系列Fe(Ⅲ)草酸配位超分子的合成、 结构及磁性

J4 ›› 2009, Vol. 47 ›› Issue (05): 1071-1080.

Previous Articles Next Articles

Synthesis, Crystal Structure and Magnetism of ThreeFe(Ⅲ)Oxlate Super Molecules

WU Hanqing, NIU Shuyun, JIN Jing, WANG Yao

School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, China

Received:2009-01-13 Online:2009-09-26 Published:2009-11-03
Contact: NIU Shuyun E-mail:syniu@sohu.com.

Abstract

Abstract:

Three Fe（Ⅲ）coordination supramolecules ［Fe(phen)₃］［Fe(ox)₃］·KOH·6H₂O(1), ［Fe(en)₂(ox)］［Fe(en)(ox)₂］·2H₂O(2), K₃(glycol)·(Fe_0.2Cr_0.8)(ox)₃(3),(phen=phenanthroline, en=ethylenediamine, ox=oxalate acid) were synthesized. The crystal structures of the complexes were determined by Xray single crystal diffraction, and the complexes were characterized by IR, UVVis and magnetic susceptibility. At a low temperature compounds 1~3 all show antiferromagnetism, compound 2 shows the highest antiferromagnetism.

Key words: Fe（Ⅲ）coordination supramolecule, crystal structure, spectra, magnetic

CLC Number:

O614

WU Han-Qing, NIU Chu-Yun, JIN Jing, WANG Yao. Synthesis, Crystal Structure and Magnetism of ThreeFe(Ⅲ)Oxlate Super Molecules[J].J4, 2009, 47(05): 1071-1080.

[1]	ZHOU Ruisha, SU Yahui, CHAI Jiaqi, LI He, SONG Jiangfeng. Two New Hydroxyl Sulfate Frameworks： In situ Synthesis of Organic Sulfur and Crystal Structures [J]. Journal of Jilin University Science Edition, 2021, 59(3): 676-681.
[2]	SU Lijuan, ZHANG Xiaoyu, ZHOU Ruisha. Synthesis and Thermal Stability of a Copper 3,5PyrazoleDicarboxylate Coordination PolymerContaining MetalWater Chain [J]. Journal of Jilin University Science Edition, 2020, 58(4): 1015-1019.
[3]	ZHAO Zhixin, TANG Hui. Stability Analysis of Repairable Systemwith Two Different Failure Modes [J]. Journal of Jilin University Science Edition, 2020, 58(2): 285-292.
[4]	WANG Li, FU Yuanxia, XU Li, GONG Hao, YANG Hao. Time Evolution Characteristics of Zn Plasma Spectra in Brass Induced by Laser [J]. Journal of Jilin University Science Edition, 2020, 58(1): 140-144.
[5]	WANG Sen, WANG Xuesong, ZHANG Xin, SHI Guoxin, WANG Jian. Application of NearInfrared Spectroscopy inMonitoring Fermentation Process of L-Isoleucine [J]. Journal of Jilin University Science Edition, 2020, 58(1): 177-183.
[6]	WANG Yu, WANG Chunjie, ZHANG Haixiang. Weighed Conditional Least Squares Estimation for ADCINAR(1) Model [J]. Journal of Jilin University Science Edition, 2019, 57(3): 553-561.
[7]	XIAO Xiao, LI Jiwei, HU Min, SUN Zhenyuan, LI Caixia, JIANG Tao. Crystal Structure and Antitumor Activity ofa Triphenyl Organotin Complex [J]. Journal of Jilin University Science Edition, 2019, 57(04): 973-978.
[8]	HAN Guanghui, QU Gangrong. Relaxation Strategy for Richardson Iterative Method [J]. Journal of Jilin University Science Edition, 2018, 56(6): 1379-1384.
[9]	BAO Jie, OU Renxia. Spectral Properties of Acetonum Moleculeunder Asymmetric External Field [J]. Journal of Jilin University Science Edition, 2018, 56(3): 713-717.
[10]	ZHOU Qin, YANG Yin. Spectral Collocation Method for Solving Nonlinear TimeFractional KleinGordon Equation [J]. Journal of Jilin University Science Edition, 2018, 56(2): 286-292.
[11]	CHEN Xiao, SHEN Hongjian, LI Fei, WANG Xi, WEN Changji. Salient Text Detection Method Based on SpectralResidual and Stroke Width Transform [J]. Journal of Jilin University Science Edition, 2017, 55(06): 1528-1533.
[12]	ZHAO Jianxing. Estimates of Lower Bounds for Minimum Eigenvalueof Nonsingular M-Matrices [J]. Journal of Jilin University Science Edition, 2017, 55(03): 553-558.
[13]	ZHAO Haishi, LU Laijun, YANG Chen. A Method for Density Peaks Clustering BandSelection Based on Image Entropy [J]. Journal of Jilin University Science Edition, 2017, 55(02): 376-378.
[14]	SUN Yuan, SUN Zhenghao, LENG Jing, WANG Lili, YANG Qiang, LIU Weida, LIU Runru. FirstPrinciples Calculation on Magnetism of MultiferroicMaterials BiNi_xFe_1-xO₃(x=0~0.5) [J]. Journal of Jilin University Science Edition, 2017, 55(02): 398-402.
[15]	XU Yi, FAN Huimin. Software Defect Analysis Algorithm Based on Combinationof Spectral Clustering and Chaotic Immunity [J]. Journal of Jilin University Science Edition, 2016, 54(05): 1082-1086.

Synthesis, Crystal Structure and Magnetism of ThreeFe(Ⅲ)Oxlate Super Molecules

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0