Journal of Jilin University(Earth Science Edition) ›› 2020, Vol. 50 ›› Issue (2): 392-404.doi: 10.13278/j.cnki.jjuese.20190265

Previous Articles     Next Articles

Geochemical Characteristics and Paleolimnological Information of Oil Shale in 1st Member of Qingshankou Formation in Northern Songliao Basin

Zheng Guodong1,2, Meng Qingtao3,4, Liu Zhaojun3,4   

  1. 1. Lunan Geological Engineering Investigation Institute of Shandong Province, Jining 272100, Shandong, China;
    2. Engineering Innovation Center for Restoration&Reclamation in Mining-Induced Subsidence Land of MNR, Jining 272100, Shandong, China;
    3. College of Earth Sciences, Jilin University, Changchun 130061, China;
    4. Key Laboratory of Oil Shale and Coexistent Energy Minerals of Jilin Province, Changchun 130061, China
  • Received:2019-12-09 Online:2020-03-26 Published:2020-03-31
  • Supported by:
    Supported by National Natural Science Foundation of China (41872103) and Project of China Geological Survey (1212011220800)

Abstract: The geochemical characteristics and paleolimnological information of oil shale are the key evidence to reveal the rule of metallogeny and enrichment of oil shale. Based on the analyses of TOC, oil yield, rock pyrolysis, element, biomarker compound,and organic maceral, geochemical characteristics of oil shale in the 1st Member of Qingshankou Formation in Well ZY1 in northern Songliao basin the were refinedly characterized, paleolimnological information recorded by the oil shale was analyzed, then the control effect of paleolake on organic matter enrichment of oil shale was discussed. The results show that there are 8 layers of medium-high quality oil shale in the 1st Member of Qingshankou Formation, and the high quality oil shale is mainly in the lower part. The TOC of oil shale has good correlation with the oil yield. Seen from the thermal evolution, the oil shale is in the immature-low mature stage with high hydrocarbon potential. Abundant steranes and terpanes are detected from the oil shale samples. The organic matter type of oil shale is mainly Ⅰ, and the main source of organic matter is lake aquatic organisms dominated by lamalginite. The paleolacustrine productivity of the lower part can be divided into three cycles by geochemical parameters, correspondingly the water salinity of paleolake shows three cycles from semi-saline to saline, and the redox property of paleo-lake shows reduction-strong reduction-reduction. And the paleolacustrine productivity of the late cycle Ⅱ is the highest, corresponding to the highest water salinity and the strongest reducibility. It is suggested that the high lake yield caused by lake eutrophication is the material basis of organic matter enrichment of high-quality oil shale in the 1st Member of Qingshankou Formation, and the strong reduction environment of bottom water controlled by salinity stratification is favorable for the accumulation of organic matter in high-quality oil shale.

Key words: oil shale, geochemical, paleolimnology, 1st Member of Qingshankou Formation, Songliao basin

CLC Number: 

