吉林大学学报(地球科学版) ›› 2020, Vol. 50 ›› Issue (2): 326-340.doi: 10.13278/j.cnki.jjuese.20190312
王嗣敏1,2, 臧东升1,2, 王熙琼3, 李杰1,2, 韩嵩1,2, 李建中1,2
Wang Simin1,2, Zang Dongsheng1,2, Wang Xiqiong3, Li Jie1,2, Han Song1,2, Li Jianzhong1,2
摘要: 辽西地区建昌盆地含有丰富的油页岩资源。利用野外露头、钻井和化验分析等资料,分析油页岩分布、岩石学特征、地球化学特征和沉积环境。研究表明:油页岩发育于下白垩统九佛堂组一段、二段和三段,共计9个矿组,九佛堂组三段油页岩平均含油率高、厚度大;建昌盆地油页岩平均含油率为5.15%,平均灰分质量分数可达81.9%,平均发热量为5.19 kJ/g,全硫质量分数低,属于中品位高灰分中高发热量低硫型油页岩,开发时对环境污染小;碱厂、五家子、九佛堂、七道泉子和敖汉旗大青山含矿区累计油页岩查明技术可采资源8.22×108 t,油页岩油查明可回收资源3.17×107 t,建昌盆地预测油页岩资源9.27×1010 t。有机地化特征显示,建昌盆地油页岩有机质丰度较高,有机质类型主要为Ⅰ型和Ⅱ1型,成熟度较低,处于未成熟—低成熟阶段。九佛堂组时期气候温暖湿润,来源于陆地和湖泊的有机质大量沉积于淡水—咸水的湖泊中,水底为还原环境,有利于有机质的保存。
中图分类号:
[1] 刘招君, 杨虎林, 董清水, 等. 中国油页岩[M]. 北京:石油工业出版社, 2009. Liu Zhaojun, Yang Hulin, Dong Qingshui, et al. Oil Shale in China[M]. Beijing:Petroleum Industry Press, 2009. [2] Dyni J R. Geology and Resources of Some World Oil-Shale Deposits[R]. Reston:US Geological Survey, 2006:8-38. [3] Li Z X, Liu X J, Li Y, et al. Mechanisms of Accumulation and Coexistence of Coal and Oil Shale in Typical Basins[J]. Energy Exploration & Exploitation, 2016,34(3):360-377. [4] 刘招君, 孟庆涛, 柳蓉. 中国陆相油页岩特征及成因类型[J]. 古地理学报, 2009, 11(1):105-114. Liu Zhaojun, Meng Qingtao, Liu Rong. Characteristics and Genetic Types of Continental Oil Shales in China[J]. Journal of Palaeogeography, 2009, 11(1):105-114. [5] 刘招君, 孙平昌, 柳蓉, 等. 中国陆相盆地油页岩成因类型及矿床特征[J]. 古地理学报, 2016, 18(4):525-534. Liu Zhaojun, Sun Pingchang, Liu Rong, et al. Genetic Types and Deposit Features of Oil Shales in Continental Basin in China[J]. Journal of Palaeogeography, 2016, 18(4):525-534. [6] 王超, 陆永潮, 杜学斌,等. 油页岩岩性非均质性特征及地球物理精细刻画:以苏北盆地溱潼凹陷阜宁组二段为例[J]. 石油与天然气地质, 2015, 36(5):814-821. Wang Chao, Lu Yongchao, Du Xuebin, et al.Characteristics and Geophysical Prediction of Lithology Heterogeneity of Oil Shale:Taking the 2nd Member of Funing Formation of Qintong Sag,Subei Basin,as an Example[J]. Oil & Gas Geology, 2015, 36(5):814-821. [7] 孙耀庭, 徐守余, 张世奇,等. 山东昌乐凹陷油页岩地球化学特征及成因探讨[J]. 吉林大学学报(地球科学版), 2015, 45(3):736-742. Sun Yaoting, Xu Shouyu, Zhang Shiqi, et al. Geochemical Characteristics and Genesis of the Oil Shale in Changle Sag, Shandong Province[J]. Journal of Jilin University (Earth Science Edition), 2015, 45(3):736-742. [8] 郑玉龙, 马志强, 王佰长,等. 黑龙江省柳树河盆地始新统八虎力组油页岩元素地球化学特征及沉积环境[J]. 古地理学报, 2015, 17(5):689-698. Zheng Yulong, Ma Zhiqiang, Wang Baichang, et al. Geochemistry Characteristics and Sedimentary Environment of Oil Shale from the Eocene Bahuli Formation in Liushuhe Basin,Heilongjiang Province[J]. Journal of Palaeogeography, 2015, 17(5):689-698. [9] 宋青磊, 刘招君, 胡菲,等. 松辽盆地扶余-长春岭地区上白垩统青山口组油页岩品质特征及意义[J]. 