吉林省油页岩中铂族元素的化学特征及分配规律研究

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The Chemical Characteristics and Distribution of Platinum Group Elements in the Oil Shale Samples, Jilin Province

WANG Wen-ying¹, SU Ke², GAO Gui-mei¹, GAN Shu-cai¹, LIU Zhao-jun³

1.College of Chemistry, Jilin University, Changchun 130026, China;2.The Center of Test and Science Experiment, Jilin University, Changchun 130026, China;3.College of Earth Sciences, Jilin University, Changchun 130061, China

Received:2006-08-28 Revised:1900-01-01 Online:2006-11-26 Published:2006-11-26
Contact: GAN Shu-cai

Abstract

Abstract: The contents of platinum group elements (PGEs) in the oil shale from Jilin Province were determined by the inductively-coupled plasma mass spectrometry (ICP-MS). The chemical characteristics, correlation of PGE to the inorganic components and the distribution model of the PGE in the oil shale samples were described and reviewed in this paper. By comparing the average contents of PGE in oil shale with the abundance of PGE in the earth's crust and in the exposed crust in East China, clearly Rh, Ru, Ir are enriched in the oil shale samples, and the abundance of Rh, Ir is about 10 times richer than that of the earth crust. The distribution of PGEs in the oil shale is characterized by Pt-Pd pattern，and generally Pt is richer than Pd. The positive relationship between PGEs and inorganic components shows that the PGEs probably occur in clay minerals such as kaolinite, glimmerton in adsorbed state.

Key words: oil shale, platinum group elements, chemical characteristics

CLC Number:

P618.12

WANG Wen-ying, SU Ke, GAO Gui-mei, GAN Shu-cai, LIU Zhao-jun. The Chemical Characteristics and Distribution of Platinum Group Elements in the Oil Shale Samples, Jilin Province[J].J4, 2006, 36(6): 969-0973.

References

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