Journal of Jilin University(Earth Science Edition) ›› 2020, Vol. 50 ›› Issue (6): 1766-1775.doi: 10.13278/j.cnki.jjuese.20190204

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Geochemical Characteristics and Influencing Factors of Selenium in Soil from Dandong Area, Liaoning Province

Li Yuchao, Wang Chengyu, Yu Chengguang   

  1. Liaoning Survey Academy Limited Liability Company of Geological and Mineral, Shenyang 110031, China
  • Received:2019-09-21 Published:2020-12-11
  • Supported by:
    Supported by Project of China Geological Survey (12120113001100)

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Abstract: The content, distribution regular and enrichment mechanism of Se in the soil of Dandong area (Liaoning Province) were discussed based on the survey data of the surface soil, soil profiles,and pedogenic rocks. The results show that the content of Se in the surface soil in the study area ranges from 0.028×10-6 to 0.910×10-6, which is higher than the national Se average in soil. The spatial distribution of Se is affected by the strata of Liaohe Group, showing the characteristics of surficial enrichment. The Se enrichment mechanism in the soil is the following:Se derived from the metamorphic rocks of Gaixian Formation and Gaojiayu Formation, gathered and affected by the process of soil formation, in which the clay particles or iron oxides aggregated in the brown loam layer and combined with selenium; The environmental geochemistry played a certain role in the enrichment of selenium in the surface soil, and the S, N and Se in soil adsorbed and fixed with each other, which was conducive to Se enrichment in soil;In addition, Al and Fe oxides had a strong adsorption capacity to Se; A significant negative correlation occurs between Se and pH in the soil in the study area, implying the low pH value in the soil accompanied by high Se content. In general, the content of Se in soil in the study area shows obviously positive relationship with organic matter, Fe-Al oxides, S and N, which is consistent with the research results of Se in Guangzhou, Fengcheng,and Enshi.

Key words: soil, selenium, geochemical charactertics, Dandong area, Liaoning

CLC Number: 