  • P618.12
[1] 王慧中,梅洪明. 东营凹陷沙三下亚段油页岩中古湖泊学信息[J]. 同济大学学报(自然科学版),1998, 26(3):315-319. Wang Huizhong, Mei Hongming.Paleolimnological Information from the Oil Shale in the Lower Part of Sha3 Formation, in Dongying Depression[J]. Journal of Tongji University(Natural Sciences),1998, 26(3):315-319.
[2] 陈中红, 查明, 金强. 东营凹陷波动古湖相烃源岩沉积特征[J]. 湖泊科学, 2006, 18(1):29-35. Chen Zhonghong,Zha Ming,Jin Qiang. Sedimentary Charaeteristics of the Sourerocks in Fluctuation from Lake Facies:An Example from the Well Niu-38 in the Dongying Depression,China[J]. Journal of Lake Science, 2006, 18(1):29-35.
[3] 孟庆涛, 刘招君, 胡菲, 等. 桦甸盆地始新世古湖泊生产力与有机质富集机制[J]. 中国石油大学学报(自然科学版), 2012, 36(5):38-44. Meng Qingtao, Liu Zhaojun, Hu Fei, et al. Productivity of Eocene Ancient Lake and Enrichment Mechanismof Organic Matter in Huadian Basin[J]. Journal of China University of Petroleum (Edition of Natural Science), 2012, 36(5):38-44.
[4] 柳蓉. 东北地区东部新生代断陷盆地油页岩特征及成矿机制研究[D]. 长春:吉林大学, 2007. Liu Rong. Research on Oil Shale Characteristics and Metallogenic Mechanism of Cenozoic Fault Basins in Eastern Northeast Region[D]. Changchun:Jilin University, 2007.
[5] 王克兵. 柴北缘团鱼山地区中侏罗统石门沟组油页岩有机地球化学特征及成矿条件[D]. 长春:吉林大学, 2018. Wang Kebing. Organic Geochemistry Characteristics and Metallogenic Condition of Oilshale in Middle Jurassic Shimengou Formation in Tuanyushan Area,Northern Qaidam Basin, China[D]. Changchun:Jilin University, 2018.
[6] 贾建亮, 刘招君, Achim Bechtel, 等. 松辽盆地嫩江组油页岩发育控制因素[J]. 地球科学:中国地质大学学报, 2014, 39(2):174-186. Jia Jianliang, Liu Zhaojun, Achim B, et al. Major Factors Controlling Formation of Oil Shale in Nenjiang Formation of Songliao Basin[J]. Earth Science:Journal of China University of Geoscience, 2014, 39(2):174-186.
[7] 柳蓉, 刘招君, 杜江峰, 等. 依兰盆地始新统达连河组油页岩成因新认识[J]. 吉林大学学报(地球科学版), 2012, 42(4):941-947. Liu Rong, Liu Zhaojun, Du Jiangfeng, et al. New Research on Oil Shale Origin of Eocene Dalianhe Formation in Yilan Basin[J]. Journal of Jilin University (Earth Science Edition), 2012, 42(4):941-947.
[8] 孙平昌. 松辽盆地东南部上白垩统含油页岩系有机质富集环境动力学[D]. 长春:吉林大学, 2013. Sun Pingchang. Environmental Dynamics of Organic Accumulation in the Oil Shale Bearing Layers in the Upper Cretaceous, Southeast Songliao Basin(NE China)[D]. Changchun:Jilin University, 2013.
[9] 刘招君, 孟庆涛, 贾建亮, 等. 陆相盆地油页岩成矿规律:以东北地区中、新生代典型盆地为例[J]. 吉林大学学报(地球科学版), 2012, 42(5):1285-1297. Liu Zhaojun, Meng Qingtao, Jia Jianliang, et al. Metallogenic Regularity of Oil Shale in Continental Basin:Case Study in the Meso-Cenozonic Basin of Northest China[J]. Journal of Jilin University (Earth Science Edition), 2012, 42(5):1285-1297.
[10] 刘招君, 孟庆涛, 柳蓉, 等. 古湖泊学研究:以桦甸断陷盆地为例[J]. 沉积学报, 2010, 28(5):917-925. Liu Zhaojun, Meng Qingtao, Liu Rong, et al. Paleolimnology Study:Taking Huadian Fault Basin as an Example[J]. Acta Sedimentologica Sinica, 2010, 28(5):917-925.
[11] 刘招君, 杨虎林, 董清水, 等. 中国油页岩[M]. 北京:石油工业出版社, 2009. Liu Zhaojun, Yang Hulin, Dong Qingshui, et al. Oil Shale in China[M]. Beijing:Petroleum Industry Press, 2009.
[12] Feng Z Q,Jia C Z,Xie X N,et al. Tectonostratigraphic Units and Stratigraphic Sequences of the Nonmarine Songliao Basin,Northeast China[J]. Basin Research,2010,22:79-95.
[13] 贾建亮. 基于地球化学-地球物理的松辽盆地上白垩统油页岩识别与资源评价[D]. 长春:吉林大学, 2012. Jia Jianliang. Research on the Recognition and Resource Evaluation of the Upper Cretaceous Oil Shale Based on Geochemistry-Geophysics Technique in the Songliao Basin(NE, China)[D]. Changchun:Jilin University, 2012.