世界地质, 2016, 35(2):487-494. Song Qinglei, Liu Zhaojun, Hu Fei, et al.Oil Shale Characteristics of Upper Cretaceous Qingshankou Formation in Fuyu-Changchunling Area of Songliao Basin and Its Significance[J]. Global Geology, 2016, 35(2):487-494. [10] 曹新星, 宋之光, 李艳,等. 茂名油页岩沉积有机质特征及古气候意义[J]. 地学前缘, 2016, 23(3):243-252. Cao Xinxing, Song Zhiguang, Li Yan, et al. The Characteristics of Organic Matter in Maoming Oil Shales and Their Paleoclimate Significance[J]. Earth Science Frontiers, 2016, 23(3):243-252. [11] 刘招君, 王永莉, 何大祥,等. 抚顺盆地始新统计军屯组油页岩地球化学特征及其地质意义[J]. 天然气地球科学, 2009, 24(6):1196-1204. Liu Zhaojun, Wang Yongli, He Daxiang, et al. Shale Gas Potential and Organic Geochemical Characteristics of Oil Shale in the Southeast of Jungger Basin[J]. Natural Gas Geoscience, 2013, 24(6):1196-1204. [12] 刘招君, 孟庆涛, 贾建亮,等. 陆相盆地油页岩成矿规律:以东北地区中、新生代典型盆地为例[J]. 吉林大学学报(地球科学版), 2012, 42(5):1286-1297. Liu Zhaojun, Meng Qingtao, Jia Jianliang, et al. Metallogenic Regularity of Oil Shale in Continental Basin:Case Study in the Meso-Cenozoic Basins of Northeast China[J]. Journal of Jilin University (Earth Science Edition), 2012, 42(5):1286-1297. [13] 刘招君, 孙平昌, 柳蓉,等. 敦密断裂带盆地群油页岩特征及成矿差异分析[J]. 吉林大学学报(地球科学版), 2016, 46(4):1090-1099. Liu Zhaojun, Sun Pingchang, Liu Rong, et al. Research on Oil Shale Features and Metallogenic Differences in Dunhua-Mishan Fault Zone[J]. Journal of Jilin University (Earth Science Edition), 2016, 46(4):1090-1099. [14] 高苑, 王永莉, 何大祥,等. 准噶尔盆地东南缘油页岩有机地球化学特征及含气潜力[J]. 天然气地球科学, 2013, 24(6):1196-1204. Gao Yuan, Wang Yongli, He Daxiang, et al. Shale Gas Potential and Organic Geochemical Characteristics of Oil Shale in the Southeast of Jungger Basin[J]. Natural Gas Geoscience, 2013, 24(6):1196-1204. [15] 温志良, 姜福平, 钟长林,等. 松辽盆地东南隆起超大型油页岩矿床特征及成因[J]. 吉林大学学报(地球科学版), 2016, 46(3):681-691. Wen Zhiliang, Jiang Fuping, Zhong Changlin, et al. Features and Origin of Super-Large Oil Shale Deposit in Southeast Uplift of the Songliao Basin[J]. Journal of Jilin University (Earth Science Edition), 2016, 46(3):681-691. [16] 李忠雄, 何江林, 谢尚克. 藏北羌塘上侏罗统-下白垩统胜利河油页岩单体烃碳同位素研究[J]. 地质学报, 2017, 91(2):453-464. Li Zhongxiong, He Jianglin, Xie Shangke, et al. The Key Parameters of Oil Shale Resource Appraisement and Its Evaluating Methods[J]. Acta Geologica Sinica, 2017, 91(2):453-464. [17] Goodarzi F, Haeri-Ardakani O, Gentzis T, et al.Organic Petrology and Geochemistry of Tournaisian-Age Albert Formation Oil Shales, New Brunswick, Canada[J]. International Journal of Coal Geology, 2016, 205:43-57. [18] Song Y, Liu Z J, Meng Q T, et al. Multiple Controlling Factors of the Enrichment of Organic Matter in the Upper Cretaceous Oil Shale Sequences of the Songliao Basin, NE China:Implications from Geochemical