吉林大学学报(地球科学版) ›› 2021, Vol. 51 ›› Issue (3): 680-693.doi: 10.13278/j.cnki.jjuese.20200091

• 地质与资源 • 上一篇    下一篇

银额盆地石板泉西石炭系白山组碳酸盐岩地球化学特征及其环境意义

史冀忠, 牛亚卓, 许伟, 宋博, 王宝文   

  1. 中国地质调查局西安地质调查中心, 西安 710054
  • 收稿日期:2020-04-16 出版日期:2021-05-26 发布日期:2021-06-07
  • 作者简介:史冀忠(1983—),男,高级工程师,主要从事油气基础地质调查研究,E-mail:shijizhong0241@sina.com
  • 基金资助:
    中国地质调查局项目(DD20190092)

Geochemical Characteristics and Sedimentary Environment of Carboniferous Baishan Formation Carbonate in Shibanquanxi of Yingen-Ejin Banner Basin

Shi Jizhong, Niu Yazhuo, Xu Wei, Song Bo, Wang Baowen   

  1. Xi'an Center, China Geological Survey, Xi'an 710054, China
  • Received:2020-04-16 Online:2021-05-26 Published:2021-06-07
  • Supported by:
    Supported by the Project of China Geological Survey (DD20190092)

摘要: 对银额盆地石板泉西石炭系白山组碳酸盐岩进行详细的地球化学分析,探讨各特征元素对古环境、古气候的指示意义。地球化学测试结果显示:除样品CH3外,其余样品主量元素中的Al及微量元素中的Ti、Zr、Th等典型陆源特征元素的含量较低,Y/Ho平均值为45.58,反映研究区白山组碳酸盐岩较少受陆源物质输入的影响;δCe与δEu、w(ΣREE)、(La/Sm)N未见良好的相关性,也不具备Eu正异常,说明研究区白山组碳酸盐岩受成岩作用和热液作用的影响也较为有限。碳酸盐岩中所含微量元素主要为海水自生成因,能够反映原始沉积环境。根据特征元素对古水深、古盐度、古气候、古氧相和古水温进行研究,显示研究区白山组碳酸盐岩段虽然岩性较为单一,但其地球化学特征可以反映早晚的沉积古环境差异。研究区白山组碳酸盐岩总体经历了1个大的海侵海退旋回,沉积于正常海水,气候潮湿,弱氧化—弱还原环境,古水温为8.51~27.10℃,早期水温低,晚期水温升高。

关键词: 银额盆地, 白山组, 碳酸盐岩, 地球化学, 古环境

Abstract: In this study,the major elements,trace elements, and rare earth elements of carbonate rocks from the Carboniferous Baishan Formation were analyzed, and the paleo-environment and paleo-climate of the Shibanquanxi of Yingen-Ejin Banner basin were discussed. The results of geochemical tests showed that the rock has low contents of typical continental elements,such as Al、Ti、Zr and Th,except for sample CH3; Combine with the ratio of Y/Ho(45.58), terrestrial input in the study area is limited. Additionally,there is no strong correlation between δCe and δEu, w(ΣREE), and (La/Sm)N, and there is no positive Eu anomaly, indicating that the diagenesis and hydrothermal process had little impact on the sediments. The trace elements contained in the carbonate rocks are mainly self-generated by seawater, which can reflect the original sedimentary environment. The study of paleo-water depth,paleo-saltitude,paleo-climate,paleo-oxygen phase, and paleo-water temperature show that although the lithology of the carbonate section of the Baishan Formation is relatively simple,its geochemical characteristics can reflect the difference of sedimentary environment. The carbonate rocks of the Baishan Formation went through a huge transgression and regression cycle,and deposited in normal seawaterwith humid climate and weak oxidation-weak reduction environment. The paleo-water temperature was 8.51-27.10 ℃. The water temperature was low in the early stage,and increased in the late stage.