[14] 黄清华, 郑玉龙, 杨明杰, 等. 松辽盆地白垩纪古气候研究[J]. 微体古生物学报, 1999, 16(1):95-103. Huang Qinghua, Zheng Yulong, Yang Mingjie, et al. On Cretaceous Paleoclimate in the Songliao Basin[J].Acta Micropalaeontologica Sinica, 1999, 16(1):95-103.
[15] 尹秀珍. 松辽盆地中部晚白垩世早期古湖泊生产力研究[D]. 北京:中国地质大学(北京), 2008. Yin Xiuzhen. Palaeolacustrine Study of Early Late Cretaceous in the Central Area of Songliao Basin[D]. Beijing:China University of Geosciences (Beijing), 2008.
[16] Echtel A, Reischenbacher R D, Sachsenhoofer R F, et al. Paleogeography and Paleoecology of the Upper Miocene Zillingdorf Lignite Deposit(Austria)[J]. International Journal of Coal Geology, 2007, 69(3):119-143.
[17] 王春江, 傅家谟, 盛国英. 辽河西部凹陷古潜山原油及其源岩的分子碳同位素地球化学[J]. 地球化学, 2006, 35(1):68-80. Wang Chunjiang, Fu Jiamo, Sheng Guoying. Molecular Carbon Isotopic Geochemistry of Buried-Hill Oilsand Source Rocks of the West Liaohe Depression, China[J]. Geochimica, 2006, 35(1):68-80.
[18] Kleemann G, Poralla K, Englert G, et al. Tetrahymanol from the Phototrophic Bacterium Rhodopseudomonas Palustirs:First Report of a Gammacerane Triterpene from a Prokaryotes[J]. Journal of General Microbiology, 1990, 136:2551-2553.
[19] Hall P B, Douglas A G. The Distribution of Cyclic Alkanes in Two Lacustrine Deposits[C]//Advances in Organic Geochemistry. New York:J Wiley and Sons, 1981:576-587.
[20] Muller P J, Suess E. Productivity, Sedimentation Rate and Sedimentary Organic Matter in the Ocean:I:Organic Carbon Preservation[J]. Deep Sea Research, 1979, 26:1347-1362.
[21] Graninal L, Muller B, Wehrli B. Origin and Dynamics of Fe and Mn Sedimentary Layers in Lake Baikal[J].Chem Geol, 2004, 205:55-72.
[22] 张立平, 黄第藩, 廖志勤. 伽马蜡烷:水体分层的地球化学标志[J]. 沉积学报, 1999, 17(1):136-140. Zhang Liping, Huang Difan, Liao Zhiqin. Gammacerane:Geochemical Indicator of Water Column Stratification[J]. Acta Sedimentologica Sinica, 1999, 17(1):136-140.
[23] Sinninghe D, Kock-van J S,Dalen A C,et al. The Identification of Mono-,Di-,and Trimethyl 2-Methyl-2(4,8,12-Trimethyltridecyl) Chromans and Their Occurrence in Geosphere[J]. Geochimica et Cosmochimica Acta, 1987, 51(9):2393-2400.
[24] 邓宏文, 钱凯. 沉积地球化学与环境分析[M]. 兰州:甘肃科学技术出版社, 1993. Deng Hongwen, Qian Kai. Sedimentary Geochemistry and Environmental Analysis[M]. Lanzhou:Gansu Science and Technology Publishing House, 1993.
[25] 韩刚,张文婧,黄清华,等. 松辽盆地晚白垩世青山口组缺氧事件层的地质地球化学特征[J]. 现代地质,2012,4(26):741-746. Han Gang, Zhang Wenjing, Huang Qinghua, et al.Geological and Geochemical Characteristics of Anoxic Event Bed in the Qingshankou Formation of Late Cretaceous in Songliao Basin[J]. Geoscience, 2012,4(26):741-746.
[26] 梅博文, 刘希江. 我国原油中异戊间二烯烷烃的分布及其与地质环境的关系[J]. 石油与天然气地质, 1980, 1(2):99-115. Mei Bowen, Liu Xijiang. The Distribution of Isoprenoid Alkannes in China's Crude Oil and Its Relation with the Geologic Environment[J]. Oil and Gas Geology, 1980, 1(2):99-115.
[27] Hatch J R, Leventhal J S. Relationship Between Inferred Redoxpotential of the Depositional Environment and Geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone, Wabaunsee County, Kansas, U.S.A[J]. Chemical Geology, 1992, 99:65-82.
[1] Liu Zhaojun, Liu Rong, Sun Pingchang, Meng Qingtao, Hu Fei. Oil Shale Characteristics and Distribution in Typical Basins of China [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 313-325.
[2] Wang Simin, Zang Dongsheng, Wang Xiqiong, Li Jie, Han Song, Li Jianzhong. Oil Shale Features and Sedimentary Environment in Jianchang Basin, Western Liaoning Province [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 326-340.
