疏水降溶性磷石膏填充沥青路面的水稳特性

doi:10.13229/j.cnki.jdxbgxb.20241186

吉林大学学报(工学版) ›› 2025, Vol. 55 ›› Issue (12): 3964-3975.doi: 10.13229/j.cnki.jdxbgxb.20241186

• 交通运输工程·土木工程 • 上一篇

疏水降溶性磷石膏填充沥青路面的水稳特性

郭威¹(),顾凯鹏²,王思莹¹,任东亚³,李学友⁴,田伟²()

^1.中国矿业大学矿业工程学院，江苏徐州 221116
^2.吉林建筑大学交通科学与工程学院，长春 130119
^3.西南交通大学土木工程学院，成都 610031
^4.中铁二局第四工程有限公司，成都 610306

收稿日期:2024-11-05 出版日期:2025-12-01 发布日期:2026-02-03
通讯作者: 田伟 E-mail:weiguo@cumt.edu.cn;weitianjljz@outlook.com
作者简介:郭威（1993-），男，讲师，博士.研究方向：矿山固废的路用处置.E-mail：weiguo@cumt.edu.cn
基金资助:
国家自然科学基金青年科学基金项目(52408499);吉林省科技发展计划重点研发项目(20230203169SF)

Moisture stability of hydrophobicity⁃desolubilization phosphogypsum filled asphalt pavement

Wei GUO¹(),Kai-peng GU²,Si-ying WANG¹,Dong-ya REN³,Xue-you LI⁴,Wei TIAN²()

^1.School of Mining Engineering，China University of Mining and Technology，Xuzhou 221116，China
^2.School of Traffic Science & Engineering，Jilin Jianzhu University，Changchun 130119，China
^3.School of Civil Engineering，Southwest Jiaotong University，Chengdu 610031，China
^4.China Railway ERJU 4th Engineering Co. ，Ltd，Chendu 610306，China

Received:2024-11-05 Online:2025-12-01 Published:2026-02-03
Contact: Wei TIAN E-mail:weiguo@cumt.edu.cn;weitianjljz@outlook.com

摘要/Abstract

摘要：

针对磷石膏填充沥青路面遇水后的溶融软化现象，提出了一种路用磷石膏的疏水降溶处置方法，并对其填充沥青路面的水稳特性和疏水降溶机理进行了研究。结果表明，未改性磷石膏沥青路面浸水残留稳定度以及冻融劈裂强度比均不满足路用水稳要求，其浸水600 h后，磷石膏填料颗粒数量减少了52.60%。经疏水降溶改性处理后，磷石膏的表面极性分量降低了72.46%，与沥青的黏附功提高了11.15%，界面过渡区厚度提高了546%。其作用机理在于，硅烷偶联剂可在磷石膏表面发生脱水缩合反应，接枝形成硅醇基团覆膜，通过覆膜改变磷石膏的表面亲水特性，有效阻止水分的入侵以及水分对沥青膜的置换，进而提高水稳性能。本文研究成果可为拓展磷石膏的路用场景提供理论指导。

关键词: 磷石膏, 疏水降溶, 路面充填, 水稳特性, 降溶机理

Abstract:

To address the melting and softening issues of phosphogypsum （PG）-filled asphalt pavement after exposure to water， a hydrophobicity treatment of PG was introduced to reduce solubility. An in-depth investigation was conducted into the moisture stability characteristics and solubility reduction mechanisms of asphalt pavement incorporating modified PG. The results showed that the immersion residual stability and freeze-thaw splitting strength ratio did not meet the moisture stability requirements for pavements. Additionally， after 600 hours of immersion， the number of PG filler particles decreased by 52.60%. Following hydrophobic modification， the polar component of PG decreased by 72.46%， the interface adhesion strength improved by 11.15%， and the thickness of the interface transition zone increased by 546%. The mechanism is that silane coupling agent can undergo dehydration condensation reaction on the surface of phosphogypsum and graft to form a silanol group coating. The hydrophilic property of the phosphogypsum surface is altered by the coating， which effectively prevents the intrusion of water and the displacement of the asphalt film， thereby improving the water stability performance. These results provide a theoretical basis for expanding the application of PG in road construction.

Key words: phosphogypsum, hydrophobicity desolubilization, pavement filling, moisture stability, hydrophobicity mechanism

中图分类号:

U414

郭威,顾凯鹏,王思莹,任东亚,李学友,田伟. 疏水降溶性磷石膏填充沥青路面的水稳特性[J]. 吉林大学学报(工学版), 2025, 55(12): 3964-3975.

