滇西兰坪盆地中-新生代蒸发岩元素地球化学特征及其形成环境

doi:10.13278/j.cnki.jjuese.20180221

吉林大学学报(地球科学版) ›› 2019, Vol. 49 ›› Issue (2): 356-379.doi: 10.13278/j.cnki.jjuese.20180221

滇西兰坪盆地中-新生代蒸发岩元素地球化学特征及其形成环境

张治波^1,2, 朱志军¹, 王文锋¹, 徐颖¹, 李丽荣¹

1. 东华理工大学地球科学学院, 南昌 330013;
2. 陕西省一九四煤田地质有限公司, 陕西铜川 727000

收稿日期:2018-08-22 出版日期:2019-03-26 发布日期:2019-03-28
通讯作者: 朱志军(1976-),男,副教授,博士,主要从事沉积学方面的研究,E-mail:zhuzj013@163.com E-mail:zhuzj013@163.com
作者简介:张治波(1987-),男,硕士,主要从事沉积学和石油地质学方面的研究,E-mail:zzb397132190@126.com
基金资助:
国家自然科学基金项目（41362008）；江西省研究生创新项目（YC2016-S277）

Geochemical Characteristics and Formation Environment of Mesozoic and Cenozoic Evaporative Rocks in Lanping Basin, Western Yunnan

Zhang Zhibo^1,2, Zhu Zhijun¹, Wang Wenfeng¹, Xu Ying¹, Li Lirong¹

1. College of Earth Sciences, East China University of Technology, Nanchang 330013, China;
2. Shaanxi Province 194 Coalfield Geology Co., Ltd., Tongchuan, 727000, Shaanxi, China

Received:2018-08-22 Online:2019-03-26 Published:2019-03-28
Supported by:
Supported by National Natural Science Foundation of China (41362008) and Jiangxi Province Graduate Innovation Project (YC2016-S277)

摘要/Abstract

摘要： 兰坪盆地蒸发岩极为发育，且与贱金属矿关系密切。本文采用电感耦合等离子体质谱（ICP-MS）方法对兰坪盆地三叠系三合洞组和古近系云龙组的石膏、灰岩和膏泥共计49件样品进行了稀土元素及微量元素分析，结果显示石膏和灰岩地球化学特征相近，而它们与膏泥的地球化学特征差异较大。具体表现在：石膏和灰岩的稀土配分模式曲线相对比较平缓且混乱，不同的是石膏Eu的正负异常均有出现，而灰岩仅出现Eu的负异常；石膏和灰岩微量元素的Sr/Ba、Sr/Cu、V/Cr、V/（V+Cr）、Ni/Co、U/Th和δU的特征值类似，但与膏泥明显不同；膏泥的稀土元素显示Eu负异常明显"V"字形右倾的配分模式，相对于石膏和灰岩比较陡峭。上述表明石膏和灰岩形成于气候干热的咸水-缺氧的还原环境中，不同的是它们的物质来源不同：石膏的盐源有深部卤水参与；而灰岩则无深部卤水参与；膏泥形成于气候温湿的半咸水-淡水-富氧的氧化环境，其物质来源却与灰岩类似，可能是气候的周期性变化所致。

关键词: 地球化学, 蒸发岩, 石膏, 兰坪盆地, 环境

Abstract: Evaporates are widely developed in Lanping basin and closely related to base metal. In this study, the rare earth elements and trace elements of 49 gypsum, limestone and paste mud samples from Triassic Sanhedong Formation and Paleogene Yunlong Formation in Lanping basin were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The results show that the geochemical characteristics of gypsum and limestone are similar but different from those of plaster. The characteristics of rare earth partitioning mode of gypsum and limestone are relatively flat and chaotic. The difference is that both positive and negative Eu anomalies of gypsum occur, while only negative Eu anomalies are found in limestone.The characteristic ratios of Sr/Ba, Sr/Cu, V/Cr, V/(V+Cr), Ni/Co, U/Th and δU of gypsum and limestone are similar,but they are significantly different from paste. The rare earth elements of paste show an obvious "V" shape of negative Eu anomaly,more steep than those of gypsum and limestone. It indicates that gypsum and limestone were formed in a salt-water-anoxic reductive environment of dry climate, with different material sources:The salt source of gypsum was participated by deep brine, while the limestone was not involve in deep brine.Plaster was formed in warm and humid oxidation environment of brackish water, fresh water and oxygen-rich water, and its material source is similar to that of limestone, which may be caused by cyclical changes in climate.

