Journal of Jilin University(Earth Science Edition) ›› 2018, Vol. 48 ›› Issue (4): 1043-1049.doi: 10.13278/j.cnki.jjuese.20170100

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Catalytic Pyrolysis of Oil Shale in the Presence of Three Kinds of Inorganic Salt

Abakar Rabiea, Sun Youhong, Han Jing, Guo Mingyi   

  1. College of Construction Engineering, Jilin University, Changchun 130026, China
  • Received:2017-11-11 Online:2018-07-26 Published:2018-07-26
  • Supported by:
    Supported by National Natural Science Foundation of China (51604123), Science and Technology Development Project of Jilin Province, China (20150520073JH) and Open Project of Key Laboratory of Complicated Condition Drilling Technology of Ministry of Land and Resources, China (2016-2017)

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Abstract: The pyrolysis of oil shale in the presence of the catalysis metal chloride (stannous chloride, molybdenum chloride, zinc chloride) was evaluated. Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and thermogravimetric (TG) analysis were conducted to characterize the solid residues. Moreover, the kinetic parameters were calculated using the Coats-Redfern method. The results showed that catalysts can promote the organic conversion to oil and gas at low temperature, and also effect on the activation energy of the solid residues, particularly with stannous chloride, molybdenum chloride and zinc chloride, with which the activation energy decreased about 15.10, 10.66 and 20.58 kJ/mol respectively compared to those with no catalyst therein.

Key words: oil shale, pyrolysis, catalyst, kinetics

CLC Number: 

