In order to ensure efficient computerized detection of vehicles passing green toll lane of highway, a detection method, named PGM-OCSVM, is proposed for free toll lane of highway based on multi-feature fusion. First, the Principal Component Analysis (PCA) is used to filter and simplify the sample characteristics. Then, the Genetic Algorithm is applied for adaptive adjustment of bandwidth of kernel function (σ) and false acceptance rate (v), which are two important parameters of one-class SVM. Finally, a one-class SVM model is constructed to learn the samples and classify the results. Big data analysis demonstrates that the proposed PGM-OCSVM can effectively complete green-vehicle discrimination task. This method has been applied to the vehicle detection system in free toll lane of highway.