Key words: geochemistry, evaporate, gypsum, Lanping basin, environment

中图分类号:

P588.247

张治波, 朱志军, 王文锋, 徐颖, 李丽荣. 滇西兰坪盆地中-新生代蒸发岩元素地球化学特征及其形成环境[J]. 吉林大学学报(地球科学版), 2019, 49(2): 356-379.

Zhang Zhibo, Zhu Zhijun, Wang Wenfeng, Xu Ying, Li Lirong. Geochemical Characteristics and Formation Environment of Mesozoic and Cenozoic Evaporative Rocks in Lanping Basin, Western Yunnan[J]. Journal of Jilin University(Earth Science Edition), 2019, 49(2): 356-379.

参考文献

[1] 高建华.滇西金顶铅锌矿床和蒸发岩建造成因关系的初步探讨[J].地球科学:中国地质大学学报,1989,14(5):513-522. Gao Jianhua.Preliminary Study on the Relationship Between the Genesis of the Jinding Lead-Zinc Beposit and the Construction of Evaporative Rock in Western Yunnan[J].Earth Science:Journal of China University of Geosciences,1989,14(5):513-522.
[2] 王安建,曹殿华,高兰,等.论云南兰坪金顶超大型铅锌矿床的成因[J].地质学报,2009,83(1):43-54. Wang Anjian,Cao Dianhua,Gao Lan,et al.On the Genesis of Super Large Lead-Zinc Beposit in Lanping,Yunnan[J].Acta Geologica Sinica,2009,83(1):43-54.
[3] 朱志军,姜勇彪,郭福生,等,兰坪盆地古近纪沉积相类型及沉积环境演化[J].岩石矿物学杂志,2011,30(3):409-418. Zhu Zhijun,Jiang Yongbiao,Guo Fuseng,et al.Lanping Basin Paleogene Sedimentary Facies Types and Sedimentary Environment Evolution[J].Acta Petrologica Et Mineralogica,2011,30(3):409-418.
[4] 董帅.兰坪金顶铅锌矿区盐丘构造发育特征及形成机制[D].昆明:昆明理工大学,2012. Dong Shuai.Structural Development Characteristics and Formation Mechanism of Salt Mounds in Lanping Jinding Pb-Zn Mining Area[D].Kunming:Kunming University of Technology,2012.
[5] 李彬,薛传东,董帅.兰坪金顶铅锌矿床膏盐与成矿关系初探[J].科学技术与工程,2012,12(20):4881-4885. Li Bin,Xue Chuandong,Dong Shuai.Preliminary Study on the Relationship Between Ointment Salt and Metallogenic in Lanping Jinding Pb-Zn Deposit[J].Science Technology and Engineering,2012,12(20):4881-4885.
[6] 胡古月,李延河,曾普胜.膏盐在金顶铅锌矿成矿中的作用:硫和锶同位素证据[J].地质学报,2013,87(11):1694-1702. Hu Guyue,Li Yanhe,Zeng Pusheng.The Role of Ointment Salt in Metallogenic Mineralization of Jinding Lead-Zinc Ore:Isotopic Evidence of Sulfur and Strontium[J].Acta Geologica Sinica,2013,87(11):1694-1702.
[7] 罗君烈,杨友华,赵准,等.滇西特提斯的演化及主要金属矿床的成矿作用[M].北京:地质出版社,1994:157-215. Luo Junlie,Yang Youhua,Zhao Zhun,et al. The Evolution of the Western Tethys and the Mineralization of Major Metal Beposits[M].Beijing:Geological Publishing House,1994:157-215.
[8] 王义昭,李兴林,段丽兰,等.三江地区南段大地构造与成矿[M].北京:地质出版社,2000:107-120. Wang Yizhao,Li Xinglin,Duan Lilan,et al.The Tectonic and Mineralization of the Southern Section of the Sanjiang Area[M].Beijing:Geological Publishing House,2000:107-120.