  • P618.12
[1] Na Jeong geol, Lm Cheol hyun, Chung Soo hyun, et al. Effect of Oil Shale Retorting Temperature on Shale Oil Yield and Properties[J]. Fuel, 2012, 95(1):131-135.
[2] 钱家麟,王剑秋,李述元. 世界油页岩资源利用和发展趋势[J].吉林大学学报(地球科学版), 2006, 36(6):877-887. Qian Jialin, Wang Jianqiu, Li Shuyuan. World Oil Shale Utilization and Its Future[J]. Journal of Jilin University (Earth Science Edition), 2006, 36(6):877-887.
[3] Jiang X M, Han X X, Cui Z G. Progress and Recent Utilization Trends in Combustion of Chinese Oil Shale[J]. Progress in Energy and Combustion Science, 2007, 33(6):552-579.
[4] Pan Yi, Zhang Xiaoming, Liu Shouhui, et al. A Review on Technologies for Oil Shale Surface Retort[J]. Journal of the Chemical Society of Pakistan, 2012, 34(6):1331-1338.
[5] Al-Makhadmeh L, Maier J, Scheffknecht G. Oxyfuel Technology:No Reduction During Oxy-Oil Shale Conditions[J]. Fuel, 2014, 128(21):155-161.
[6] Tiwari P, Deo M, Lin C L, et al. Characterization of Oil Shale Pore Structure Before and After Pyrolysis by Using X-Ray Micro CT[J]. Fuel, 2013, 107(9):547-554.
[7] Yan Junwei, Jiang Xiumin, Han Xiangxin, et al. A TG-FTIR Investigation to the Catalytic Effect of Mineral Matrix in Oil Shale on the Pyrolysis and Combustion of Kerogen[J]. Fuel, 2013, 104(2):307-317.
[8] Allawzi M, Al-Otoom A, Allaboun H, et al. CO2 Supercritical Fluid Extraction of Jordanian Oil Shale Utilizing Different Co-Solvents[J]. Fuel Processing Technology, 2011, 92(10):2016-2023.
[9] Liu Zhaojun, Dong Qingshui, Ye Songqing, et al. Oil Shale Character and Exploitation & Utilization Prospect[J]. Earth Science Frontiers, 2005, 12(3):315-323.
[10] Han Shuangbiao, Zhang Jinchuan, Li Yuxi, et al. Evaluation of Lower Cambrian Shale in Northern Guizhou Province, South China:Implications for Shale Gas Potential[J]. Energy & Fuels, 2013, 27(6):2933-2941.
[11] 刘招君,董清水,叶松青,等.中国油页岩资源现状[J]. 吉林大学学报(地球科学版),2006,36(5):869-876. Liu Zhaojun, Dong Qingshui, Ye Songqing, et al. The Situation of Oil Shale Resources in China[J]. Journal of Jilin University (Earth Science Edition), 2006, 36(6):869-876.
[12] Sun P, Sachsenhofer R F, Liu Z, et al. Organic Matter Accumulation in the Oil Shale-and Coal-Bearing Huadian Basin (Eocene; NE China)[J]. International Journal of Coal Geology, 2013, 105:1-15.
[13] Sun Youhong, Bai Fengtian, Liu Baochang, et al. Characterization of the Oil Shale Products Derived via Topochemical Reaction Method[J]. Fuel, 2014, 115(1):338-346.
[14] Guo Hongfan, Bie Yansong,Wang Kuikui, et al. Retorting Oil Shale by a Self-Heating Route[J]. Energ & Fuel, 2013, 27(5):2445-2451.
[15] Ballice L. Stepwise Chemical Demineralization of Göynük (Turkey) Oil Shale and Pyrolysis of Demineralization Products[J]. Industrial & Engineering Chemistry Research, 2006, 45(3):906-912.
[16] Patterson J H. A Review of the Effects of Minerals in Processing of Australian Oil Shales[J]. Fuel, 1994, 73(3):321-327.
[17] Wlliams P T, Chishti H M. Two Stage Pyrolysis of Oil Shale Using a Zeolite Catalyst[J]. Journal of Analytical & Applied Pyrolysis, 2000, 55(2):217-234.
[18] Metecan I H, Saglam M, Yanik J, et al. Effect of Pyrite Catalyst on the Hydroliquefaction of Goynuk (Turkey) Oil Shale in the Presence of Toluene[J]. Fuel, 1999, 78(5):619-622.
[19] Tiikma L, Johannes I, Luik H, et al. Thermal Dissolution of Estonian Oil Shale[J]. Journal of Analytical & Applied Pyrolysis, 2009, 85(1):502-507.
[20] Jiang Haifeng, Song Lihua, Cheng Zhiqiang, et al. Influence of Pyrolysis Condition and Transition Metal Salt on the Product Yield and Characterization via Huadian Oil Shale Pyrolysis[J]. Journal of Analytical and Applied Pyrolysis, 2015, 112(1):230-236.
[21] Pulushev D A, Rossa J R H. Catalysis for Conversion of Biomass to Fuels via Pyroly is and Gasification[J]. Catalysis Today, 2011, 171:1-13.
[22] Espitalie J, Madec M, Tissot B. Role of Mineral Matrix in Kerogen Pyrolysis:Influence on Petroleum Generation and Migration[J]. AAPG Bull, 1980, 64(1):59-66.
[23] Wei Z, Moldowan J M, Paytan A. Diamondoids and Molecular Biomarkers Generated from Modern Sediments in the Absence and Presence of Minerals During Hydrous Pyrolysis[J]. Organic Geochemistry, 2006, 37(8):891-911.
[24] ASTM D4749-1987(2012) Standard Test Method for Performing the Sieve Analysis of Coal and Designating Coal Size[S/OL].[2012-05-10]. http://www.zbgb.org/48/StandardDetail2310510.htm.
[25] GB 474-2008煤样的制备方法[S]. 北京:中国标准出版社,2008. GB 474-2008 Method for Preparation of Coal Sample[S]. Beijing:Standards Press of China, 2008.
[26] Kok M V. Effect of Clay on Crude Oil Combustion by Thermal Analysis Techniques[J]. Journal of Thermal Analysis Calorimetry, 2006, 84(2):361-366.
[27] Coats A W, Redfern J P. Kinetic Parameters from Thermogravimetric Data[J]. Nature, 1964, 201:68-69.
[28] Bolonkin A, Friedlander J, Neumann S, et al. Innovative Unconventional Oil Extraction Technologies[J]. Fuel Processing Technology, 2014, 124(10):228-242.
[29] 刘德勋,王红岩,郑德温,等. 世界油页岩原位开采技术进展[J]. 天然气工业,2009,29(5):128-132. Liu Dexun, Wang Hongyan, Zheng Dewen, et al. World Progress of Oil Shale In-Situ Exploitation Methods[J]. Natural Gas Industry, 2009, 29(5):128-132.
[30] Bhargava S, Awaja F, Subasinghe N D, et al. Characterisation of Some Australian Oil Shale Using Thermal, X-Ray and IR Techniques[J]. Fuel, 2005, 84(6):707-715.
[31] Adams M J, Awaja F, Bhargava S, et al. Prediction of Oil Yield from Oil Shale Minerals Using Diffuse Reflectance Infrared Fourier Transform Spectroscopy[J]. Fuel, 2005, 84(14):1986-1991.
[32] Wlliams D J, Akira S. Clay Minerals and Petroleum-Forming Reactions During Burial and Diagenesis[J]. AAPG Bull1, 1972, 56(11):2160-2167.
[33] Wlliams D J. Clay Mineral Catalysis and Petroleum Generation[J]. Annual Review of Earth & Planetary Sciences, 1979, 7(1):183-198.
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