  • P595
[1] Navarro-Alarcón M, López-Martínez M C. Essentiality of Selenium in the Human Body:Relationship with Different Diseases[J]. Science of the Total Environment, 2000, 249(1/2/3):347-371.
[2] Keshavarzi B, Moore F, Najmeddin A, et al. The Role of Selenium and Selected Trace Elements in the Etiology of Esophageal Cancer in High Risk Golestan Province of Iran[J]. Science of the Total Environment, 2012, 433:89-97.
[3] 李永华,王五一. 硒的土壤环境化学研究进展[J]. 土壤通报,2002, 33(3):230-233. Li Yonghua, Wang Wuyi. Process on the Study Soil Environmental Chemistry of Selenium[J]. Chinese Journal of Soil Science, 2002, 33(3):230-233.
[4] 余涛,杨忠芳,王锐,等. 恩施典型富硒区土壤硒与其他元素组合特征及来源分析[J]. 土壤, 2018, 50(6):1119-1125. Yu Tao, Yang Zhongfang, Wang Rui, et al. Characteristics and Sources of Soil Selenium and Other Elements in Typical High Selenium Soil Area of Enshi[J]. Soils, 2018, 50(6):1119-1125.
[5] Lü Yaoyao, Yu Tao, Yang Zhongfang, et al. Constraint on Selenium Bioavailability Caused by Its Geochemical Behavior in Typical Kaschin-Beck Disease Areas in Aba, Sichuan Province of China[J]. Science of the Total Environment, 2014, 493:737-749.
[6] 王锐,余涛,杨忠芳,等. 富硒土壤硒生物有效性及影响因素研究[J]. 长江流域资源与环境, 2018, 28(7):1647-1654. Wang Rui, Yu Tao, Yang Zhongfang, et al. Bioavailability of Soil Selenium and Its Influencing Factors in Selenium-Enriched Soil[J]. Resources and Environment in the Yangtze Basin,2018, 28(7):1647-1654.
[7] Li Zhe, Liang Dongli, Peng Qin, et al. Interaction Between Selenium and Soil Organic Matter and Its Impact on Soil Selenium Bioavailability:A Review[J]. Geoderma, 2017, 295:69-79.
[8] 布和敖斯尔,张东威,刘力.土壤硒区域环境分异及安全阈值的研究[J].土壤学报,1995,32(2):186-193. Buber Aoseer, Zhang Dongwei, Liu Li. Regional Environmental Differentiation and Regional Safety Threshold of Soil Selenium[J]. Acta Pedologica Sinica, 1995, 32(2):186-193.
[9] 曾庆良,余涛,王锐. 土壤硒含量影响因素及富硒土地资源区划研究:以湖北恩施沙地为例[J]. 现代地质, 2018, 32(1):105-112. Zeng Qingliang, Yu Tao, Wang Rui. The Influencing Factors of Selenium in Soils and Classifying the Selenium-Rich Soil Resources in the Typical Area of Enshi, Hubei[J]. Geoscience, 2018, 32(1):105-112.
[10] Supriatin S, Weng L, Comans R N J. Selenium-Rich Dissolved Organic Matter Determines Selenium Uptake in Wheat Grown on Low-Selenium Arable Land Soils[J]. Plant and Soil, 2016, 408(1/2):73-94.
[11] 段国正, 马力, 郝立波, 等. 大兴安岭地区火山岩风化过程中的微量元素均一化[J]. 吉林大学学报(地球科学版), 2003,33(4):434-436. Duan Guozheng, Ma Li, Hao Libo,et al. The Trace Element Homogenizition in Weathering Process of Volcanic Rocks, in the Greater Xing'an Mountains[J]. Journal of Jilin University(Earth Science Edition), 2003, 33(4):434-436.
[12] 王冬艳, 杨园园, 李月芬,等. 吉林西部土壤有机碳含量与元素地球化学特征[J]. 吉林大学学报(地球科学版), 2011,41(增刊1):333-338. Wang Dongyan, Yang Yuanyuan, Li Yuefen, et al. Content of Soil Organic Carbon and Characteristics of Elemental Geochemistry in West of Jilin Province[J]. Journal of Jilin University(Earth Science Edition), 2011, 41(Sup.1):333-338.