[9] 帅开业.云南中、新生代地质构造演化与蒸发岩建造[J].现代地质,1987,1(2):207-229. Shuai Kaiye.Geological Tectonic Evolution and Evaporation Rock Construction in Mesozoic and Cenozoic in Yunnan[J].Geoscience,1987,1(2):207-229.
[10] 张治波.兰坪盆地蒸发岩的地球化学特征及其与金属成矿关系探讨[D].南昌:东华理工大学,2018. Zhang Zhibo.Geochemical Characteristics of Evaporative Rocks in Lanping Basin and Their Relationship with Metal Mineralization[D].Nanchang:East China University of Technology,2018.
[11] 曲一华,袁品泉,帅开业,等.兰坪-思茅盆地钾盐成矿规律及预测[M].北京:地质出版社,1998. Qu Yihua,Yuan Pinquan,Shuai Kaiye,et al.Metallogenic Regularity and Prediction of Potassium Salt in Lanping-Simao Basin[M].Beijing:Geological Publishing House,1998.
[12] 郭福祥.滇西兰坪思茅地区晚白垩世至早第三纪的成盐带和成盐期[J].地质科学,1986(2):161-169. Guo Fuxiang.Salt Belt and Salt-Forming Period of Late Cretaceous to Early Tertiary in Lanping Simao Area,Western Yunnan[J].Chinese Journal of Geology,1986(2):161-169.
[13] 朱志军,姜勇彪,郭福生,等.兰坪盆地古近纪沉积相类型及沉积环境演化[J].岩石矿物学杂志,2011,30(3):409-418. Zhu Zhijun,Jiang Yongbiao,Guo Fusheng,et al.Paleogene Sedimentary Facies Types and Sedimentary Environment Evolution in Lanping Basin[J].Acta Petrologica Et Mineralogica,2011,30(3):409-418.
[14] 刘成林,焦鹏程,王弭力,等.新疆罗布泊第四纪盐湖上升卤水流体及其成钾意义[J].矿床地质,2003,22(4):386-392. Liu Chenglin,Jiao Pengcheng,Wang Mili,et al.Upward Brine Fluid and Its Potassium Forming Significance in Quaternary Salt Lake of Luobupo,Xinjiang[J].Mineral Deposits,2003,22(4):386-392.
[15] 沈立建,刘成林,王立成.云南兰坪盆地云龙组上段稀土、微量元素地球化学特征及其环境意义[J].地质学报,2015,89(11):2036-2045. Shen Lijian,Liu Chenglin,Wang Licheng.Geochemical Characteristics and Environmental Significance of Rare Earth and Trace Elements in the Upper Segment of Yunlong Group in Lanping Basin,Yunnan Province[J].Acta Geologica Sinica,2015,89(11):2036-2045.
[16] 朱志军,郭福生,刘腾,等.云南兰坪盆地古近系细碎屑岩地球化学特征及其地质意义[J].吉林大学学报(地球科学版),2015,45(6):1631-1641. Zhu Zhijun,Guo Fusheng,Liu Teng,et al.Geochemical Characteristics and Geological Significance of Paleogene Fine Clastic Rocks in Lanping Basin,Yunnan Province[J].Journal of Jilin University (Earth Science Edition),2015,45(6):1631-1641.
[17] Elderfied I I,Pagett R.Rare Earth Elements in Ichthyoliths:Variations with Redox Condition and Bepositional Environment[J].Science of the Total Environment,1986,49:175-197.
[18] 李军,桑树勋,林会喜,等.渤海湾盆地石炭二叠系稀土元素特征及其地质意义[J].沉积学报,2007,25(4):589-596. Li Jun,Sang Shuxun,Lin Huixi,et al.Characteristics and Geological Significance of Rare Earth Elements in Carboniferous Permian in Bohai Bay Basin[J].Acta Sedimentologica Sinica,2007,25(4):589-596.
[19] 刘俊海,杨香华,于水,等.东海盆地丽水凹陷古新统沉积岩的稀土元素地球化学特征[J].现代地质,2003,17(4):421-427. Liu Junhai,Yang Xianghua,Yu Shui,et al.Geochemical Characteristics of Rare Earth Elements in Paleocene Sedimentary Rocks in Lishui Sag,Donghai Basin[J].Modern Geology,2003,17(4):421-427.
