Journal of Jilin University(Engineering and Technology Edition) ›› 2024, Vol. 54 ›› Issue (3): 674-682.doi: 10.13229/j.cnki.jdxbgxb.20220457

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Nickel⁃Cobalt sulfide/phosphide nanocomposite for hydrogen evolution reaction

Su-feng WEI1(),Dian-dong SUN2,Jun-yu ZHANG3,Yu-zhe WANG3,En-ze LI1,Guo-yong WANG3()   

  1. 1.College of Materials Science and Engineering，Changchun University of Technology，Changchun 130012，China
    2.State Key Laboratory of Metal Material for Marine Equipment and Application，Ansteel Group，Anshan 114021，China
    3.College of Materials Science and Engineering，Jilin University，Changchun 130022，China
  • Received:2022-05-16 Online:2024-03-01 Published:2024-04-18
  • Contact: Guo-yong WANG E-mail:weisufeng@gmail.com;materwanggy@jlu.edu.cn

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Abstract:

For seeking cheap， high performance and stable catalysts to replace noble metals. In this paper， sulfide/phosphide catalysts were obtained by one-step annealing treatment with transition metals Ni/Co， and the successful preparation of the catalysts was verified by electron detection and elemental analysis method. The electrochemical test results showed that the catalytic activity and charge transfer rate of the prepared Ni-Co sulfide/phosphide exceeded those of Ni-Co hydroxide/sulfide/phosphide due to the synergistic effect between anions/cations. Ni-Co sulfur/phosphide only requires an overpotential of 106 mV to achieve a current density of 10 mA·cm-2 and the stability was more than 20 h.

Key words: transition metal based catalyst, hydrogen evolution reaction, sulphide phosphates, heterostructure, synergistic effect

CLC Number: 

  • TB332

Fig.1

Schematic diagram of NCSP composite synthesis"

Fig.2

FESEM image of four different morphologies of hydroxides"

Fig.3

Morphology and microstructure diagram of NCSP"

Fig.4

XRD diffraction diagram of Ni x Co1-x （OH）2 and the NCSP composite"

Fig. 5

Full scan spectra of XPS patterns for NCSP，NCS，NCP and Ni0.5Co0.5（OH）2"

Fig.6

XPS characterization diagrams of NCSP"

Fig.7

HER performance analysis charts"

Table 1

Performance comparison between NCSP and other catalysts for HER in 1.0 M KOH"

催化剂过电势/mV（j=10 mA·cm-2）Tafel斜率/（mV·dec-1）参考文献
NiFeSP9182.6［19］
Mn-CoP nanosheets14861［20］
Ni-Co-P-30015060.6［21］
Co-Ni-P16771.2［21］
CoP NA/CC145123［22］
Co0.85Se/NiFe-LDH280160［23］
O-Co2P16065.8［24］
CoPS film12857［25］
NCSP10674本文

Fig.8

CV curves with various scan rates （20， 40， 60， 80， 100， 120 and 140 mV·s-1） and the plots of the current density versus the scan rate of NCSP"

