吉林大学学报(工学版)

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利用不同籽晶面生长优质宝石级金刚石单晶

臧传义,马红安,田宇,肖宏宇,贾晓鹏   

  1. 吉林大学 超硬材料国家重点实验室,长春 130012
  • 收稿日期:2005-05-19 修回日期:2005-08-11 出版日期:2006-01-01 发布日期:2006-01-01
  • 通讯作者: 贾晓鹏

Growth of Highquality Gem Diamonds with Different Seed Facets

Zang Chuanyi,Ma Hongan,Tian Yu,Xiao Hongyu,Jia Xiaopeng   

  1. National Key Laboratory for Superhard Materials, Jilin University, Changchun 130012, China
  • Received:2005-05-19 Revised:2005-08-11 Online:2006-01-01 Published:2006-01-01
  • Contact: Jia Xiaopeng

摘要: 为了研究不同籽晶生长面合成宝石级金刚石单晶(>1 mm),以NiMnCo金属触媒,采用高温高压温度梯度法合成了籽晶{1 0 0}生长面的优质宝石级金刚石单晶(>4 mm),并与以籽晶{1 1 1}作为生长面合成的晶体作了对比分析。结果表明:随着合成温度的升高,用{1 0 0}面生长出的晶体形貌由低温片状逐渐过渡到高温塔状,而用{1 1 1}面生长出的晶体形貌变化趋势则相反;采用籽晶{1 0 0}面或{1 1 1}面生长晶体,无论合成温度高低,包裹体都不容易进入片状晶体内部;只要存在合适的温度梯度,NiMnCo触媒同样适合利用籽晶{1 1 1}面生长优质大尺寸宝石级金刚石(≥4 mm)。因此可以利用该方法寻找物美价廉的新触媒以取代目前价格日益增长的NiMnCo合金。

关键词: 凝聚态物理学, 宝石级金刚石, 温度梯度法, 籽晶, 触媒

Abstract: lity gemgrade diamond crystal(>4 mm) was synthesized on {1 1 1} seed facets with NiMnCo as metal solvent using temperature gradient method (TGM) under high pressure and high temperature(HPHT), and compared with that grown on {1 0 0} facet. The results show that in the case of {1 0 0} , the morphology of crystal changes from lowtemperature sheet to hightemperature tower with increasing the synthesized temperature, whereas in the case of {1 1 1} the change trend is contrary to {1 0 0}. When {1 1 1} facet or {1 1 1} was used as the growth facet, the sheetlike crystal is more difficult to incorporated for the metal inclusion regardless of synthesized temperature. With NiMnCo metal as solvent, large highquality gemgrade diamonds can also grow on {1 1 1} facet with proper temperature gradient. Therefore, this method can be used to seek a cheaper metal solvent to replace expensive NiMnCo alloy for diamond synthesis.

Key words: condensed matter physics, gem diamond, temperature gradient method, seed, metal solvent

中图分类号: 

  • O469
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