Journal of Jilin University(Earth Science Edition) ›› 2018, Vol. 48 ›› Issue (4): 1043-1049.doi: 10.13278/j.cnki.jjuese.20170100

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Catalytic Pyrolysis of Oil Shale in the Presence of Three Kinds of Inorganic Salt

Abakar Rabiea, Sun Youhong, Han Jing, Guo Mingyi   

  1. College of Construction Engineering, Jilin University, Changchun 130026, China
  • Received:2017-11-11 Online:2018-07-26 Published:2018-07-26
  • Supported by:
    Supported by National Natural Science Foundation of China (51604123), Science and Technology Development Project of Jilin Province, China (20150520073JH) and Open Project of Key Laboratory of Complicated Condition Drilling Technology of Ministry of Land and Resources, China (2016-2017)

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Abstract: The pyrolysis of oil shale in the presence of the catalysis metal chloride (stannous chloride, molybdenum chloride, zinc chloride) was evaluated. Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and thermogravimetric (TG) analysis were conducted to characterize the solid residues. Moreover, the kinetic parameters were calculated using the Coats-Redfern method. The results showed that catalysts can promote the organic conversion to oil and gas at low temperature, and also effect on the activation energy of the solid residues, particularly with stannous chloride, molybdenum chloride and zinc chloride, with which the activation energy decreased about 15.10, 10.66 and 20.58 kJ/mol respectively compared to those with no catalyst therein.

Key words: oil shale, pyrolysis, catalyst, kinetics

CLC Number: 

  • P618.12
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