Analyses[J]. Oil Shale, 2016, 33(2):142-166. [19] Sun T, Wang C S, Li Y L, et al. Geochemical Investigation of Lacustrine Oil Shale in the Lunpola Basin (Tibet):Implications for Paleoenvironment and Paleoclimate[J]. Oil Shale, 2013, 30(2):101-116. [20] Bradely W H,Eugster H P. Geochemistry and Palimnology of the Trona Deposits and Associated Auhigenic Minerals of the Green River Formation of Wyoming[R]. Reston:US Geological Survey Professional Paper, 1969:496-517. [21] Demaison G J, Moore G T. Anoxic Environments and Oil Source Bed Genesis[J]. AAPG Bulletin, 1980, 64:1179-1209. [22] Li L, Liu Z J,Georgec S C, et al. Lake Evolution and Its Influence on the Formation of Oil Shales in the Middle Jurassic Shimengou Formation in the Tuanyushan area, Qaidam Basin, NW China[J]. Geochemistry, 2019:162-177 [23] Zhang M M, Li Z, Yin J. Sedimentary and Geochemical Characteristics of Oil Shale in the Permian Lucaogou Formation in the Southeastern Junggar Basin, Northwest China:Implications for Sedimentary Environments[J]. Oil Shale, 2018, 35(2):97-112. [24] Peter H, Martina D,Arkadi C, et al. Geochemical and Organic Petrological Characterization of the Organic Matter of Lacustrine Eocene Oil Shales (Prinz Von Hessen, Germany):Reconstruction of the Depositional Environment[J]. Journal of Paleolimnology, 2005,33:155-168. [25] Chen Y H, Zhu Z W, Zhang L. Control Actions of Sedimentary Environments and Sedimentation Rates on Lacustrine Oil Shale Distribution, an Example of the Oil Shale in the Upper Triassic Yanchang Formation, Southeastern Ordos Basin (NW China)[J]. Marine and Petroleum Geology, 2019, 102:508-520. [26] 刘招君, 柳蓉. 中国油页岩特征及开发利用前景分析[J]. 地学前缘, 2005, 12(3):315-323. Liu Zhaojun, Liu Rong. Oil Shale Resource State and Evaluating System[J]. Earth Science Frontiers, 2005, 12(3):315-323. [27] 刘招君, 董清水, 叶松青,等. 中国油页岩资源现状[J]. 吉林大学学报(地球科学版),2006, 36(6):869-876. Liu Zhaojun, Dong Qingshui, Ye Songqing, et al. The Situation of Oil Shale Resources in China[J]. Journal of Jilin University (Earth Science Edition), 2006, 36(6):869-876. [28] 董清水, 王立贤, 于文斌,等. 油页岩资源评价关键参数及其求取方法[J]. 吉林大学学报(地球科学版), 2006, 36(6):899-903. Dong Qingshui, Wang Lixian, Yu Wenbin, et al. The Key Parameters of Oil Shale Resource Appraisement and Its Evaluating Methods[J]. Journal of Jilin University (Earth Science Edition), 2006, 36(6):899-903. [29] 张海龙, 刘招君, 张健,等. 油页岩技术可采系数研究与应用[J]. 吉林大学学报(地球科学版), 2006, 36(6):904-908. Zhang Hailong, Liu Zhaojun, Zhang Jian, et al. The Research and Application of the Oil Shale Technology Mining Coefficient[J]. Journal of Jilin University (Earth Science Edition), 2006, 36(6):904-908. [30] 李玉宏, 姜亭, 武富礼,等. 鄂尔多斯盆地东南部油页岩资源评价[J]. 