Key words: Yingen-Ejin Banner basin, Baishan Formation, carbonate rocks, geochemistry, paleo-environment

中图分类号: 

  • P54
[1] Guy C,Daux V,Schott J. Behaviour of Rare Earth Elements During Seawater/Basalt Interactions in the Muruoa Massi[J]. Chemical Geology,1999,158:21-35.
[2] Haley B A, Kinkhammer G P, McMauns J. Rare Earth Elements in Pore Waters of Marine Sediments[J]. Geochimica et Cosmochimica Acta,2004,68(6):1265-1279.
[3] 胡俊杰,李琦,李娟,等.羌塘盆地角木日地区二叠系碳酸盐岩元素地球化学特征及其对古沉积环境的指示[J].高校地质学报,2014,20(4):520-527. Hu Junjie,Li Qi,Li Juan,et al. Geochemical Characteristics and Its Application to Depositional Environment Analysis of Permian Carbonates in Jiaomuri Area,Qiangtang Basin[J]. Geological Journal of China Universities,2014,20(4):520-527.
[4] 赵晓辰,刘池洋,赵岩,等.鄂尔多斯西南缘水泉岭组碳酸盐岩地球化学特征[J].西北大学学报(自然科学版),2017,47(1):101-109. Zhao Xiaochen,Liu Chiyang,Zhao Yan,et al. Geochemical Characteristics of the Shuiquanling Formation Carbonates in the Southwestern Margin of Ordos Basin[J].Journal of Northwest University(Natural Science Edition),2017,47(1):101-109.
[5] 何雨旸,赵广涛,赵利,等.巢北地区二叠系栖霞组碳酸盐岩地球化学特征及其古环境意义[J].中国海洋大学学报,2014,44(5):79-88. He Yuyang,Zhao Guangtao,Zhao Li,et al. Geochemistry Characteristics and Paleo-Environment Significance of Qixia Formation in Chaobei Area[J].Periodical of Ocean University of China,2014,44(5):79-88.
[6] 杨振宇,沈渭洲,郑连弟.广西来宾蓬莱滩二叠纪瓜德鲁普统—乐平统界线剖面元素和同位素地球化学研究及地质意义[J].地质学报,2009,83(1):1-15. Yang Zhenyu,Shen Weizhou,Zheng Liandi. Elements and Isotopic Geochemistry of Guadalupian-Lopingian Boundary Profile at the Penglaitan Section of Laibin,Guangxi Province,and Its Geological Implications[J]. Acta Geologica Sinica,2009,83(1):1-15.
[7] 卢进才,牛亚卓,魏仙样,等.北山红石山地区晚古生代火山岩LA-ICP-MS锆石U-Pb年龄及其构造意义[J].岩石学报,2013,29(8):2685-2694. Lu Jincai,Niu Yazhuo,Wei Xianyang,et al. LA-ICP-MS Zircon U-Pb Dating of the Late Paleozoic Volcanic Rocks from the Hongshishan Area of the Beishan Orogenic Belt and Its Tectonic Significances[J].Acta Petrologica Sinica,2013,29(8):2685-2694.
[8] 牛亚卓,魏建设,史冀忠,等.甘肃北山地区北部上石炭统火山岩LA-ICP-MS锆石U-Pb年龄及其构造意义[J].地质通报,2013,32(11):1720-1727. Niu Yazhuo,Wei Jianshe,Shi Jizhong,et al. LA-ICP-MS Zircon U-Pb Dating of the Upper Carboniferous Volcanic Rocks from Northern Beishan Region in Gansu Province and Its Tectonic Significance[J].Geological Bulletin of China,2013,32(11):1720-1727.
