Journal of Jilin University(Earth Science Edition) ›› 2018, Vol. 48 ›› Issue (6): 1831-1837.doi: 10.13278/j.cnki.jjuese.20170081

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Degradation of 1,4-Dioxane in Groundwater by Ultrasound Enhanced ZVI-Activated Persulfate Oxidation Process

Liu Na, Ding Jiyang, Yu Qingmin, Zhang Sida, Zhao Hongjun, Lü Chunxin   

  1. Key Laboratory of Groundwater Resources and Environment(Jilin University), Ministry of Education/College of New Energy and Environment, Jilin University, Changchun 130021, China
  • Received:2017-06-01 Published:2018-11-26
  • Supported by:
    Supported by National Natural Science Foundation of China (41572217)

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Abstract: Ultrasound enhanced zero-valent iron (ZVI) activated persulfate process to degrade 1,4-dioxane in groundwater was studied, and the effects of ultrasound, ZVI dosage, concentration of persulfate and carbonate ions were also investigated. ZVI was characterized by X-ray photo electron spectroscopy (XPS) and scanning electron microscope (SEM). The results show that ultrasound can accelerate the generation of sulfate radicals and Fe2+, and enhance the degradation of 1,4-dioxane. The degradation efficiency can be increased through increasing ZVI dosage and persulfate concentration;however, the final degradation efficiency of 1,4-dioxane decreases when Fe0 dosage is much more than persulfate. The presence of carbonate ions in groundwater reduces the concentration of sulfate radicals, thus the efficiency of 1,4-dioxane degradation decreases with the increase of carbonate concentration. In conclusion, ultrasound enhanced ZVI-activated persulfate process can effectively degrade 1,4-dioxane, is a promising method in the treatment of 1,4-dioxane in groundwater.

Key words: zero-valent iron, persulfate, 1,4-dioxane, ultrasound, groundwater

CLC Number: 

  • X703
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