Wei GUO,Kai-peng GU,Si-ying WANG,Dong-ya REN,Xue-you LI,Wei TIAN. Moisture stability of hydrophobicity⁃desolubilization phosphogypsum filled asphalt pavement[J]. Journal of Jilin University(Engineering and Technology Edition), 2025, 55(12): 3964-3975.

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参考文献 22

[1]	丁建文, 张帅, 洪振舜, 等. 水泥-磷石膏双掺固化处理高含水率疏浚淤泥试验研究[J]. 岩土力学, 2010, 31(9): 2817-2822.
	Ding Jian-wen, Zhang Shuai, Hong Zhen-shun, et al. Experimental study of solidification of dredged clays with high water content by adding cement and phosphogypsum synchronously[J]. Rock and Soil Mechanics, 2010, 31(9): 2817-2822.
[2]	崔荣政, 白海丹, 高永峰, 等. 磷石膏综合利用现状及“十四五”发展趋势[J]. 无机盐工业, 2022, 54(4): 1-4.
	Cui Rong-zheng, Bai Hai-dan, Gao Yong-feng, et al. Current situation of comprehensive utilization of phosphogypsum and its development trend of 14th Five-Year Plan[J]. Inorganic Chemicals Industry, 2022, 54(4): 1-4.
[3]	夏举佩. 磷石膏用作建筑材料的瓶颈与关键技术[J]. 磷肥与复肥, 2020, 35(11): 1.
	Xia Ju-pei. Bottleneck and key technology of phosphogypsum as building material[J]. Eco-industry Science & Phosphorus Fluorine Engineering, 2020, 35(11): 1.
[4]	江君德, 杨艳, 胡黔, 等. 磷石膏的转晶机制研究进展[J]. 生态产业科学与磷氟工程, 2024, 39(9): 60-65.
	Jiang Jun-de, Yang Yan, Hu Qian, et al. Research progress on crystal transformation mechanism of phosphogypsum[J]. Eco-industry Science & Phosphorus Fluorine Engineering, 2024, 39(9): 60-65.
[5]	EI-Didamony H, Gado H S, Awwad N S, et al. Treatment of phosphogypsum waste produced from phosphate ore processing[J]. Journal of Hazardous Materials, 2013, 244-245: 596-602.
[6]	陈攀, 李梦迪, 胡磊, 等. 磷石膏资源化利用的现状、方法、趋势和挑战[J]. 广东化工, 2024, 51(14): 68-70.
	Chen Pan, Li Meng-di. Hu Lei,et al. The current situation, methods, trends, and challenges of resource utilization of phosphogypsum[J]. Guangdong Chemical Industry, 2024, 51(14): 68-70.
[7]	张利珍, 张永兴, 张秀峰, 等. 中国磷石膏资源化综合利用研究进展[J]. 矿产保护与利用, 2019, 39(4): 14-18, 92.
	Zhang Li-zhen, Zhang Yong-xing, Zhang Xiu-feng, et al. Research progress on resource utilization of phosphogypsum in china[J]. Conservation and Utilization of Mineral Resources, 2019, 39(4): 14-18, 92.
[8]	Liu D S, Wang C Q, Mei X D, et al. An effective treatment method for phosphogypsum[J]. Environmental Science and Pollution Research, 2019, 26(29): 30533-30539.
[9]	Tovazhnyansky L L, Meshalkin V P, Kapustenko P O, et al. Energy efficiency of complex technologies of phosphogypsum conversion[J]. Theoretical Foundations of Chemical Engineering, 2013, 47(3): 225-230.
[10]	张峻, 解维闵, 董雄波, 等. 磷石膏材料化综合利用研究进展[J]. 材料导报, 2023, 37(16): 163-174.
	Zhang Jun, Xie Wei-min, Dong Xiong-bo, et al. Research progress on comprehensive utilization of phosphogypsum materials[J]. Materials Reports, 2023, 37(16): 163-174.
[11]	Reijnders L. Cleaner phosphogypsum, coal combustion ashes and waste incineration ashes for application in building materials: a review[J]. Building and Environment, 2007, 42(2): 1036-1042.
[12]	黄赟. 磷石膏基水泥的开发研究[D]. 武汉: 武汉理工大学材料科学与工程学院, 2010.
	Huang Yun. Research and development of phosphogypsum based cement[D]. Wuhan: School of Materials Science and Engineering of Wuhan University of Technology, 2010.
[13]	Wu J H, Xu T, Chu H Q, et al. Study on synergistic effect of xanthan gum and sodium methylsiliconate on mechanical strength and water stability of phosphogypsum road-based materials[J]. Materials, 2023, 16(20): No.6766.
[14]	陈涛, 陈德玉, 米阳, 等. 用磷建筑石膏制备抹面砂浆试验研究[J]. 混凝土与水泥制品, 2018,(4): 77-80.
	Chen Tao, Chen De-yu, Mi Yang, et al. Experimental research on decorative mortar prepared by calcined gypsum from phosphogypsum[J]. China Concrete and Cement Products, 2018, (4): 77-80.
[15]	李俊鹏, 谭维. 磷石膏在公路路基中的应用研究[J]. 低碳世界, 2018, (11): 227-228.
	Li Jun-peng, Tan Wei. Research on the application of phosphogypsum in highway roadbed[J]. Low Carbon World, 2018, (11): 227-228.
[16]	张厚记, 宗炜, 郑武西, 等. 工业固废磷石膏复合稳定基层材料研究[J]. 武汉理工大学学报, 2021, 43(12): 7-12.
	Zhang Hou-ji, Zong Wei, Zheng Wu-xi, et al. Composite stabilized base material research of industrial solid waste phosphogypsum[J]. Journal of Wuhan University of Technology, 2021, 43(12): 7-12.
[17]	Shi Y, Li Y, Wang H. Eco-friendly solid waste-based cementitious material containing a large amount of phosphogypsum: Performance optimization, micro-mechanisms, and environmental properties[J]. Journal of Cleaner Production, 2024, 471: No.143335.
[18]	陈开圣, 张坤, 胡兴, 等. 磷石膏稳定土临界动应力及累积变形特性研究[J]. 建筑科学与工程学报, 2023, 40(6): 170-180.
	Chen Kai-sheng, Zhang Kun, Hu Xing, et al. Study on the critical dynamic stress and accumulated deformation characteristics of phosphogypsum stabilized soil [J]. Journal of Architecture, Science and Engineering, 2023, 40(6): 170-180.
[19]	Dong C Y, Xiang H, Hu X D, Wu H, et al. Evaluation of the influence of phosphogypsum-based composite filler on performance of the SMA-13 asphalt mixture and its harmless treatment[J]. Sustainability, 2024, 16(15):No.6613.
[20]	Qian G P, Wang K, Bai X P, et al. Effects of surface modified phosphate slag powder on performance of asphalt and asphalt mixture[J]. Construction and Building Materials, 2018,158: 1081-1089.
[21]	. 公路工程沥青及沥青混合料试验规程 [S]
[22]	Chen X, Wu Q, Gao J, et al. Hydration characteristics and mechanism analysis of β-calcium sulfate hemihydrate[J]. Construction and Building Materials, 2021, 296: No.123714.