[9] 卢进才,牛亚卓,姜亭.中国北方石炭系—二叠系油气地质调查与勘探进展[J].地质通报,2018,37(1):7-15. Lu Jincai,Niu Yazhuo,Jiang Ting. Progress in Geological Survey and Petroleum Exploration of Carboniferous-Permian Strata in Northern China[J].Geological Bulletin of China,2018,37(1):7-15.
[10] 卢进才,史冀忠,牛亚卓,等.内蒙古西部北山—银额地区石炭纪—二叠纪层序地层与沉积演化[J].岩石学报,2018,34(10):3101-3115. Lu Jincai,Shi Jizhong,Niu Yazhuo,et al. The Carboniferous-Permian Sequence Stratigraphy and Sedimentary Evolution of Beishan-Yin’e Region,Western Inner Mongolia[J]. Acta Petrologica Sinica,2018,34(10):3101-3115.
[11] 史冀忠,陈高潮,姜亭,等.银额盆地及邻区石炭纪小独山期—二叠纪紫松期岩相古地理[J].地质通报,2018,37(1):107-119. Shi Jizhong,Chen Gaochao,Jiang Ting,et al. Lithofacies Palaeogeography of Carboniferous Xiaodushanian-Permian Zisongian Stage in Yingen-Ejin Basin and Its Adjacent Areas[J].Geological Bulletin of China,2018,37(1):107-119.
[12] 史冀忠,卢进才,魏建设,等.内蒙古阿拉善右旗雅干地区二叠系埋汗哈达组硅质岩成因及其沉积环境[J].吉林大学学报(地球科学版),2018,48(6):1711-1724. Shi Jizhong,Lu Jincai,Wei Jianshe,et al. Petrogenesis and Sedimentary Environment of Permian Maihanhada Formation Cherts in Yagan Region of Alxa Right Banner,Inner Mongolia[J]. Journal of Jilin University(Earth Science Edition),2018,48(6):1711-1724.
[13] 任纪舜,王作勋,陈炳蔚,等.从全球看中国大地构造:中国及邻区大地构造图简要说明[M].北京:地质出版社,1999. Ren Jishun,Wang Zuosxun,Chen Bingwei,et al. Look at China Tectonic from the Global:A Brief Instruction to the Tectonic Map of China and Adjacent Regions[M]. Beijing:Geological Publishing House,1999.
[14] 夏林圻,夏祖春,徐学义,等.天山及邻区石炭纪—早二叠世裂谷火山岩岩石成因[J].西北地质,2008,41(4):1-68. Xia Linqi,Xia Zuchun,Xu Xueyi,et al. Petrogenesis of Caboniferous-Early Permian Rift-Related Volcanic Rocks in the Tianshan and Its Neighboring Areas,Northwestern China[J]. Northwestern Geology,2008,41(4):1-68.
[15] 卢进才,魏仙样,李玉宏,等.额济纳旗地区土壤油气地球化学特征及其意义[J].新疆石油地质,2009,30(1):6-8. Lu Jincai,Wei Xianyang,Li Yuhong,et al. Characteristics and Significance of Soil Oil-Gas Geochemistry in Ejina Qi Region[J].Xinjiang Petroleum Geology,2009,30(1):6-8.
[16] 卢进才,陈高潮,李玉宏,等.银额盆地及邻区石炭—二叠系油气地质条件与资源前景[M].北京:地质出版社,2012. Lu Jincai,Chen Gaochao,Li Yuhong,et al. Carboniferous-Permian Geological Conditions and Resources Perspective in Yingen-Ejin Banner Basin and Its Vicinities[M].Beijing:Geological Publishing House,2012.
[17] 史冀忠,陈高潮,姜亭,等.内蒙古银额盆地及邻区石炭纪小独山期—二叠纪紫松期物源[J].地质通报,2013,32(11):1777-1789. Shi Jizhong,Chen Gaochao,Jiang Ting,et al. The Provenance of Carboniferous Xiaodushanian-Permian Zisongian Stage in Yingen-Ejin Banner Basin and Its Vicinities[J]. Geological Bulletin of China,2013,32(11):1777-1789.
