Journal of Jilin University(Engineering and Technology Edition) ›› 2019, Vol. 49 ›› Issue (6): 2010-2018.doi: 10.13229/j.cnki.jdxbgxb20181037

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Effect of TiC particles on microstructure and mechanical properties of as cast ductile iron

Jin-guo WANG1,2(),Shuai REN1,2,Rui-fang YAN1,2,Kai HUANG1,2,Zhi-qiang WANG1,2   

  1. 1. Key Laboratory of Automotive Materials, Ministry of Education, Jilin University, Changchun 130022, China
    2. College of Materials Science and Engineering, Jilin University, Changchun 130022, China
  • Received:2018-10-15 Online:2019-11-01 Published:2019-11-08

Abstract:

TiC powder was modified by high-energy ball milling and added to the melt of nodular cast iron. The tissues were analyzed by optical microscopy (OM), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). The results show that both graphite and matrix of the ductile iron are improved. As the heterogeneous nucleation core of graphite, some TiC particles promote the nucleation of graphite, increase the number of graphite spheres by 40.5%, refine the size of graphite spheres, indirectly increase the ferrite content by 4.5%, and increase the spheroidization rate by 9.1%. On the one hand, the morphology of the surrounding cementite is changed, and even the unique “pearlite colony” structure can be formed. On the other hand, the ferrite grain is refined due to the hindrance of TiC particles to grain boundary movement. The mechanical properties of the as-cast ductile iron were tested by tensile test machine and impact test machine. The total elongation, impact toughness at room temperature and impact toughness at low temperature (-20 °C) were increased by 19.1%, 31.1% and 21.8% respectively by adding a small amount of TiC particles.

Key words: metallic materials, as cast ductile iron, TiC, plasticity, impact toughnes

CLC Number: 

  • TG143.5

Fig.1

Morphology and element surface distribution of modified TiC particles"

Table 1

Mass fraction of composition ofductile iron samples %"

试样 C Si Mn P S Ti Mg Ce
a 3.03 2.40 0.52 0.006 0.008 0.006 0.041 0.029
b 3.03 2.37 0.51 0.006 0.008 0.022 0.042 0.027

Fig.2

Graphite and matrix structure ofdifferent samples"

Table 2

Specimen tissue statistics"

试样 球化率/% 单位石墨数/(N·mm-2) 石墨面积比/%

铁素体

含量/%

a 70.2 42.5 9.30 61.5
b 79.3 59.7 11.39 66.0

Fig.3

Distribution of TiC particles in matrix"

Fig.4

Schematic diagram of ferrite grain size measurement"

Fig.5

Tensile curves of sample"

Fig.6

Impact toughness of specimens"

Fig.7

Fracture morphology"