[13] 魏华玲, 周国华, 孙彬彬,等. 浙江省东部土壤元素地球化学特征及意义[J]. 吉林大学学报(地球科学版), 2013, 43(2):564-572. Wei Hualing, Zhou Guohua, Sun Binbin, et al. Significance and Characteristics of Soil Trace Elements Geochemistry in the Eastern of Zhejiang Province, China[J]. Journal of Jilin University(Earth Science Edition), 2013, 43(2):564-572.
[14] 杨琼, 侯青叶, 顾秋蓓, 等. 广西武鸣县典型土壤剖面Se的地球化学特征及其影响因素研究[J]. 现代地质, 2016, 30(2):455-462. Yang Qiong, Hou Qingye, Gu Qiubei, et al. Study of Geochemical Characteristics and Influencing Factors of Soil Selenium in the Typical Soil Profiles in Wuming County of Guangxi[J]. Geoscience, 2016, 30(2):455-462.
[15] 沈骁, 姬丙艳, 许光, 等. 青海西宁-乐都富硒土壤成因探讨[J]. 中国矿业, 2016, 25(增刊1):382-385,389. Shen Xiao, Ji Bingyan, Xu Guang, et al. Discussion on the Genetic Type of Selenium-Rich Area in Xining-Ledu[J]. China Mining Magazine, 2016, 25(Sup.1):382-385,389.
[16] 魏振山, 涂其军, 唐蜀虹, 等. 天山北坡乌鲁木齐至沙湾地区富硒土壤地球化学特征及成因探讨[J]. 物探与化探, 2016, 40(5):893-898. Wei Zhenshan, Tu Qijun, Tang Shuhong, et al. A Discussion on the Geochemical Features and Origin of Selenium-Rich Soil on the Northern Slope of the Tianshan Mountains from Urumqi to Shawan County[J]. Geophysical & Geochemical Exploration, 2016, 40(5):893-898.
[17] 商靖敏, 罗维, 吴光红, 等. 洋河流域不同土地利用类型土壤硒(Se)分布及影响因素[J]. 环境科学, 2015, 36(1):301-308. Shang Jingmin, Luo Wei, Wu Guanghong, et al. Spatial Distribution of Se in Soils from Different Land Use Types and Its Influencing Factors Within the Yanghe Watershed, China[J].Environmental Science, 2015, 36(1):301-308.
[18] 多目标地球化学调查规范:DZ/T 0258-2014[S].北京:中国标准出版社,2014. Sepcification of Multi-Purpose Regional Geochemical Survey:DZ/T 0258-2014[S]. Beijing:Standards Press of China,2014.
[19] 黎彤. 化学元素的地球丰度[J]. 地球化学, 1976,5(3):167-174. Li Tong. Chemical Element Abundances in the Earth and Its Major Shells[J]. Geochimica, 1976,5(3):167-174.
[20] 鄢明才,迟清华.中国东部地壳与岩石的化学组成[M].北京:地质出版社,1997. Yan Mingcai, Chi Qinghua. Chemical Composition of Crust and Rocks in Eastern China[M]. Beijing:Geological Publishing House, 1997.
[21] Goldschmidt. Geochemistry[M]. Fair Lawn:Oxford University Press, 1954.
[22] Vinogradov A P. Detection and Analysis of Rare Elements[M]. London:Oldbourne Press, 1962.
[23] Taylor S R. Trace Element Abundances and the Chondritic Earth Model[J]. Geochimica et Cosmochimica Acta, 1964, 28(12):1989-1998.
[24] Taylor S R, Mclennan S M. The Continental Crust:Its Composition and Evolution[J]. The Journal of Geology, 1985, 94(4):57-72.
[25] Wedepohl K H. The Composition of the Continental Crust[J]. Geochimica et Cosmochimica Acta, 1995, 59(7):1217-1232.
[26] 郦逸根, 董岩翔, 郑洁, 等. 浙江富硒土壤资源调查与评价[J]. 第四纪研究, 2005,25(3):323-330. Li Yigen, Dong Yanxiang, Zheng Jie, et al. SELENIUM:Abundant Soil Survey and Assessment in Zhejiang[J]. Quaternary Sciences, 2005, 25(3):323-330.
[27] 杨忠芳,余涛,侯青叶,等. 海南岛农田土壤Se的地球化学特征[J]. 现代地质,2012, 26(5):837-849. Yang Zhongfang, Yu Tao, Hou Qingye, et al. Geochemical Characteristics of Soil Selenium in Farmland of Hainan Island[J]. Geoscience, 2012, 26(5):837-849.
