A pure phase material Na
4MnV(PO
4)
3@C(NMVP@C) was prepared by solgel method, the Na
4MnV(PO
4)
3 was synthesized by graphene, and the JahnTeller effect was inhibited by reducing the content of Mn in the material. Electrochemical performance of materials were tested by galvanostatic dischargecharge method. The results show that when the Na
4MnV(PO
4)
3@C was used as a cathode material for sodium ion batteries, the specific capacity of 25—40 V was 105 mA·h/g, the average voltage was 3.6 V, and the capacity retention rate after 30 cycles was 63%. The capacity retention rate of composite material after 30 cycles was 71%. The specific capacity of low manganese material Na
3.5Mn
0.5V
1.5(PO
4)
3@C was 110 mA·h/g in 25—42 V, and the capacity retention rate after 50 cycles was 90%. The capacity retention rate of material was greatly improved.