云南会泽矿山厂铅锌矿床流体包裹体特征及成矿物理化学条件

doi:10.13278/j.cnki.jjuese.201703107

Abstract

Abstract: Systematic researches on fluid inclusions in the sphalerite and calculation of the ore-forming physicochemical conditions, combining with previous research results, lead to the conclusions that the homogenization temperature of fluid inclusions in the sphalerite grains from the Kuangshanchang lead-zinc deposit vary from 131 to 280 ℃, with a greater change range, the salinity(w(NaCl)) between 3.2% and 22.7 %. The homogenization temperatures of fluid inclusions in the dolomite vary from 86 to 163 ℃, the salinity of most fluid inclusions vary from 1.1% to 14.8 %. There are obvious regular characteristics of homogenization temperature and salinity of fluid inclusions in the sphalerite precipitated in three metallogenic stages and the dolomite. Namely, from the hydrothermal mineralization stage I, stage Ⅱ, stage Ⅲ to the altered wall rock, the ore-forming fluid is characterized by high-moderate temperature and high salinity, moderate temperature and high-moderate salinity, moderate-low temperature and high-moderate salinity, as well as moderate-low temperature and low salinity. Moreover, there are two kinds of fluids with different salinity participating in the hydrothermal ore-forming process. The mixing of the fluids is likely to be the major mineralization mechanism. The calculated pH values show that ore-forming fluid is acidic in migration stage, whereas, from metallogenic stage I to IV, the pH value of the fluid increases gradually. In major metallogenic stage, II and III, a large number of sphalerite and galena minerals precipitated under neutral-weak alkaline condition. CO^2-₃ and HCO^-₃ buffer pair, which is controlled by the fugacity balance among CO, CO₂, O₂, adjusts the pH value of the ore-forming fluid. The carbonate plays a vital role in migration and precipitation of metallogenic elements of the lead and zinc.

Key words: fluid inclusion in sphalerite, physicochemical conditions, ore-forming fluid, Kuangshanchang lead-zinc deposit in Huize, northeastern Yunnan ore concentration area

CLC Number:

Zhang Yan, Han Runsheng, Wei Pingtang, Qiu Wenlong. Fluid Inclusion Features and Physicochemical Conditions of the Kuangshanchang Pb-Zn Deposit, Huize, Yunnan Province[J].Journal of Jilin University(Earth Science Edition), 2017, 47(3): 719-733.

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Fluid Inclusion Features and Physicochemical Conditions of the Kuangshanchang Pb-Zn Deposit, Huize, Yunnan Province

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