[18] 段先锋,张雄华,卜建军.甘肃北山地区下石炭统红柳园组四射珊瑚动物群及其地质意义[J].地质科技情报,2011,30(6):13-17. Duan Xianfeng,Zhang Xionghua,Bu Jianjun. Early Carboniferous Rugose Coral Fauna Found in Hongliuyuan Formation in Beishan Area and Their Geological Significances[J].Geological Science and Technology Information,2011,30(6):13-17.
[19] Murray R W,Ten Brink M R B,Gerlach D C,et al. Rare Earth,Major,and Trace Element Composition of Monterey and DSDP Chert and Associated Host Sediment:Assessing the Influence of Chemical Fractionation During Diagenesis[J].Geochimica et Cosmochimica Acta,1992,56(7):2657-2671.
[20] 常华进,储雪蕾,冯连君,等.氧化还原敏感微量元素对古海洋沉积环境的指示意义[J].地质论评,2009,55(1):91-99. Chang Huajin,Chu Xuelei,Feng Lianjun,et al. Redox Sensitive Trace Elements as Paleoenvironments Proxies[J]. Geological Review,2009,55(1):91-99.
[21] Webb G E,Kamber B S. Rare Earth Elements in Holocene Reefal Microbialites:A New Shallow Seawater Proxy[J].Geochimica et Cosmochimica Acta,2000,64:1557-1564.
[22] Bau M,Dulski P D. Istribution of Yttrium and Rare Earth Elements in the Penge and Kuruman Ironformations,Transvaal Supergroup,South Africa[J].Precambiran Research,1996,79:27-55.
[23] Nagarajan R,Madhavaraju J,Armstrong-Altrin J S,et al. Geochemistry of Neoprotero-Zoic Limestones of the Shahabad Formation,Bhima Basin,Karnataka,Southern India[J]. Geosciences Journal,2011,15(1):9-25.
[24] McLennan S M. Rare Earth Elements in Sedimentary Rocks:Influence of Provenance and Sedimentary Processes[J].Mineralogical Society of American,1989,21:169-200.
[25] Shields G,Stille P. Diagenetic Constraints on the Use of Cerium Anomalies as Palaeoseawater Redox Proxies: An Isotopic and REE Study of Cambrian Phosphorites[J]. Chemical Geology,2001,175(1/2):29-48.
[26] Sholkovitze R,Landingw M,Lewis B L. Ocean Particle Chemistry: The Fractionation of Rare Earth Elements Between Suspended Particles and Seawater[J]. Geochimica et Cosmochimica Acta,1994,58(6):1567-1579.
[27] 王中刚,于学元,赵振华.国外稀土元素地球化学的进展[J].矿物岩石地球化学通报,1986,5(1):2-4. Wang Zhonggang,Yu Xueyuan,Zhao Zhenhua. Progress of Geochemistry on Rare Earth Elements Abroad[J].Bulletin of Mineralogy,Petrology and Geochemistry,1986,5(1):2-4.
[28] Bellanca A,Masetti D,Neti R. Rare Earth Elements in Limestone/Marlstone Couplets from the Albian-Cenomanian Cismon Section(Venetian Region,Northern Italy):Assessing REE Sensitivity to Environmental Changes[J]. Chemical Geology,1997,141:141-152.
