吉林大学学报(工学版) ›› 2024, Vol. 54 ›› Issue (3): 674-682.doi: 10.13229/j.cnki.jdxbgxb.20220457

• 材料科学与工程 • 上一篇    

镍-钴硫/磷化物纳米复合材料用于析氢反应

魏素凤1(),孙殿东2,张君宇3,王瑜喆3,李恩泽1,王国勇3()   

  1. 1.长春工业大学 材料科学与工程学院，长春 130012
    2.鞍钢集团 海洋装备用金属材料及其应用国家重点实验室，辽宁 鞍山 114021
    3.吉林大学 材料科学与工程学院，长春 130022
  • 收稿日期:2022-05-16 出版日期:2024-03-01 发布日期:2024-04-18
  • 通讯作者: 王国勇 E-mail:weisufeng@gmail.com;materwanggy@jlu.edu.cn
  • 作者简介:魏素凤（1979-），女，高级实验师，博士.研究方向：纳米材料，电催化材料.E-mail：weisufeng@gmail.com
  • 基金资助:
    国家自然科学基金重点研发项目(2018YFA0702304)

Nickel⁃Cobalt sulfide/phosphide nanocomposite for hydrogen evolution reaction

Su-feng WEI1(),Dian-dong SUN2,Jun-yu ZHANG3,Yu-zhe WANG3,En-ze LI1,Guo-yong WANG3()   

  1. 1.College of Materials Science and Engineering，Changchun University of Technology，Changchun 130012，China
    2.State Key Laboratory of Metal Material for Marine Equipment and Application，Ansteel Group，Anshan 114021，China
    3.College of Materials Science and Engineering，Jilin University，Changchun 130022，China
  • Received:2022-05-16 Online:2024-03-01 Published:2024-04-18
  • Contact: Guo-yong WANG E-mail:weisufeng@gmail.com;materwanggy@jlu.edu.cn

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摘要：

为寻求廉价、性能优异且反应稳定的碱性析氢催化剂以代替贵金属，以过渡金属Ni、Co为研究对象，通过一步煅烧处理得到Ni-Co硫/磷化物催化剂，借助X射线检测和能谱分析等方法验证了催化剂的成功制备。电化学测试结果表明，由于阴/阳离子之间的协同作用，所制备的Ni-Co硫/磷化物的催化活性和电荷转移速率均超过Ni-Co氢氧化物/硫化物/磷化物。Ni-Co硫/磷化物仅需要106 mV的过电势就可以达到10 mA·cm-2的电流密度，循环寿命超过20 h。

关键词: 过渡金属催化剂, 析氢反应, 硫磷化物, 异质结构, 协同作用

Abstract:

For seeking cheap， high performance and stable catalysts to replace noble metals. In this paper， sulfide/phosphide catalysts were obtained by one-step annealing treatment with transition metals Ni/Co， and the successful preparation of the catalysts was verified by electron detection and elemental analysis method. The electrochemical test results showed that the catalytic activity and charge transfer rate of the prepared Ni-Co sulfide/phosphide exceeded those of Ni-Co hydroxide/sulfide/phosphide due to the synergistic effect between anions/cations. Ni-Co sulfur/phosphide only requires an overpotential of 106 mV to achieve a current density of 10 mA·cm-2 and the stability was more than 20 h.

Key words: transition metal based catalyst, hydrogen evolution reaction, sulphide phosphates, heterostructure, synergistic effect

中图分类号: 

  • TB332

图1

NCSP复合材料合成示意图"

图2

四种不同形貌氢氧化物的FESEM图"

图3

NCSP的形貌以及微观结构图"

图4

Ni x Co1-x （OH）2和NCSP复合材料XRD衍射图"

图5

NCSP，NCS，NCP和Ni0.5Co0.5（OH）2的XPS全谱对比"

图6

NCSP的XPS图谱"

图7

HER性能分析图"

表1

NCSP与其他HER催化剂在1.0 M KOH电解液中的性能对比"

催化剂过电势/mV（j=10 mA·cm-2）Tafel斜率/（mV·dec-1）参考文献
NiFeSP9182.6［19］
Mn-CoP nanosheets14861［20］
Ni-Co-P-30015060.6［21］
Co-Ni-P16771.2［21］
CoP NA/CC145123［22］
Co0.85Se/NiFe-LDH280160［23］
O-Co2P16065.8［24］
CoPS film12857［25］
NCSP10674本文

图8

NCSP在碱性条件不同扫描速率（20、40、60、80、100、120和140 mV·s-1）下的CV曲线和相应计算出的扫描速率-电流密度曲线"

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