[28] 章海波,骆永明,吴龙华,等. 香港土壤研究:Ⅱ:土壤硒的含量、分布及其影响因素[J]. 土壤学报, 2005, 42(3):404-410. Zhang Haibo, Luo Yongming, Wu Longhua, et al. Hong Kong Soil Researches:Ⅱ:Distribution and Content of Selenium in Soils[J]. Acta Pedologica Sinica, 2005, 42(3):404-410.
[29] 杨志强,李杰,郑国东,等. 广西北部湾沿海经济区富硒土壤地球化学特征[J]. 物探与化探, 2014, 38(6):1260-1264. Yang Zhiqiang, Li Jie, Zheng Guodong, et al. Geochemical Characteristics of Selenium-Rich Soil in Beibu Gulf Coastal Economic Zone of Guangxi[J]. Geophysical and Geochemical Exploration, 2014, 38(6):1260-1264.
[30] 侯少范,王丽珍,李德珠,等. 控制土壤硒化学行为因素的探讨[J]. 地理研究,1991, 10(4):12-18. Hou Shaofan, Wang Lizhen, Li Dezhu, et al.The Study of the Controlling Factors of Selenium Chemical Behaviour in Soil[J]. Geographical Research, 1991, 10(4):12-18.
[31] 王五一,王大成,王卫中,等. 我国土壤中硒的淋溶[J]. 地理研究, 1992, 11(2):34-40. Wang Wuyi, Wang Dacheng, Wang Weizhong, et al.A Preliminary Study on Leaching of Selenium in the Soils of China[J]. Geographical Research, 1992, 11(2):34-40.
[32] Kausch M F, Pallud C E. Modeling the Impact of Soil Aggregate Size on Selenium Immobilization[J]. Biogeosciences,2013, 10(3):1323-1336.
[33] 朱建明, 梁小兵, 凌宏文, 等. 环境中硒存在形式的研究现状[J].矿物岩石地球化学通报, 2003,22(1):75-81. Zhu Jianming, Liang Xiaobing, Li Hongwen, et al. Advances in Studying Occurrence Modes of Selenium in Environment[J]. Bulletin of Mineralogy Petrology & Geochemistry, 2003, 22(1):75-81.
[34] 李永华, 王五一, 杨林生, 等. 陕南土壤中水溶态硒、氟的含量及其在生态环境的表征[J]. 环境化学, 2005(3):279-283. Li Yonghua,Wang Wuyi,Yang Linsheng,et a1. The Soil Water Content in the South of Shaanxi Province Dissolved Selenium, Fluoride and in the Characterization of the Ecological Environment[J]. Environmental Chemistry,2005(3):279-283.
[35] 王美珠, 章明奎. 我国部分高硒低硒土壤的成因初探[J]. 浙江农业大学学报, 1996, 22(1):89-93. Wang Meizhu, Zhang Mingkui. A Discussion on the Cause of High-Se and Low-Se Soil Information[J]. Journal of Zhejiang Agricultural University, 1996, 22(1):89-93.
[36] 周越, 吴文良, 孟凡乔, 等. 土壤中硒含量、形态及有效性分析[J]. 农业资源与环境学报, 2014, 31(6):527-532. Zhou Yue, Wu Wenliang, Meng Fanqiao, et al. Review on the Content, Specification of Selenium and Its Availability in Soils[J]. Journal of Agricultural Resources and Environment, 2014, 31(6):527-532.
[37] 龚河阳, 李月芬, 汤洁, 等. 吉林省西部土壤硒含量、形态分布及影响因素[J]. 吉林农业大学学报, 2015, 37(2):177-184, 190. Gong Heyang, Li Yuefen,Tang Jie, et al. Content, Form Distribution and Influencing Factors of Soil Seleniumin Western Jilin Province[J]. Journal of Jilin Agricultural University, 2015, 37(2):177-184, 190.
[38] 陈显著, 李就好. 广州市土壤硒含量的分布及其影响因素研究[J]. 福建农业学报, 2016,31(4):401-407. Chen Xianzhu, Li Jiuhao. Concentration, Distribution,and Influencing Factors on Soil Selenium in Guangzhou[J]. Fujian Journal of Agricultural Sciences, 2016, 31(4):401-407.
[39] 韩笑,周越,吴文良,等. 富硒土壤硒含量及其与土壤理化性状的关系:以江西丰城为例[J]. 农业环境科学学报, 2018, 37(6):1177-1183. Han Xiao, Zhou Yue, Wu Wenliang, et al. Selenium Contents of Farmland Soils and Their Relationship with Main Soil Properties in Fengcheng, Jiangxi[J]. Journal of Agro-Environment Science, 2018, 37(6):1177-1183.
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