溶剂散逸自组装法制备定向透光金属有序光子膜

吉林大学学报(理学版) ›› 2026, Vol. 64 ›› Issue (1): 143-0148.

溶剂散逸自组装法制备定向透光金属有序光子膜

程欣, 王芃芃, 贾若琨

东北电力大学化学工程学院, 吉林吉林 132012

收稿日期:2024-11-01 出版日期:2026-01-26 发布日期:2026-01-26
通讯作者: 贾若琨 E-mail: jiaruokun@163.com

Preparation of Oriented Light-Transmitting Metal Ordered Photonic Films by Solvent Evaporation Self-assembly Method

CHENG Xin, WANG Pengpeng, JIA Ruokun

College of Chemical Engineering, Northeast Electric Power University, Jilin 132012, Jilin Province, China

Received:2024-11-01 Online:2026-01-26 Published:2026-01-26

摘要/Abstract

摘要： 在潮湿条件下, 利用溶剂散逸自组装法制备聚己内酯（PCL）有序光子膜. 通过控制溶液浓度得到高度有序的多孔贯通膜. 用离子溅射法将贯通膜表面吸附一层金属, 并将银氨溶液置换成银. 结果表明：这种银包覆的有序多孔贯通膜具有双层有序多孔结构, 显著增强其导电性; 与单层膜相比, 双层膜透光性受入射角度的限制, 可实现定向透光的功能; 经热处理后的光子膜性质发生变化, 具有耐高温性质, 且各角度的透光性均增强；这种定向透光有序阵列膜具有电磁屏蔽的特性.

关键词: 溶剂散逸自组装, 聚己内酯, 有序光子膜, 定向透光

Abstract: Under humid conditions, we prepared polycaprolactone (PCL) ordered photonic films by using solvent evaporation self-assembly method. We obtained highly ordered porous through films by controlling the solution concentration. We used ion sputtering method to adsorb a layer of metal on the surface of the through films, and replaced silver ammonia solution with silver. The results show that this silver-coated ordered porous through film has a double-layer ordered porous structure, and its conductivity is significantly enhanced. Compared with the single-layer film, the light transmittance of the double-layer film is limited by the incident angle and can achieve the function of directional light transmission. The properties of the heat-treated photonic films change, exhibiting high-temperature resistance and enhanced light transmittance at all angles. This directional light transmission ordered array film has the characteristics of electromagnetic shielding.

Key words: solvent evaporation self-assembly, polycaprolactone, ordered photonic film, directional light transmission

中图分类号:

O484

程欣, 王芃芃, 贾若琨. 溶剂散逸自组装法制备定向透光金属有序光子膜[J]. 吉林大学学报(理学版), 2026, 64(1): 143-0148.

CHENG Xin, WANG Pengpeng, JIA Ruokun. Preparation of Oriented Light-Transmitting Metal Ordered Photonic Films by Solvent Evaporation Self-assembly Method[J]. Journal of Jilin University Science Edition, 2026, 64(1): 143-0148.

[1]	韩梦瑶, 孙辉, 周鸥翔, 齐东丽, 李同辉, 沈龙海. Ag掺杂In₂O₃薄膜的制备及其光电性能[J]. 吉林大学学报(理学版), 2024, 62(4): 985-991.
[2]	卢婉, 杨永彪, 丁明明. 用有限元模拟方法研究阶层式多孔薄膜几何参数对水通量的影响[J]. 吉林大学学报(理学版), 2024, 62(3): 721-727.
[3]	田惠博, 张强, 闫岩, 赵淑华, 王丽丽, 王欣, 孙德烨. Ag/石墨烯复合涂层的制备及抗菌性能[J]. 吉林大学学报(理学版), 2020, 58(2): 403-409.
[4]	王宇, 王丽丽, 王欣, 陈蕊, 李宏广, 刘正杭, 陈国利. 阶梯热还原法制备Fe₃O₄/rGO复合膜[J]. 吉林大学学报(理学版), 2019, 57(06): 1491-1496.
[5]	刘伟达, 陈蕊, 王丽丽, 李宏广, 安涛, 张东辉, 徐士翀. 不同基片生长γ′-Fe_4N薄膜的结构及其磁学性能[J]. 吉林大学学报(理学版), 2019, 57(1): 156-160.
[6]	徐强, 杨光敏, 邢光宗. 稀磁半导体Cr_xMn_1-xTe的第一性原理计算[J]. 吉林大学学报(理学版), 2015, 53(04): 762-765.
[7]	徐强, 杨光敏, 邢光宗. 稀磁半导体MnTe和CrTe的微观结构及电磁性能[J]. 吉林大学学报(理学版), 2015, 53(03): 553-560.
[8]	王丽丽, 闫岩, 安涛, 卢歆, 谭芳, 王立杰, 邹林. Fe₃N纳米晶薄膜退火过程的结构演变及其磁性[J]. 吉林大学学报(理学版), 2013, 51(06): 1148-1150.
[9]	刘楠, 赵长春, 孙瑶, 王新, 李野, 端木庆铎. Cu薄膜生长初期的计算机模拟[J]. J4, 2013, 51(02): 301-304.
[10]	王丽丽, 安涛, 郑伟涛. γ′-（Fe_1-xNi_x)₄N薄膜结构及其磁学性能[J]. J4, 2012, 50(02): 337-340.
[11]	王丽丽, 王志军, 宋立军, 杨睿, 金勇, 安涛, 苏杭, 王永权, 李守春. Mn掺杂纳米晶ZnO的制备及其性质[J]. J4, 2011, 49(06): 1110-1114.
[12]	王健, 白亦真, 张东, 潘丽, 柳浩, 管昌雨, 吴占玲, 赵纪军. 用不同靶材制备B\\|C\\|N薄膜及其红外表征[J]. J4, 2010, 48(06): 1027-1030.
[13]	李启源, 魏长平, 孙小飞. 退火温度对ZnO/SiO₂复合薄膜结构及光学性能的影响[J]. J4, 2010, 48(03): 478-481.
[14]	郭守月, 曹春斌, 孙兆奇. 掺银ITO薄膜退火前后的性能比较[J]. J4, 2010, 48(02): 291-294.
[15]	姜伟棣, 宫杰, 焦志伟. Cr/Gd 双层膜的磁特性[J]. J4, 2010, 48(02): 299-302.