1 Cao S, Wang C J, Fu W F, et al. Metal phosphides as Co-Catalysts for photocatalytic and photoelectrocatalytic water splitting[J]. ChemSusChem, 2017, 10(22): 4306-4323.
2 Guo L, Zhao Y, Yao Z. Mechanical mixtures of metal oxides and phosphorus pentoxide as novel precursors for the synthesis of transition-metal phosphides[J]. Dalton Trans, 2016, 45(3): 1225-1232.
3 Hong L F, Guo R T, Yuan Y, et al. Recent progress of transition metal phosphides for photocatalytic hydrogen evolution[J]. ChemSusChem, 2020, 14(2): 539-557.
4 Li R, Zang J, Li W, et al. Three-dimensional transition metal phosphide heteronanorods for efficient overall water splitting[J]. ChemSusChem, 2020, 13(14): 3718-3725.
5 王凤武, 朱传高, 方文彦,等. 有机体系中制备纳米TiO2掺杂Ni电极及其性能测试[J]. 吉林大学学报:工学版, 2006(6): 861-865.
Wang Feng-wu, Zhu Chuan-guo, Fang Wen-yan, et al. Preparation of TiO2 nanodoped Ni electrodes in organic systems and their performance tests[J]. Journal of Jilin University (Engineering Edition), 2006(6): 861-865.
6 Yin J, Wu B, Wang Y, et al. Novel elastic, lattice dynamics and thermodynamic properties of metallic single-layer transition metal phosphides: 2H-M 2P (Mo2P, W2P, Nb2P and Ta2P)[J]. Journal of Physics: Condensed Matter, 2018, 30(13): No. 135701.
7 Su P, Li Y, Zhang J, et al. Characterization and chemical fixation of stainless steel pickling residue using sodium sulfide hydrate[J]. Environmental Science and Pollution Research, 2019, 26(10): 10240-10250.
8 Kong D S, Cha J J, Wang H, et al. First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction[J]. Energy & Environmental Science, 2013, 6(12): 3553-3558.
9 Peng S, Li L, Han X, et al. Cobalt sulfide nanosheet/graphene/carbon nanotube nanocomposites as flexible electrodes for hydrogen evolution[J]. Angewandte Chemie, 2014, 126(46): 12802-12807.
10 Pan Y, Chen Y, Lin Y, et al. Cobalt nickel phosphide nanoparticles decorated carbon nanotubes as advanced hybrid catalysts for hydrogen evolution[J]. Journal of Materials Chemistry A, 2016, 4: 14675-14686.
11 Xin Y, Kan X, Gan L, et al. Heterogeneous Bimetallic Phosphide/Sulfide Nanocomposite for Efficient Solar-Energy-Driven Overall Water Splitting[J]. ACS Nano, 2017, 11: 10303-10312.
12 Acevedo M, Stone M, Schmidt J, et al. Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide[J]. Nature Materials, 2015, 14: 1245-1251.
13 Liu W, Hu E, Jiang H, et al. A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide[J]. Nature Communications, 2016, 7: No. 10771.
14 Xiao J, Zeng X, Chen W, et al. High electrocatalytic activity of self-standing hollow NiCo2S4 single crystalline nanorod arrays towards sulfide redox shuttles in quantum dot-sensitized solar cells[J]. Chemical Communications, 2013, 49: 11734-11736.
15 Yan X, Tian L, Chen X. Crystalline/amorphous Ni/NiO core/shell nanosheets as highly active electrocatalysts for hydrogen evolution reaction[J]. Journal of Power Sources, 2015, 300: 336-343.
16 Feng Y, Yu X, Paik U. Nickel cobalt phosphides quasi-hollow nanocubes as an efficient electrocatalyst for hydrogen evolution in alkaline solution[J]. Chemical Communications, 2016, 52: 1633-1636.
17 Gong Y Q, Xu Z F, Pan H L, et al. A 3D well-matched electrode pair of Ni-Co-S//Ni-Co-P nanoarrays grown on nickel foam as a high-performance electrocatalyst for water splitting[J]. Journal of Materials Chemistry A, 2018, 6: 12506-12514.
18 Kim J, Li X, Kang B, et al. High-rate performance of a mixed olivine cathode with off-stoichiometric composition[J]. Chemical Communications, 2015, 51: 13279-13282.
19 Xin Y, Kan X, Gan L Y, et al. Heterogeneous bimetallic phosphide/sulfide nanocomposite for efficient solar-energy-driven overall water splitting[J]. ACS nano, 2017, 11(10): 10303-10312.
20 Li Y, Jia B, Chen B, et al. MOF-derived Mn doped porous CoP nanosheets as efficient and stable bifunctional electrocatalysts for water splitting[J]. Dalton Transactions, 2018, 47(41): 14679-14685.
21 Feng Y, Yu X Y, Paik U. Nickel cobalt phosphides quasi-hollow nanocubes as an efficient electrocatalyst for hydrogen evolution in alkaline solution[J]. Chemical Communications, 2016, 52(8): 1633-1636.
22 Huang Z, Liu J, Xiao Z, et al. A MOF-derived coral-like NiSe@ NC nanohybrid: an efficient electrocatalyst for the hydrogen evolution reaction at all pH values[J]. Nanoscale, 2018, 10(48): 22758-22765.
23 Cheng X, Pan Z, Lei C, et al. A strongly coupled 3D ternary Fe2O3@Ni2P/Ni(PO3)2 hybrid for enhanced electrocatalytic oxygen evolution at ultra-high current densities[J]. Journal of Materials Chemistry A, 2019, 7(3): 965-971.
24 Xu K, Ding H, Zhang M, et al. Regulating water‐reduction kinetics in cobalt phosphide for enhancing HER catalytic activity in alkaline solution[J]. Advanced Materials, 2017, 29(28): No. 1606980.
25 Cabán-Acevedo M, Stone M L, Schmidt J R, et al. Efficient hydrogen evolution catalysis using ternary pyrite-type cobalt phosphosulphide[J]. Nature Materials, 2015, 14(12): 1245-1251.
26 张蕾, 张磊, 舒新前, 等. 核桃壳催化热解制取氢气[J]. 吉林大学学报: 工学版, 2008, 38(2): 287-291.
Zhang Lei, Zhang Lei, Shu Xin-qian, et al. Catalytic pyrolysis of walnut shells for hydrogen production[J]. Journal of Jilin University (Engineering and Technology Edition), 2008, 38(2): 287-291.
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