[20] Tribovillard N,Algeo T J,Lyons T,et al.Trace Metals as Paleoredox and Paleoproductivity Proxies[J].Chemical Geology,2006,232(1/2):12-32.
[21] Zhang T G,Wieslaw T,Jiang S Y,et al. Major Oceanic Redox Condition Change Correlated with the Rebound of Marine Animal Diversity During the Late Ordovician[J]. Geology,2011,39(7):675-678.
[22] 王益友,吴萍.江浙海岸带沉积物的地球化学标志[J].1983(4):82-90. Wang Yiyou,Wu Ping.Geochemical Markers of Sediments in the Coastal Zone of Jiangsu and Zhejiang[J]. Journal of Tongji University,1983(4):82-90.
[23] 刘刚,周东升.微量元素分析在判别沉积环境中的应用:以江汉盆地潜江组为例[J].石油实验地质,2007,29(3):307-310,314. Liu Gang,Zhou Dongsheng.Application of Trace Element Analysis in Discriminating Sedimentary Environment:Taking Qianjiang Group in Jianghan Basin as an Example[J].Petroleum Geology Experiment,2007,29(3):307-310,314.
[24] 王淑芳,董大忠,王玉满,等.四川盆地南部志留系龙马溪组富有机质页岩沉积环境的元素地球化学判别指标[J].海相油气地质,2014,19(3):27-34. Wang Shufang,Dong Dazhong,Wang Yuman,et al.Elemental Geochemical Discriminating Index of Organic Matter Shale Sedimentary Environment in the Southern Silurian Group of Sichuan Basin[J].Marine Origin Petroleum Geology,2014,19(3):27-34.
[25] Wignall P B.Black Shales[M].Oxford:Clarendon Press,1994:46.
[26] 王敏芳,焦养泉,王正海,等.沉积环境中古盐度的恢复:以吐哈盆地西南缘水西沟群泥岩为例[J].新疆石油地质,2005,26(6):117-120. Wang Minfang,Jiao Yangquan,Wang Zhenghai,et al.Restoration of Medieval Salinity in Sedimentary Environment:A Case Study of Water Xigou Group Mudstone in the Southwest Margin of Tuha Basin[J].Xinjiang Petroleum Geology,2005,26(6):117-120.
[27] 许璟,蒲仁海,杨林,等.塔里木盆地石炭系泥岩沉积时的古盐度分析[J].沉积学报,2010,28(3):509-517. Xu Jing,Pu Renhai,Yang Lin,et al.Analysis of Ancient Salinity During the Deposition of Carboniferous Mudstone in Tarim Basin[J].Acta Sedimentologica Sinica,2010,28(3):509-517.
[28] 钱利军,陈洪德,林良彪,等.四川盆地西缘地区中侏罗统沙溪庙组地球化学特征及其环境意义[J].沉积学报,2012,30(6):1061-1071. Qian Lijun,Chen Hongde,Lin Liangbiao,et al.Geochemical Characteristics and Environmental Significance of Shaxi Temple Group in the Middle Jurassic area of Sichuan Basin West Margin[J].Acta Sedimentologica Sinica,2012,30(6):1061-1071.
[29] 王峰.云南白秧坪银多金属矿床形成的地球化学机制[D].成都:成都理工大学,2004. Wang Feng.Geochemical Mechanism of Milver Polymetallic Deposit Formation in Baiyangping,Yunnan[D].Chengdu:Chengdu University of Technology,2004.
[30] 文华国,郑荣才,唐飞,等.鄂尔多斯盆地耿湾地区长6段古盐度恢复与古环境分析[J].矿物岩石,2008,28(1):114-120. Wen Huaguo,Zheng Rongcai,Tang Fei,et al. Analysis of the Restoration and Paleoclimate of the Ancient Salinity in 6 Sections of the Geng Wan Area of Ordos Basin[J]. Journal of Mineralogy and Petrology,2008,28(1):114-120.