地质通报, 2014(9):1417-1424. Li Yuhong, Jiang Ting, Wu Fuli, et al. Evaluation Methods and Results of Oil Shale Resources in South-Eastern Ordos Basin[J]. Geological Bulletin of China, 2014, 33(9):1417-1424. [31] 付秋萍. 建昌-喀左盆地石油地质条件初步分析[J]. 辽宁工程技术大学学报, 2005, 24(3):351-353. Fu Qiuping. Preliminary Analysis of Petroleum Geological Condition of Jianchang-Kazuo Basin[J]. Journal of Liaoning Technical University, 2005, 24(3):351-353. [32] 孙宇, 鲍强. 辽西地区盆地中生代构造演化[J]. 露天采矿技术, 2011(1):20-22. Sun Yu, Bao Qiang. The Mesozoic Tectonic Evolution of Basins in Western Liaoning Province[J]. Opencast Mining Technology, 2011(1):20-22. [33] 陈刚, 张晓明, 杨桂芳,等. 辽西地区下白垩统九佛堂组沉积与有机质发育特征[J]. 地质通报, 2019, 38(2/3):426-436. Chen Gang, Zhang Xiaoming, Yang Guifang, et al.Sedimentary and Organic Matter Characteristics of Lower Cretaceous Jiufotang Formation in Western Liaoning Province[J]. Geological Bulletin of China, 2019, 38(2/3):426-436. [34] 王宇林, 郭强, 肖乾华,等. 喀左盆地下白垩统九佛堂组油页岩特征及控矿条件[J]. 吉林大学学报(地球科学版), 2009, 39(2):211-216. Wang Yulin, Guo Qiang, Xiao Qianhua, et al. Characteristics and Ore-Controlling Condition of Oil Shale of Jiufotang Formation of Lower Cretaceous in Kazuo Basin[J]. Journal of Jilin University (Earth Science Edition), 2009, 39(2):211-216. [35] 景山, 王成善, 柳永青,等. 辽西建昌盆地早白垩世义县组沉积环境分析及盆地演化初探[J]. 沉积学报, 2009, 27(4):583-591. Jing Shan, Wang Chengshan, Liu Yongqing, et al. Depositional Environment and Basin Evolution of the Early Cretaceous Yixian Formation in Jianchang Basin, Western Liaoning[J]. Acta Sedimentologica Sinica, 2009, 27(4):583-591. [36] 戴军. 辽西朝阳大平房-四官营子盆地油页岩资源预测[J]. 地质与资源, 2011, 20(3):183-187. Dai Jun. Prediction for the Oil Shale Resources in Dapingfang-Siguanyingzi Basin, Western Liaoning Province[J]. Geology and Resources, 2011, 20(3):183-187. [37] 杨庚, 郭华. 辽西地区构造系统的形成与东北亚区域构造演化[J]. 铀矿地质, 2002, 18(4):193-201. Yang Geng, Guo Hua. Formation of Structural Systems in Western Liaoning and Regional Tectonic Evolution of Northeastern Asia[J]. Uranium Geology, 2002, 18(4):193-201. [38] 张亚明, 高玉娟, 何保. 建昌-喀左盆地中生代构造演化[J]. 辽宁工程技术大学学报, 2005, 24(6):829-831. Zhang Yaming, Gao Yujuan, He Bao. Tectonic Evolution in Jianchang-Kazuo Basin in Mesozoic Era[J]. Journal of Liaoning Technical University, 2005, 24(6):829-831. [39] 王宇林, 郭强, 李喜海,等. 辽西喀左盆地九佛堂组的划分及相关问题[J]. 地层学杂志, 2009, 33(2):147-154. Wang Yulin, Guo Qiang, Li Xihai, et al. Subdivision of the Jiufotang Formation and Related Issues in the Kazuo Basin[J]. Journal of Stratigraphy, 2009, 33(2):147-154. [40] 魏恒飞, 王宇林, 王威,等. 喀左盆地九佛堂组沉积特征及演化研究[J]. 沉积学报, 2009, 27(2):273-279. Wei Hengfei, Wang Yulin, Wang Wei, et al.Sedimentary Characteristics and Evolution of Jiufotang Formation in Kazuo Basin[J]. Acta Sedimentologica Sinica, 2009, 27(2):273-279. [41] 沉积岩中总有机碳的测定:GB/T18602-2003[S]. 