1 何春华 . 高强韧铸态球墨铸铁技术研究及应用[J]. 铸造, 2017, 66(11): 1210-1212.
1 He Chun-hua . Research and application of high strength and toughness cast ductile iron technology[J]. Foundry, 2017, 66(11): 1210-121.
2 曾大新, 何汉军, 张元好, 等 . 铸态高强度高伸长率球墨铸铁研究进展[J]. 铸造, 2017, 66(1): 38-43, 49.
2 Zeng Da-xin , He Han-jun , Zhang Yuan-hao , et al . Research progress of as cast high strength and high elongation ductile iron[J]. Foundry, 2017, 66(1): 38-43, 49.
3 陈文怡, 周建 . 球磨时间对TiC-不锈钢复合粉料粒度和组织的影响[J]. 材料热处理, 2007, 36(10): 12-14.
3 Chen Wen-yi , Zhou Jian . Influence of ball-milling time on granularity and microstructure of stainless steel nano-composite powder with TiC[J]. Material and Heat Treatment, 2007, 36(10): 12-14.
4 Wang L , Sun Y S , Fan Q , et al . Tensile and wear properties of TiC reinforced 420 stainless steel fabricated by in situ synthesis[J]. Journal of Southeast University (English Edition), 2004, 20(4): 486-491.
5 Park J J , Park E K , Hong S M , et al . Microstructure and properties of SA 106B carbon steel after treatment of the melt with nano-sized TiC particles[J]. Materials Science and Engineering A, 2014, 613: 217-223.
6 Hong Sung-mo , Eun-kwang Park , Jin-ju Park , et al . Effect of nano-sized TiC particle addition microstructure and mechanical properties of SA-106B carbon steel[J]. Materials Science and Engineering A, 2015, 643: 37-46.
7 Xu Z M , Liang G F , Guan Q F , et al . TiC as heterogeneous nuclei of the (Fe, Mn)3C and austenite intergrowth eutectic in austenite steel matrix wear resistant composite[J]. Materials Research Bulletin, 2004, 39(3): 457-463.
8 Razavi M , Yaghmaee M S , Rahimipour M R , et al . The effect of production method on properties of Fe-TiC composite[J]. International Journal of Mineral Processing, 2010, 94(3/4): 97-100.
9 Fu H G , Wu X J , Li X Y , et al . Effect of TiC particle additions on structure and properties of hypereutectic high chromium cast iron[J]. Journal of Materials Engineering and Performance, 2009, 18(8): 1109-1115.
10 Razavi M , Rahimipour M R , Rajabi-zamani A H . Effect of nanocrystalline TiC powder addition on the hardness and wear resistance of cast iron[J]. Materials Science and Engineering A, 2007, 454: 144-147.
11 马明亮, 董增祥, 魏健宁, 等 . 高能球磨在材料制备领域的工业化应用[J]. 热加工工艺, 2006, 35(6): 66-69.
11 Ma Ming-liang , Dong Zeng-xiang , Wei Jian-ning , et al . Industrial application of high-energy ball milling in the field of material preparation[J]. Hot Processing Technology, 2006, 35(6): 66-69.
12 GB/T229—2007.金属材料——夏比摆锤冲击试验方法[S].
13 GB/T9441—2009.球墨铸铁金相检验[S].
14 Bramfitt B L . Planar lattice disregistry theory and its application on heterogistry nuclei of metal[J]. Metall Mater Trans B, 1970, 1(7): 1987-1995.
15 申志清 . 球墨铸铁石墨球核心的组成及热力学分析[D]. 济南:山东大学材料科学与工程学院, 2012.
15 Shen Zhi-qing . Composition and thermodynamic analysis of graphite core of ductile iron[D]. Ji'nan:School of Materials Science and Engineering, Shandong University, 2012.
16 杨长贺, 陈美玲, 高钦, 等 . 球墨铸铁弹性模量与金相组织及抗拉强度关系的研究[J]. 大连工学院学报, 1987, 26(4): 69-73.
16 Yang Chang-he , Chen Mei-ling , Gao Qin , et al . Study on the relationship between elastic modulus and metallographic structure and tensile strength of nodular cast iron[J]. Journal of Dalian Institute of Technology, 1987, 26(4): 69-73.
17 Fra? E , Górny M . Inoculation effects of cast iron[J]. Arichives of Foundry Engineering, 2012, 12(4): 39-46.
18 邢炳泽 . 低碳球墨铸铁[M]. 北京:中国农业科学技术出版社, 2012.
19 Rivera G , Boeri R , Sikora J . Revealing and characterising solidification structure of ductile cast iron[J]. Materials Science and Technology, 2002, 18(6): 691-697.
20 康煜平 . 金属固态相变及应用[M]. 北京: 化学工业出版社, 2007.
21 GB/T6394—2002.金属平均晶粒度测定方法[S].
22 陈大柔, 顾进立, 龙锐 . 铁素体球墨铸铁拉伸断裂过程与断口形貌的研究[J]. 现代铸铁, 1987(3): 28-32.
22 Chen Da-rou , Gu Jin-li , Long Rui . Study on tensile fracture process and fracture morphology of ferritic ductile iron[J]. Modern Cast Iron, 1987(3): 28-32.
23 张新宁, 曲迎东, 李荣德, 等 . 铁素体球墨铸铁低温冲击断裂裂纹形核及扩展机理[J]. 金属学报, 2015, 51(11): 1333-1340.
23 Zhang Xin-ning , Qu Ying-dong , Li Rong-de , et al . Mechanism of crack nucleation and propagation of ferrite ductile iron during impact fracture under low temperatures[J]. Acta Metallurgica Sinica, 2015, 51(11): 1333-1340.
24 李荣德, 张新宁, 蒋立鹏, 等 . 铁素体球墨铸铁低温冲击断裂行为的影响因素[J]. 机械工程学报, 2016, 52(10): 25-31.
24 Li Rong-de , Zhang Xin-ning , Jiang Li-peng , et al . Influence factors of ferrite cast iron of low-temperature impact fracture behavior[J]. Journal of Mechanical Engineering, 2016, 52(10): 25-31.
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