[29] Veizer J,Demovic R. Strontium as a Tool for Facies Analysis[J]. Sedimentary Petrology,1974,44(1):93-115.
[30] 许中杰,孔锦涛,程日辉,等.下扬子南京地区早寒武世幕府山组海平面相对升降的地球化学和碳、氧同位素记录[J].吉林大学学报(地球科学版),2020,50(1):158-169. Xu Zhongjie,Kong Jintao,Cheng Rihui,et al. Geochemical and Carbon and Oxygen Isotope Records of Relative Sea-Level Change of Mufushan Formation in Early Cambrian in Nanjing,Lower Yangtze Region[J].Journal of Jilin University(Earth Science Edition),2020,50(1):158-169.
[31] 张健,张海华,陈树旺,等.松辽盆地北部上二叠统林西组地球化学特征及地质意义[J].吉林大学学报(地球科学版),2020,50(2):518-530. Zhang Jian,Zhang Haihua,Chen Shuwang,et al. Geochemical Characteristics and Geological Significance of Upper Permian Linxi Formation in Northern Songliao Basin[J].Journal of Jilin University (Earth Science Edition),2020,50(2):518-530.
[32] 汪凯明,罗顺社.燕山地区中元古界高于庄组和杨庄组地球化学特征及环境意义[J].矿物岩石地球化学通报,2009,28(4):356-364. Wang Kaiming,Luo Shunshe. Geochemical Characteristics and Environmental Significance of Gaoyuzhuang and Yangzhuang Formations in Yanshan Region[J]. Bulletin of Mineralogy,Petrology and Geochemistry,2009,28(4):356-364.
[33] Wright J,Schrader H,Holser W T. Palaeoredox Variations in Ancient Oceans Recorded by Rare Earth Elements in Fossil Apatite[J].Geochimica et Cosmochimica Acta,1987,51(3):631-644.
[34] Hatch J R,Leventhal J S. Relationship Between Inferred Redox Potential of the Depositional Environment and Geochemistry of the Upper Pennsylvanian (Missourian) Stark Shale Member of the Dennis Limestone,Wabaunsee County,Kansas,USA[J]. Chemical Geology,1992,99:65-82.
[35] Jones B J,Manning A C. Comparison of Geochemical Indices Used for the Interpretation of Palaeoredox Conditions in Ancient Mudstones[J].Chemical Geology,1994,111(1):111-129.
[36] 颜佳新,徐四平,李方林.湖北巴东栖霞组缺氧沉积环境的地球化学特征[J].岩相古地理,1998,18(6):27-32. Yan Jiaxin,Xu Siping,Li Fanglin. Geochemistry of the Dysaerobic Sedimentary Environments of the Qixia Formation in Badong,Hubei[J].Journal of Palaeogeography,1998,18(6):27-32.
[37] 李振清,周洪瑞,陈建强.山东淄博地区上寒武统沉积地球化学特征及其层序地层学意义[J].现代地质,2001,15(4):377-382. Li Zhenqing,Zhou Hongrui,Chen Jianqiang. Sedimental Geochemical Characteristics and Application of the Upper Cambrian in Zibo Area,Shandong[J]. Geoscience,2001,15(4):377-382.
[1] 张贵山, 邱红信, 温汉捷, 彭仁, 孟乾坤. 攀西红格钒钛磁铁矿矿田富钴硫化物中钴的地球化学特征及其地质意义[J]. 吉林大学学报(地球科学版), 2021, 51(6): 1740-1752.
