There occurs falkmanite in the Bairendaba superlarge Ag-Pb-Zn polymetallic deposit in Inner Mongolia, China. It is intimately accompanied by galenite, Ag-tetrahedrite, pyrrhotite, chalcopyrite, and boulangerite. Falkmanite crystals show as needle, pillar, prismatic, hair-like, bunchiness and anhedral grain forms, and its grain sizes commonly vary from 0.05 to 4 mm, even to 12 mm. The mineral is lightly grey-white in colour, metallic in lustur and brashy,93.25 to 127.39 kg/mm2, averaging 111.05 kg/mm for 100g load in microhardness and Moh’s=3.06~3.40. Electron microprobe analyses of seven points in the falkmanite gave the compositional results as followings(%):Pb 52.20~57.80 (54.89 on average),Sb 22.26~28.13 (26.08 on average),S 18.65~19.62 (19.01 on average), and minor contents of Fe, Cu, Zn, Ag and As, corresponding to the formula (Pb4.91,Cu0.04,Fe0.03,Zn0.01)4.99(Sb3.97,As0.04)4.01S11.00, and its simplified formula Pb5Sb4S11. The crystals are monoclinic, with cell dimensions a 2.156, b 2.349, c 0.810 nm. The formation of falkmanite would be favored by a low temperature, increasing f S2 and reduced fluid conditions during polymetallic mineralization.