Journal of Jilin University(Earth Science Edition) ›› 2016, Vol. 46 ›› Issue (2): 552-562.doi: 10.13278/j.cnki.jjuese.201602205

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Implications of Cadmium Forms and Risk Assessment of Calcareous Soil in Karst Area: A Case Study of Maocun in Guilin, China

Zhou Changsong, Zou Shengzhang, Li Lujuan, Zhu Danni, Lu Haiping, Xia Riyuan   

  1. Institute of Karst Geology, Chinese Academy of Geological Sciences/Karst Dynamics Laboratory, MLR/Key Laboratory of Karst Ecosystem and Treatment of Rocky Desertification, Guilin 541004, Guangxi, China
  • Received:2015-06-29 Published:2016-03-26
  • Supported by:

    Supported by Geological Survey Project of Ministry of Land and Resources(1212011121166,121237131301101,2002371120029,1212011220959),National Key Basic Research Program Project (2011CB201001),and Basic Research Projects of the Institute of Karst Geology, and Chinese Academy of Geological Sciences (2014030,2015016)

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Abstract:

In order to grasp the forms and accumulation of cadmium in the soils of karst area, three calcareous soil samples collected from Maocun, Guilin, were analyzed.Their cadmium concentration was tested by an atomic spectrometer, and the cadmium was tested by an improved. Tessier assay, for its different existing status as it is in the five forms of EXC(exchangeable), CAB(carbonate combined), OXI(Fe-Mn oxide combined), ORG(organic combined) and RES(residual). Moreover, its risk to the environment and implications were analyzed and evaluated. The results showed that the relative cadmium contents of the three calcareous soil are:Black calcareous soil> Brown calcareous soil> Red calcareous soil;Cadmium in Black calcareous soil and Brown calcareous soil present mainly in Fe-Mn oxide combined form, and the chance to find it in other forms is reduced by the order of OXI> RES> EXC> CAB> ORG.In Red calcareous soil, the relative contents of cadmium in different chemical forms reduced in the order of RES> OXI> EXC> CAB> ORG. The results of RSP and RAC showed that cadmium contents of the three calcareous soil are:Black calcareous soil> Brown calcareous soil> Red calcareous soil. The ecological and health risks of cadmium of the three calcareous soil are:Black calcareous soil> Brown calcareous soil> Red calcareous soil. The results provide basic data for remediation and control of cadmium in karst area.

Key words: calcareous soil, cadmium, heavy metal, forms, karst area, risk

CLC Number: 

  • S512

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