[2] 宫昀迪, 李碧乐, 李治华, 于润涛, 孙永刚, 张森. 大兴安岭北段小柯勒河花岗斑岩脉成因及地质意义:锆石U-Pb年龄、岩石地球化学及Hf同位素制约[J]. 吉林大学学报(地球科学版), 2021, 51(6): 1753-1769.
[3] 张七道, 刘振南, 尹林虎. 深变质岩区地热流体化学特征及成因——以滇西陇川盆地温泉为例[J]. 吉林大学学报(地球科学版), 2021, 51(6): 1838-1852.
[4] 李天军, 黄志龙, 王瑞, 苟红光, 张品, 殷越. 银根—额济纳旗盆地天草凹陷下白垩统巴音戈壁组有效烃源岩地球化学特征及其形成环境[J]. 吉林大学学报(地球科学版), 2021, 51(4): 957-972.
[5] 叶涛, 王清斌, 黄志, 孙哲, 李飞, 陈安清. 碳酸盐岩层序地层格架对岩溶储层的控制作用——以渤海西南海域下古生界为例[J]. 吉林大学学报(地球科学版), 2021, 51(4): 991-1005.
[6] 史冬岩, 张坤, 张玉鹏, 高勇, 唐伟, 吕明奇. 黑龙江省浅覆盖区地物化特征与找矿标志——以黑河市340高地金矿化区为例[J]. 吉林大学学报(地球科学版), 2021, 51(4): 1042-1053.
[7] 赵越, 刘敬党, 张国宾, 张艳飞. 张广才岭南部帽儿山岩体二长花岗岩年代学、地球化学特征及其构造意义[J]. 吉林大学学报(地球科学版), 2021, 51(4): 1098-1118.
[8] 杨元江, 邓昌州, 李成禄, 张立, 高永志, 于喜洹. 大兴安岭大洋山钼矿区侵入岩年代学、岩石地球化学特征及岩石成因[J]. 吉林大学学报(地球科学版), 2021, 51(4): 1064-1081.
[9] 孙超, 苟军, 孙德有, 冯钊, 田丽. 黑龙江省西北部晚古生代I-A型花岗岩的成因及构造意义[J]. 吉林大学学报(地球科学版), 2021, 51(4): 1082-1097.
[10] 张雪, 翁凯, 赵晓健, 杜守礼, 尚颖. 新疆东天山卡拉塔格二叠纪火山岩成因及构造意义[J]. 吉林大学学报(地球科学版), 2021, 51(4): 1119-1138.
[11] 张亚蒲, 杨正明, 黄延章, 李海波, 侯海涛, 朱光亚. 低渗孔隙型碳酸盐岩油藏储层特征及剩余油分布规律[J]. 吉林大学学报(地球科学版), 2021, 51(3): 659-668.
[12] 曾志杰, 陈雷. 南秦岭山阳—柞水矿集区夏家店金矿床微量-铂族元素地球化学特征及其对矿床成因的指示[J]. 吉林大学学报(地球科学版), 2021, 51(3): 704-722.
[13] 张超, 石绍山, 时溢, 魏明辉, 杨帆, 郇恒飞, 李文博, 王路远. 华北板块北缘东段中三叠世构造演化——来自辽宁法库地区侵入岩的证据[J]. 吉林大学学报(地球科学版), 2021, 51(3): 734-748.
[14] 田梦宇, 狄永军, 王帅, 贾一龙. 广西云开地区那蓬岩体黑云母二长花岗岩年代学、地球化学特征及成因[J]. 吉林大学学报(地球科学版), 2021, 51(3): 749-766.
[15] 邓红宾, 李培龙, 魏华财, 何文劲, 杨鹏涛, 李宁, 唐华. 东昆仑造山带低山头花岗岩体岩石地球化学特征及其地质意义[J]. 吉林大学学报(地球科学版), 2021, 51(3): 767-782.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 尹秀珍,刘万洙,蓝先洪,万晓樵. 南黄海表层沉积物的碎屑矿物、地球化学特征及物源分析[J]. J4, 2007, 37(3): 491 -0499 .
[2] 滕吉文,田有,刘财,韩立国. 中国双相沉积盆地、古老结晶基底与东北地区深层潜在油气藏[J]. J4, 2008, 38(4): 527 -0552 .
[3] 刘洪林,李海山. ICA及其在气液两相流辨识中的应用[J]. J4, 2009, 39(1): 31 -0036 .
[4] 杨蕴, 吴剑锋, 吴吉春. 两种智能算法在求解地下水管理模型中的对比[J]. J4, 2009, 39(3): 474 -481 .
[5] 杨晓平,李仰春,柳 震, 汪 岩,王洪杰. 黑龙江东部鸡西盆地构造层序划分与盆地动力学演化[J]. J4, 2005, 35(05): 616 -621 .
[6] 王立军,刘国才,黄继国,李跃迁,丛颖,沈照理,赵晓波. 接触氧化技术在公园景观水体功能恢复中的运用试验研究[J]. J4, 2006, 36(03): 458 -461 .
[7] 初凤友,胡大千,姚杰. 中太平洋YJB海山富钴结核矿物组成与元素地球化学[J]. J4, 2007, 37(1): 8 -0014 .
[8] 黄芮, 陈剑平, 李会中, 张晨, 张文, 徐佩华. 基于φ值粒度成分分析的泥石流动力特性[J]. J4, 2011, 41(1): 182 -187 .
[9] 张世广, 柳成志, 卢双舫, 张雁, 吴高平, 刘秋宏. 高分辨率层序地层学在河、湖、三角洲复合沉积体系的应用--以朝阳沟油田扶余油层开发区块为例[J]. J4, 2009, 39(3): 361 -368 .
[10] 曾庆栋, 刘建明. 西拉沐伦钼矿带半拉山斑岩钼矿床花岗斑岩锆石SHRIMP U-Pb测年及其地质意义[J]. J4, 2010, 40(4): 828 -834 .