[31] 郑荣才,柳梅青.鄂尔多斯盆地长6油层组古盐度研究[J].石油与天然气地质,1999,20(1):22-27. Zheng Rongcai,Liu Meiqing.Study on the Ancient Salinity of the Long 6 Reservoir Group in Ordos Basin[J]. Oil & Gas Geology,1999,20(1):22-27.
[32] 何志威,杨瑞东,高军波,等.贵州松桃道坨锰矿含锰岩系地球化学特征和沉积环境分析[J].地质论评,2014,60(5):1061-1075. He Zhiwei,Yang Ruidong,Gao Junbo,et al.Analysis of Geochemical Characteristics and Sedimentary Environment of Manganese-Bearing Rock Series in the Manganese Ore of Songtao Road,Guizhou[J].Geological Review,2014,60(5):1061-1075.
[33] 谢建成,杜建国,许卫,等.安徽贵池地区含锰岩系地质地球化学特征[J].地质论评,2006,52(3):396-408. Xie Jiancheng,Du Jianguo,Xu Wei,et al.Geological and Geochemical Characteristics of Manganese-Bearing Rocks in Guichi Area of Anhui Province[J].Geological Review,2006,53(3):396-408.
[34] Joachimski M M,Ostertag-Henning C,Pancost R D,et al.Water Column Anoxia,Enhanced Productivity and Concomitant Changes in δ¹³C and δ³⁴S Across the Frasnian-Famennian Boundary (Kowala Holy Cross Mountains,Poland)[J].Chemical Geology,2001,175(1/2):10109-10131.
[35] Johnson T M,DePaolo D J.Interpretation of Isotopic Data in Groundwater-Rock Systems:Model Development and Application to Sr Isotope Data from Yucca Mountain[J]. Water Resources Research,1994,30(5):1571-1587.
[36] 徐磊,操应长,王艳忠,等.东营凹陷古近系膏盐岩成因模式及其与油气藏的关系[J].中国石油大学学报(自然科学版),2008,32(3):30-35. Xu Lei,Cao Yingchang,Wang Yanzhong,et al.The Genesis Model of Paleogene Ointment Salt Rock in Dongying Sag and Its Relationship with Oil and Gas Reservoirs[J].Journal of China University of Petroleum (Edition of Natural Science),2008,32(3):30-35.
[37] 朱志军,郭福生,邱安庆.江西信江盆地罗塘凹陷膏盐微量元素地球化学特征[J].高校地质学报,2016,22(4):598-607. Zhu Zhijun,Guo Fusheng,Qiu Anqing.Trace Element Geochemical Characteristics of Gypsumand Its Geologic Significance from the Luotang Depression in Xinjiang Basin,Jiangxi[J]. Geological Journal of China Universities,2016,22(4):598-607.
[38] 沈立建,刘成林,王立成.云南兰坪盆地古近系云龙组上段沉积环境研究:来自碳、氧同位素的证据[J].地球学报,2016,37(3):301-306. Shen Lijian,Liu Chenglin,Wang Licheng.Study on Sedimentary Environment in the Upper Segment of the Paleogene Yunlong Group in Lanping Basin,Yunnan Province-Evidence from Carbon and Oxygen Isotopes[J].Acta Geoscientica Sinica,2016,37(3):301-306.

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滇西兰坪盆地中-新生代蒸发岩元素地球化学特征及其形成环境

Geochemical Characteristics and Formation Environment of Mesozoic and Cenozoic Evaporative Rocks in Lanping Basin, Western Yunnan

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