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技术指标	测试结果	技术要求	测试方法
密度/（g?cm^-3）	1.036	N/A	T0603
针入度/25 °C， 0.1 mm	65	60~80	T0604
软化点/℃	100	≥ 100	T0606
延度/15 ℃， cm	> 100	≥ 43	T0605

参数		MP-AM	PG-AM	SPG-AM
填料体积 /m³	浸水前	4.14×10^-6	2.59×10^-6	2.99×10^-6
填料体积 /m³	浸水后	3.73×10^-6	1.59×10^-6	2.53×10^-6
下降幅度/%		9.90	38.61	15.38
填料表面积/m²	浸水前	1.75×10^-2	1.34×10^-2	1.50×10^-2
填料表面积/m²	浸水后	1.59×10^-2	7.87×10^-3	1.28×10^-2
下降幅度/%		9.14	41.26	14.67
填料颗粒数量/n	浸水前	5 342	5 289	5 030
填料颗粒数量/n	浸水后	4 812	2 507	4 353
下降幅度/%		9.92	52.60	13.46

填料类型	MP	PG	SPG
色散分量	11.56	1.05	5.52
极性分量	11.35	71.57	19.71
表面自由能	22.91	72.63	25.23
黏附功	41.70	30.48	33.88

疏水降溶性磷石膏填充沥青路面的水稳特性

Moisture stability of hydrophobicity⁃desolubilization phosphogypsum filled asphalt pavement

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