J4 ›› 2010, Vol. 48 ›› Issue (02): 313-318.
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XU Yuehua, FU Shuang, XU Jianing, FENG Shouhua
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K0.81Li0.27Ti1.73O4 was synthesized by a solid state reaction. The conditions such as materials ratios, reaction time and reaction temperature, which are the main influencing factors of the H+ ionic exchange reaction and exfoliation of K0.81Li0.27Ti1.73O4 were studied. The results show that K0.81Li0.27Ti1.73O4 can be transformed into H1.08Ti1.73O4·H2O in a 0.1~14 mol/L HNO3 solution by ionic exchange. If the reaction temperature is higher, the product is transformed into TiO2. The optimum H+exchange conditions are: the concentration of HNO3 is 1~10 mol/L, n(HNO3) ∶〖KG-*3〗n(KLiTiO)=10~20, at room temperature for 4~7 d. H1.08Ti1.73O4·H2O can be exfoliated by both npropylamine (n\|PA) and nbutylamine. The exfoliation of H1.08Ti1.73O4·H2O is sensibly influenced by the reaction temperature and the ratio of H1.08Ti1.73O4·H2O and amine, i.e., at a higher temperature and/or a smaller ratio of amine and H1.08Ti1.73O4·H2O , the product is TiO2 rather than a layered compound. The optimum exfoliation (or intercalation) conditions are: n(nPA) ∶ n(HTiO)=20~100, at 120 ℃ for 1 d.
Key words: layered oxides, layered titanate, H+ionic exchange, intercalation and exfoliation, K0.81Li0.27Ti1.73O4
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XU Ti-Hua, FU Shuang, XU Jia-Ning, FENG Shou-Hua. The H+Exchange and Exfoliation Reactions of K0.81Li0.27Ti1.73O4[J].J4, 2010, 48(02): 313-318.
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http://xuebao.jlu.edu.cn/lxb/EN/Y2010/V48/I02/313
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