北京:中国标准出版社, 2003. Determination of Total Organic Carbon in Sedimentary Rock:GB/T18602-2003[S]. Beijing:Standards Press of China, 2003. [42] 岩石热解分析:GB/T19145-2001[S]. 北京:中国标准出版社, 2001. Rock Pyrolysis Analysis:GB/T19145-2001[S]. Beijing:Standards Press of China, 2001. [43] 气相色谱-质谱法测定沉积物和原油中生物标志物:GB/T18606-2001[S]. 北京:中国标准出版社, 2001. The Test Method for Biomarkers in Sediment and Crude Oil by GC-MS:GB/T19145-2001[S]. Beijing:Standards Press of China,2001. [44] 杨春. 建昌-喀左盆地烃源岩系沉积环境与烃源岩地球化学特征[D]. 阜新:辽宁工程技术大学, 2005. Yang Chun. The Depositional Environment of Source Rock Measures and Geochemistry Characteristics of Source Rocks in Jianchang-Kazuo Basin[D]. Fuxin:Liaoning Technical University, 2005. [45] 刘招君, 孟庆涛, 贾建亮. 油页岩成矿作用研究中的关键方法和技术[J]. 古地理学报, 2019, 21(1):127-142. Liu Zhaojun, Meng Qingtao, Jia Jianliang. Key Methods and Technologies in the Study of Oil Shale Mineralization[J]. Journal of Palaeogeography, 2019, 21(1):127-142. [46] 许世红, 吴光华, 黄开权, 等. 安参1井侏罗系和石炭-二叠系暗色泥岩地球化学特征及意义[J]. 石油实验地质, 2002, 24(3):284-286. Xu Shihong, Wu Guanghua, Huang Kaiquan, et al. Geochemical Characteristics and Significance of the Jurassic and Carboniferouspermian Melamudstone in Well Ancan-1[J]. Petroleum Geology & Experiment, 2002, 24(3):284-286. [47] Peters K E,Walters C C,Moldowan J M. The Biomarker Guide:Biomarkers and Isotopes in the Environment and Human History[M]. Cambridge:Cambridge University Press, 2005. [48] Volkman J K, Barrett S M, Blackburn S I, et al. Microalgal Biomarkers:A Review of Recent Research Developments[J]. Organic Geochemistry, 1998, 29(5/6/7):1163-1179. [49] 段冶, 张立君, 李莉, 等. 辽西大平房-梅勒营子盆地九佛堂组珍稀化石层的划分与对比[J].世界地质, 2006, 25(2):113-119. Duan Ye, Zhang Lijun, Li Li, et al. Division and Correlation of Unique Fossil-Bearing Beds of Jiufotang Formation in Dapingfang-Meileyingzi Basin of Western Liaoning[J]. Global Geology, 2006, 25(2):113-119. [50] 巩恩普, 梁俊红, 李小冬, 等. 辽西早白垩世早期热河生物群沉积环境及古地理综合研究[J].地质学报, 2007, 81(1):1-10. Gong Enpu, Liang Junhong, Li Xiaodong, et al. Comprehensive Research on the Sedimentary Environment and Palaeogeography of Early Cretaceous Jehol Bita in Western Liaoning, China[J]. Acta Geologica Sinica, 2007, 81(1):1-10. [51] 胡晓峰, 刘招君, 柳蓉, 等. 桦甸盆地始新统桦甸组黏土矿物和无机地球化学特征及其古环境意义[J]. 煤炭学报, 2012, 37(3):416-423. Hu Xiaofeng, Liu Zhaojun, Liu Rong, et al. Clay Mineral and Inorganic Geochemical Characteristics of Eocene Huadian Formation in Huadian Basin and Their Paleoenvironment Implications[J]. Journal of China Coal Society, 2012, 37(3):416-423. |
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