dacheng, Wang Weizhong, et al.A Preliminary Study on Leaching of Selenium in the Soils of China[J]. Geographical Research, 1992, 11(2):34-40. [32] Kausch M F, Pallud C E. Modeling the Impact of Soil Aggregate Size on Selenium Immobilization[J]. Biogeosciences,2013, 10(3):1323-1336. [33] 朱建明, 梁小兵, 凌宏文, 等. 环境中硒存在形式的研究现状[J].矿物岩石地球化学通报, 2003,22(1):75-81. Zhu Jianming, Liang Xiaobing, Li Hongwen, et al. Advances in Studying Occurrence Modes of Selenium in Environment[J]. Bulletin of Mineralogy Petrology & Geochemistry, 2003, 22(1):75-81. [34] 李永华, 王五一, 杨林生, 等. 陕南土壤中水溶态硒、氟的含量及其在生态环境的表征[J]. 环境化学, 2005(3):279-283. Li Yonghua,Wang Wuyi,Yang Linsheng,et a1. The Soil Water Content in the South of Shaanxi Province Dissolved Selenium, Fluoride and in the Characterization of the Ecological Environment[J]. Environmental Chemistry,2005(3):279-283. [35] 王美珠, 章明奎. 我国部分高硒低硒土壤的成因初探[J]. 浙江农业大学学报, 1996, 22(1):89-93. Wang Meizhu, Zhang Mingkui. A Discussion on the Cause of High-Se and Low-Se Soil Information[J]. Journal of Zhejiang Agricultural University, 1996, 22(1):89-93. [36] 周越, 吴文良, 孟凡乔, 等. 土壤中硒含量、形态及有效性分析[J]. 农业资源与环境学报, 2014, 31(6):527-532. Zhou Yue, Wu Wenliang, Meng Fanqiao, et al. Review on the Content, Specification of Selenium and Its Availability in Soils[J]. Journal of Agricultural Resources and Environment, 2014, 31(6):527-532. [37] 龚河阳, 李月芬, 汤洁, 等. 吉林省西部土壤硒含量、形态分布及影响因素[J]. 吉林农业大学学报, 2015, 37(2):177-184, 190. Gong Heyang, Li Yuefen,Tang Jie, et al. Content, Form Distribution and Influencing Factors of Soil Seleniumin Western Jilin Province[J]. Journal of Jilin Agricultural University, 2015, 37(2):177-184, 190. [38] 陈显著, 李就好. 广州市土壤硒含量的分布及其影响因素研究[J]. 福建农业学报, 2016,31(4):401-407. Chen Xianzhu, Li Jiuhao. Concentration, Distribution,and Influencing Factors on Soil Selenium in Guangzhou[J]. Fujian Journal of Agricultural Sciences, 2016, 31(4):401-407. [39] 韩笑,周越,吴文良,等. 富硒土壤硒含量及其与土壤理化性状的关系:以江西丰城为例[J]. 农业环境科学学报, 2018, 37(6):1177-1183. Han Xiao, Zhou Yue, Wu Wenliang, et al. Selenium Contents of Farmland Soils and Their Relationship with Main Soil Properties in Fengcheng, Jiangxi[J]. Journal of Agro-Environment Science, 2018, 37(6):1177-1183. |
[1] | 周翔. 松辽盆地北部营城组火山岩地球化学特征及地质意义[J]. 吉林大学学报(地球科学版), 2019, 49(4): 1001-1014. |
[2] | 付焱鑫, 谭思哲, 侯凯文. 南黄海盆地北凹泰州组烃源岩形成条件及资源潜力分析[J]. 吉林大学学报(地球科学版), 2019, 49(1): 230-239. |
[3] | 赵金童, 牛瑞卿, 姚琦, 武雪玲. 雷达数据辅助下的滑坡易发性评价[J]. 吉林大学学报(地球科学版), 2018, 48(4): 1182-1191. |
[4] | 胥为, 周云轩, 沈芳, 田波, 于鹏. 基于Sentinel-1A雷达影像的崇明东滩芦苇盐沼植被识别提取[J]. 吉林大学学报(地球科学版), 2018, 48(4): 1192-1200. |
[5] | 王焱, 鹿琪, 刘财, 佘松盛, 刘四新. 利用GPR天线-目标极化的瞬时属性分析方法探测LNAPL污染土壤[J]. 吉林大学学报(地球科学版), 2018, 48(2): 491-500. |
[6] | 尹业长, 郝立波, 赵玉岩, 石厚礼, 田午, 张豫华, 陆继龙. 冀东高家店和蛇盘兔花岗岩体:年代学、地球化学及地质意义[J]. 吉林大学学报(地球科学版), 2018, 48(2): 574-586. |
[7] | 郑国东, 覃建勋, 付伟, 杨志强, 赵辛金, 卢炳科. 广西北部湾地区表层土壤As分布特征及其影响因素[J]. 吉林大学学报(地球科学版), 2018, 48(1): 181-192. |
[8] | 熊凯, 宫兆宁, 张磊, 赵文吉. 再生水补水条件下土壤全氮空间分布特征[J]. 吉林大学学报(地球科学版), 2017, 47(6): 1829-1837. |
[9] | 陈治军, 任来义, 贺永红, 刘护创, 宋健. 银额盆地哈日凹陷银根组优质烃源岩地球化学特征及其形成环境[J]. 吉林大学学报(地球科学版), 2017, 47(5): 1352-1364. |
[10] | 李永涛, 郭高山, 顾延生, 韦林, 何思远. 钢厂周边污染土壤的电性与磁性特征及其环境意义[J]. 吉林大学学报(地球科学版), 2017, 47(5): 1543-1551. |
[11] | 卞建民, 刘彩虹, 杨晓舟. 吉林西部大安灌区土壤贮水能力空间变异特征及土壤水分有效性[J]. 吉林大学学报(地球科学版), 2017, 47(2): 554-563. |
[12] | 程文斌, 尹力, 陈翠华, 宋玉坤, 李关清, 张兴国, 夏抱本, 达瓦次仁. 西藏柯月Pb-Zn-Sb-Ag多金属矿床I号矿体原生晕地球化学特征[J]. 吉林大学学报(地球科学版), 2016, 46(6): 1711-1723. |
[13] | 韩凯, 郑智杰, 甘伏平, 陈贻祥, 陈玉玲. 利用多源大功率充电法定位复杂岩溶含水通道的方法[J]. 吉林大学学报(地球科学版), 2016, 46(5): 1501-1510. |
[14] | 勾福岩, 刘财, 刘洋, 王博, 冯晅. 基于OC-Seislet变换的海洋涌浪噪声衰减方法[J]. 吉林大学学报(地球科学版), 2015, 45(3): 962-970. |
[15] | 刘财, 崔芳姿, 刘洋, 王典, 刘殿秘, 张鹏. 基于低信噪比条件下新型Seislet变换的阈值去噪方法[J]. 吉林大学学报(地球科学版), 2015, 45(1): 293-301. |
|