[3] Meng Qingtao, Li Jinguo, Liu Zhaojun, Hu Fei, Xu Chuan. Organic Geochemical Characteristics and Depositional Environment of Oil Shale of Eocene of Paleocene Youganwo Formation in Yangjiao Mining Area of Maoming Basin [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 356-367.
[4] Jia Jianliang, Liu Zhaojun, Meng Qingtao, Sun Pingchang, Xu Jinjun, Liu Rong, Bai Yueyue. Response Mechanism Between Oil Yield and Total Organic Carbon of Non-Marine Oil Shale in China [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 368-377.
[5] Song Yu, Liu Zhaojun, Achim Bechtel, Xu Yinbo, Meng Qingtao, Sun Pingchang, Zhu Kai. Controlling Factors of Oil Shale and Coal Oil Yield in Lower Cretaceous Muling Formation in Laoheishan Basin [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 378-391.
[6] Zhang Jian, Zhang Haihua, Chen Shuwang, Zheng Yuejuan, Zhang Dejun, Su Fei, Huang Xin. Geochemical Characteristics and Geological Significance of Upper Permian Linxi Formation in Northern Songliao Basin [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 518-530.
[7] Miao Changsheng, Xu Wen, Liu Yuhu, Xie Rongxiang. Characteristics of Volcanic Reservoirs in Southern Songliao Basin [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(2): 635-643.
[8] Zhang Penghui, Zhang Xiaobo, Fang Hui, Wang Xiaojiang, Liu Jianxun. Deep and Shallow Structural Characteristics of Middle Segment of Nenjiang-Balihan Fault Based on Geophysical Data [J]. Journal of Jilin University(Earth Science Edition), 2020, 50(1): 261-272.
[9] Chi Huanzhao, Dong Fuxiang, Xue Xiaogang, Liu Cai, Si Kao. Geological Characteristics of Typical Volcanic Edifices of Yingcheng Formation in Southern Songliao Basin [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(6): 1649-1657.
[10] Zeng Wenren, Meng Qingtao, Liu Zhaojun, Xu Yinbo, Sun Pingchang, Wang Kebing. Organic Geochemical Characteristics and Paleo-Lake Conditions of Oil Shale of Middle Jurassic Shimengou Formation in Tuanyushan Area of Northern Qaidam Basin [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(5): 1270-1284.
[11] Zhou Xiang. Geochemistry and Tectonic Implication of Volcanic Rocks of Yingcheng Formation in Northern Songliao Basin [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(4): 1001-1014.
[12] Shan Chengheng, Wang Zheng, Shi Changhao. Geochemical Assessment of Land Quality Based on Comprehensive Grading Method: A Case Study of Wulajie Town in Jilin Province [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(3): 817-829.
[13] Ma Zhongliang, Wang Qiang, Zheng Lunju, Zhang Caiming. Identification Method & Application of Temperature and Heating Time and Hydrocarbon Conversion Rate of Oil Shale In-Situ Mining [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(2): 394-399.
[14] Mei Xi, Zhang Xunhua, Liu Jian, Wang Zhongbo, Guo Xingwei, Huang Xiangtong. Elemental Geochemical Record of Land and Sea Environmental Evolution Since 3.50 Ma in South Yellow Sea [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(1): 74-84.
[15] Fu Yanxin, Tan Sizhe, Hou Kaiwen. Formation Conditions and Resource Potentiality of Taizhou Formation in North Sag of South Yellow Sea Basin [J]. Journal of Jilin University(Earth Science Edition), 2019, 49(1): 230-239.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!