Yilan basin,oil shale,organic geochemical; depositional environment,Dalianhe Formation ,"/>
吉林大学学报(地球科学版) ›› 2023, Vol. 53 ›› Issue (1): 60-72.doi: 10.13278/j.cnki.jjuese.20220082
高家俊1,2, 孟庆涛1,2, 曾文人3,李金国4,李丽5,康嘉楠1,2
1.吉林大学地球科学学院,长春130061
2.吉林省油页岩与共生能源矿产重点实验室,长春130061
3.中国石油大学地球科学学院,北京102249
4.中国石油长庆油田分公司第三采油厂,银川750006
5.辽河油田勘探开发研究院,辽宁盘锦124010
Gao Jiajun1,2, Meng Qingtao1,2, Zeng Wenren3, Li Jinguo4, Li Li5, Kang Jianan1,2
1. College of Earth Sciences, Jilin University, Changchun 130061, China
2. Key-Lab for Oil Shale and Paragenetic Energy Minerals, Jilin Province, Changchun 130061, China
3. College of Earth Science, China University of Petroleum, Beijing 102249, China
4. The Third Oil Production Plant of PetroChina Changqing Oilfield Company,Yinchuan 750006,China
5. Liaohe Oilfield Exploration and Development Research Institute,Panjin 124010,Liaoning,China
Abstract: Based on the analysis of oil content, total organic carbon(TOC), rock pyrolysis and biomarker, the authors studied the organic geochemical characteristics, hydrocarbon generation potential, the origin of organic matter, and depositional environment of Eocene Dalianhe Formation oil shale in Yilan basin. The results show that there are two types of oil shales, the independent oil shale of semi-deep lake facies and the coal-bearing oil shale of limno-telmatic facies in the study area. The oil content of independent oil shale is between 3.55%-4.18%, w(TOC) is between 9.00%-10.55%, and the kerogen is type Ⅱ1. The oil content of coal-bearing oil shale is between 3.85%-18.57%, w(TOC) is 8.90%-30.10%, and the kerogen is type Ⅰ-Ⅱ1, which has better hydrocarbon generation potential. Low Tmax (425-440 ℃), High CPI (1.32-1.68), low C2920S/(20S+20R), low C29ββ/(αα+ββ) and low Ts/Tm indicate that the organic matter of the two types of oil shale is in the immature stage. The main peak of n-alkanes is C27 or C29, the average value of CPI is 1.50, which shows that odd carbon number of single and back peak is dominant, and Pr/Ph (average value: 3.16) indicates that pristane is dominant. The carbon number distribution of n-alkanes and the relative content of C27-29 regular steranes indicate that oil shale is a mixed source of higher plants and algae, and algae contribute more to the organic matter of coal-bearing oil shale. The contents of Pr/Ph and rearranged steranes in the coal-bearing oil shale are significantly higher, in contrast, the gamma paraffin index of the two types of oil shale is very low, which reveals that the independent oil shale is deposited in the oxygen-limited freshwater environment, and the coal-bearing oil shale is deposited in the weakly oxidized freshwater environment. The independent oil shale is affected by frequent gravity flows, and its quality decreases. Based on the above research, it is considered that the origin of organic matter and the gravity flows are the critical factors for the differential enrichment of organic matter between the two types of oil shale in the study area.
摘要:
为了研究依兰盆地始新统达连河组油页岩的品质及沉积环境,通过对研究区样品的含油率、总有机碳、岩石热解、生物标志化合物的分析,讨论了油页岩的有机地球化学特征、生烃潜力、有机质来源和沉积环境。结果表明:达连河组发育油页岩段半深湖相和含煤段湖沼相两种类型油页岩。油页岩段油页岩含油率为3.55%~4.18%,w(TOC)为9.00%~10.55%,有机质类型为Ⅱ1型;含煤段油页岩含油率为3.85%~18.57%,w(TOC)为8.90%~30.10%,有机质类型为Ⅰ—Ⅱ1型,具有更大的生烃潜力。最大热解峰温Tmax(425~440 ℃)低、碳优势指数CPI(1.32~1.68)大、C29 20S /(20S+20R)值低、C29ββ/(αα+ββ)值低和Ts/Tm低,指示两种类型的油页岩有机质均处于未成熟阶段。正构烷烃主峰碳为C27或C29,CPI平均值为1.50,呈现单峰、后峰式的奇碳数优势,Pr/Ph(平均值为3.16)指示姥鲛烷占优势。正构烷烃碳数分布和C27-29规则甾烷质量分数指示油页岩为高等植物和藻类的混合来源,含煤段油页岩有机质中藻类贡献更大。两种类型油页岩伽马蜡烷指数均极低,而含煤段油页岩Pr/Ph和重排甾烷含量明显更高,揭示油页岩段油页岩形成于贫氧的淡水环境,而含煤段油页岩形成于弱氧化的淡水环境。油页岩段油页岩受频繁的重力流影响,品质降低。综合以上研究,认为有机质来源和重力流是研究区两种类型油页岩有机质差异富集的主控因素。
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